• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.2
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• pp.233-240
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• 2000

An experimental study of condensation heat transfer was performed for pure refrigerants HFC32, HFCI25, and HFC134a, and a ternary refrigerant mixture of HFC32/125/134a (23/25/52wt%). The heat transfer coefficients were measured inside a horizontal smooth tube 5.8 mm I.D. and 8.0 m long. The refrigerant temperature at inlet was 40 $^{\circ}C$, and the mass flux was varied from 150 to 400 $kg/m^2s$. As for the pure refrigerants, the heat transfer coefficient of HFC32/125/l34a decreased as the quality decreased. In addition, the heat transfer coefficient of HFC32/l25/134a was about 20 % lower than HFC 134a at a low mass flux but showed no reduction at a high mass flux. The heat transfer coefficient of ternary refrigerant mixtures was 30% lower on the average than that of the pure refrigerant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.4
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• pp.262-270
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• 2001

This paper deals with a prediction method for the condensation of ternary refrigerant mixture inside a horizontal smooth tube. Based on some reliable assumptions, the governing equations for the local heat and mass transfer characteristics are derived, and the prediction for the condensation of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a, including R407C, is carried out. The local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, mass flux etc. are obtained for a constant wall temperature and a constant wall heat flux conditions, and the effects of the composition of HFC32/HFC125/HFC134a on heat transfer characteristics are examined. The prediction result is also compared with experimental data for condensation of ternary refrigerant mixtures. The predicted wall temperature distribution has a similar trend with experimental data but the predicted local heat transfer coefficients are 20-30% higher than the experimental data.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.6
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• pp.912-920
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• 1999

The forced convective boiling heat transfer coefficients of R-407C were measured inside a horizontal tube 6.0mm I.D. and 4.0m long. The heat transfer coefficients increased according to an increase in heat flux at constant mass flux. Because nucleation was completely suppressed in the two-phase flow region with high quality, heat transfer coefficients in forced convective evaporation were higher than those in nucleate boiling region. Average heat transfer coefficients of R-407C were about 30 percent lower than the pure refrigerant correlation, due to mass transfer resistance at the gas-liquid interface. However, the total experimental data shows an agreement with the predicted data for ternary refrigerant mixtures with a mean deviation of 30%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.6
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• pp.468-476
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• 2002

This paper deals with heat and mass transfer characteristics and performance evaluation of a counter flow double-tube condenser for a multi-component refrigerant mixture. The local heat and mass transfer characteristics of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a are evaluated for a counter flow double-tube condenser cooled by water. Then, the local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, heat flux and condensation mass flux are obtained. The heat exchange performance for ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a on the total pressure drop and the heat transfer characteristics are also compared with those for R404A, R410A, R502, R22, R32, Rl23 and R134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.3
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• pp.276-283
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• 1997

The nucleate boiling heat transfer experiments are performed using a ternary refrigerant R407C which is a candidate of alternatives of HCFC 22. The boiling phenomena for R-32, R-125, and R-134a which are the constituent refrigerants of R407C are also investigated to give the foundation of theoretical research for the mixture component boiling. The nucleate boiling heat transfer coefficients of R407C is less than those of HCFC 22 which has the similar physical and transport properties. Since the experimental results show the deterioration of boiling heat transfer coefficients of ternary mixture refrigerants R407C, the boiling heat transfer coefficients of R407C cannot be obtained by the linear combination of boiling heat transfer coefficients from its constituent components R-32, R125, and R134a.

• International Journal of Air-Conditioning and Refrigeration
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• v.6
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• pp.93-103
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• 1998

The nucleate boiling heat transfer experiments are performed using a ternary refrigerant R407C which is a candidate of alternatives of HCFC 22. The boiling phenomena of R-32, R-125 and R-134a which are the constituent refrigerants of R407C are also investigated. The nucleate boiling heat transfer coefficients of R407C are less than those of HCFC 22 which have the similar physical and transport properties. In our experimental pressure range, which is similar to the operational pressure of air conditioning system, the deterioration of boiling heat transfer coefficients of mixture refrigerant R407C does not appear for moderate wall superheat region. Since nucleate boiling heat transfer coefficients cannot be obtained from ideal mixing law of mixture, Thome's method was used to predict. To account for the heat flux effect and system pressure in Thome's method, the correcting factor, a(P.L1T), was introduced and obtained from experiments for ternary refrigerant R407C.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.5 no.3
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• pp.217-225
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• 1993

