• 제목/요약/키워드: Ternary system

검색결과 329건 처리시간 0.025초

Effects of Ligand-exchanged Cadmium Selenide Nanoparticles on the Performance of P3HT:PCBM:CdSe Ternary System Solar Cells

  • Park, Eung-Kyu;Fu, Honghong;Choi, Mijung;Luan, Weiling;Kim, Yong-Sang
    • Bulletin of the Korean Chemical Society
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    • 제34권8호
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    • pp.2321-2324
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    • 2013
  • An improved hybrid solar cell was obtained by focusing on the effects of ligand for CdSe nanoparticles, in the active layers. The performance was compared by mixing nanoparticles capped with pyridine or oleic acid for the acceptor material into poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester based active layer. The solar cells with pyridine capped CdSe nanoparticles showed a power conversion efficiency of 2.96% while oleic acid capped CdSe nanoparticles showed 2.85%, under AM 1.5G illumination. Formation of percolation pathways for carrier transport and a reduction in the hopping event resulted in better performance of pyridine capped nanoparticles.

THERMALLY INDUCED PHASE SEPARATION IN TERNARY POLYMER SOLUTION

  • Jung, Bum-Suk;Kang, Yong-Soo;Jones, Richard-A.L.
    • 한국막학회:학술대회논문집
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    • 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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    • pp.79-82
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    • 1999
  • Using Small Angle Light Scattering (SALS), the effect of quench depth on the kinetics of phase separation for ternary solution blends was investigated. The system was composed of two polymers (polystyrene and polybutadiene) and a solvent (toluene). The analyses of the early stage of phase separation were based of the Cahn-Hilliard theory [1,5]. Apparent diffusion coefficients and the fastest mode of fluctuations were evaluated, when quench depth of the system were varied near the critical composition of polymer. In the late stage of phase separation, the domain growth showed a power law with the 1/3 exponent, i.e. $q_m(t)~t^{-1/3}$. For comparison between real images and scattering profiles with time, the image of phase domains with time were obtained by using Laser Confocal Scanning Microscopy (LSCM).

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2성분계 및 3성분계 초유동 자기충전 콘크리트의 강도 특성 (Strength Propreties of Binary and Ternary Blended of Ultra Flowing Self-Compacting Concrete)

  • 최연왕;김경환;하상우;문대중;강현진
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.489-492
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    • 2006
  • Needs for the new technologies and cutting-edge Ultra Flowing Self-Compacting Concrete are emerging as the concrete structures are becoming bigger and more specialized recently. In North America and Europe, SCC, which has high resistance against flow ability and segregation, is being used as concrete material in applications such as precast and prestressed bridges, where reinforcing bars are overcrowdedly placed. In Korea, SCC has been utilized limitedly in building structures but its utilization should be expanded to engineering structures such as bridges. In this study, for the application in precast and prestressed bridges with overlycrowded reinforcing bars, USCC was mixed with admixtures to give a binary system and a ternary system according to the 1st grade rules by JSCE (Japan Society of Civil Engineers). Compressive strength and splitting tensile strength of the resulting USCCs were tested. Elastic modulus were compared with the values suggested in CEB-FIP code and ACI 318-05.

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HOM-LIE-YAMAGUTI SUPERALGEBRAS

  • Gaparayi, Donatien;Attan, Sylvain;Issa, A. Nourou
    • Korean Journal of Mathematics
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    • 제27권1호
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    • pp.175-192
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    • 2019
  • (Multiplicative) Hom-Lie-Yamaguti superalgebras are defined as a ${\mathbb{Z}}_2$-graded generalization of Hom-Lie Yamaguti algebras and also as a twisted generalization of Lie-Yamaguti superalgebras. Hom-Lie-Yamaguti superalgebras generalize also Hom-Lie supertriple systems (and subsequently ternary multiplicative Hom-Nambu superalgebras) and Hom-Lie superalgebras in the same way as Lie-Yamaguti superalgebras generalize Lie supertriple systems and Lie superalgebras. Hom-Lie-Yamaguti superalgebras are obtained from Lie-Yamaguti superalgebras by twisting along superalgebra even endomorphisms. We show that the category of (multiplicative) Hom-Lie-Yamaguti superalgebras is closed under twisting by self-morphisms. Constructions of some examples of Hom-Lie-Yamaguti superalgebras are given. The notion of an nth derived (binary) Hom-superalgebras is extended to the one of an nth derived binary-ternary Hom-superalgebras and it is shown that the category of Hom-Lie-Yamaguti superalgebras is closed under the process of taking nth derived Hom-superalgebras.