Nonflammable mixtures of flammable and nonflammable refrigerants are possible as substitute refrigerants for use in domestic heat pumps and refrigerators. Refrigerant leakage from such a system is of paramount concern since it is possible that the resulting mixture composition remaining in system will reside in the flammable range. This paper presents a simulation of a leakage process of refrigerant mixtures. Idealized cases of isothermal leakage process are considered in this study representing a slow leak. Simulation is performed for selected composition of binary and ternary refrigerant mixture; R-32/134a and R-32/125/134a. Mixture compositions with respect to percentage leak of original charge are presented. In isothermal leakage process, both vapor and liquid compositions of more volatile refrigerant decrease during vapor and liquid leak, but the total composition of this component decreases during vapor leak and increases during liquid leak. Vapor and liquid compositions are determined depending on the vapor-liquid equilibrium relation of the refrigerant mixture. The refrigerant mixture left in the system can go to a nonflammable direction relying on which component in the mixture is flammable.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.6
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• pp.732-742
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• 1998

Prediction method for heat transfer coefficients in a horizontal smooth tube with forced convection condensation is proposed. In this paper, the analogy between momentum and heat transfer was applied to an annular flow regime and the logarithmic velocity distribution is applied to describe the velocity profile within the liquid film. Prediction results are compared with those of experimental ones. The test refrigerants are R113, R22, R134a, R407C(R33/R125/R134a, 23/25/52 wt%), R410A(R32/R125, 50/50 wt%) and R134a＋R123(R134a/R123, 85.5/14.5 wt%) which are used under operating conditions in a condenser of air-conditioner. The proposed prediction method shows good agreement with experimental data within$\pm 30%$ for pure refrigerants. For the mixture refrigerants including the ternary mixture refrigerant R407C, condensation heat transfer from this study are higher than those from experiments. By correcting the constant in two-phase frictional multiplier, the predicated heat transfer coefficients become similar to the experimental results.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.22 no.6
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• pp.383-391
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• 2010

In this study, HFC152a, HFC134a/HFC152a and HC290/HFC134a/HFC152a mixtures are studied for the supplementary and alternative refrigerants for HFC134a used in automobile air-conditioners. Due to the high global warming potential of HFC134a, it has to be phased out in the long run. Thermodynamic performance of these refrigerants are measured in a bench tester of 3.5 kW capacity with an open type compressor under both summer and winter conditions. Test results show that the coefficient of performance (COP) and capacity of pure HFC152a and HFC134a/HFC152a mixture are 9.1~12% and 7% higher than those of HFC134a. As for the HC290/HFC134a/HFC152a, the COP is up to 9.5% higher than that of HFC134a with 1~2% of HC290 while that is up to 6.1% lower than that of HFC134a with 5% HC290. The capacity of the ternary mixture, however, is 8.6% higher than that of HFC134a at all compositions tested. The compressor discharge temperatures of all refrigerants tested are $6{\sim}10^{\circ}C$ higher than that of HFC134a. For all refrigerants, the amount of charge is reduced up to 32% due to the decrease in liquid density. Overall, these refrigerants provide good performance with reasonable energy savings with less environmental problem and thus can be used as long term alternatives for automobile air-conditioners.

• Solar Energy
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• v.15 no.3
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• pp.75-90
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• 1995

This paper is concerned about alternative refrigerants for HCFC22 used in room air conditioners and heat pumps. Computer simulation of residential air conditioners using refrigerant mixtures is carried out. Following refrigerants are selected as the pure refrigerants constituting the mixtures studied: R32, R124, R125, R134, R134a, R143a and R152a. Simulation results are presented fur the following mixtures: R32/R134a, R32/R152a, R32/R134, R32/R124, R143a/R134a, R143a/R152a, R143a/R124, R125/R134a, R125/R152a, R125/R124, R32/R152a/R134a, R32/R152a/R134, R32/R152a/R124. The best fluid is found to be the ternary mixture of R32/R152a/R124. For that mixture, the coefficient of performance(COP) and volumetric capacity for refrigeration(VCR) are 13.7% larger and 23% smaller than the respective values for HCFC22. R32/R124 mixture is the best binary fluid pair whose COP and VCR are 13.4% larger and 9.6% smaller than those for HCFC22.