Mobile Phase Compositions for Ceramide III by Normal Phase High Performance Liquid Chromatography

  • Hong, Seung-Pyo;Lee, Chong-Ho;Kim, Se-Kyung;Yun, Hyun-Shik;Lee, Jung-Heon;Row, Kyung-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제9권1호
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    • pp.47-51
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    • 2004
  • Ceramide III was prepared by the cultivation of Saccharomyces cerevisiae. Ceramide III was partitioned from the cell extracts by solvent extraction and analyzed by Normal Phase High Performance Liquid Chromatography (NP-HPLC) using Evaporative Light Scattering Detector (ELSD). We experimentally determined the mobile phase composition to separate ceramide III with NP-HPLC. Three binary mobile phases of n-hexane/ethanol, n-hexane/lsoprophyl Alcohol(IPA) and n-hexane/n-butanol and one ternary mobile phase of n-hexane/IPA/methanol were demonstrated. For the binary mobile phase of n-hexane/ethanol, the first mobile phase composition, 95/5(v/v), was step-increased to 72/23(v/v) at 3 min. In the binary mobile phase, the retention time of ceramide III was 7.87min, while it was 4.11 min respectively in the ternary system, where the mobile phase composition of n-hexane/IPA/methanol, 85/7/8(v/v/v), was step-increased to 75/10/15(v/v/v) at 3 min. However, in the ternary mobile phase, the more peak area of ceramide III was observed.

Phase Change of Precipitates and Age Hardening in Rapidly Solidified Mg-Zn-Ca Base Alloys

  • Park Won-Wook;You Bong-Sun
    • 한국분말재료학회지
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    • 제12권4호
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    • pp.303-308
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    • 2005
  • Various kinds of Mg-Zn-Ca base alloys were rapidly quenched via melt spinning process. The meltspun ternary and quaternary alloy ribbons were heat-treated, and then the effects of additional elements on age hardening behavior and phase change of precipitates were investigated using Vickers hardness tester, XRD, and TEM equipped with EDS system. In ternary alloys, age hardening was mostly due to the distribution of $Mg_6Ca_2Zn_3$ and $Mg_2Ca$. The stable phases of precipitates were varied according to the aging temperature and the alloy composition. With the increase of Ca content, $Mg_2Ca$ precipitates were detected more than $Mg_6Ca_2Zn_3$ precipitates. In quaternary alloys, the precipitates taken from Mg-Zn-Ca-Co were identified as new quaternary phase, whereas those taken from Mg-Zn-Ca-Zr as MgZnCa containing Zr. In general, the ternary alloy showed higher peak hardness and thermal stability than the quaternary considering the total amounts of the solutes. It implies that the structure of precipitate should be controlled to have the coherent interface with the Mg matrix.

pH-민감성 삼성분계 공중합체 젤의 합성 및 팽윤 속도론 (Synthesis and Swelling Kinetics of a Cross-Linked pH-Sensitive Ternary Copolymer Gel System)

  • Zafar, Zafar Iqbal;Malana, M.A.;Pervez, H.;Shad, M.A.;Momma, K.
    • 폴리머
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    • 제32권3호
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    • pp.219-229
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    • 2008
  • A pH sensitive ternary copolymer gel was synthesized in the presence of ethylene glycol dimethacrylate (EGDMA) as a crosslinking agent through radical polymerization of vinyl acetate (VA), acrylic acid (AA) and methyl acrylate(MA) with a weight ratio of 1 : 1.3 : 1. A number of experiments were carried out to determine the swelling behavior of the gel under a variety of pH conditions of the swelling medium. As the pH of the swelling medium was changed from 1.0 to 8.0 at $37^{\circ}C$, the gel showed a shift in the pH-dependent swelling behavior from Fickian (n=0.3447) to non-Fickian (n=0.9125). The resulting swelling parameters were analyzed using graphical and statistical methods. The results showed that the swelling of the gel was controlled by the pH of the medium, i.e. $n=n_o{\exp}(S_{C}pH)$, where n is the diffusion exponent, $n_o(=28.9645{\times}10^{-2})$ is the pre-exponential factor and $S_C$(=0.1417) is pH sensitivity coefficient. The swelling behavior of the gel was also examined in aliphatic alcohols. The results showed that the rate of swelling increased with increasing number of carbon atoms in the alcoholic molecular chain.