• Journal of Life Science
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• v.5 no.4
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• pp.155-161
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• 1995

The effects of substrate concentration, enzyme concentration, reaction temperature, and water content were investigated in intramolecular esterification. This study used cyclohexane as organic solvent, power lipase as enzyme, and benzyl alcohol and octanoic acid as substrate. The initial reaction rate was found to be proportional to enzyme concentration; followed Michaelis-Menten equation for octanoic acid; and was inhibited by benzyl alcohol . The observed initial reaction rate first increased, then decreased with increasing reaction temperature, giving rise to the maximum rate at 20$\circ$. The drop in the reaction rate at higher temperature was to partition equilibrium change of substrate between organic solvent and hydration layer of enzyme molecule in addition to the deactivation by enzyme denaturation. Water layer surrounding enzyme molecule seemed to activate in organic solvent and the realistic reaction was done in the water layer. In the enzymatic reaction in organic solvent, the initial reaction rate was influenced by partition quilibrium of substrate, so the optimum condition of substrate concentration, enzyme concentration, reaction temperature, and water content would give a good design tool.

• 한국전산유체공학회:학술대회논문집
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• 2008.03b
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• pp.324-327
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• 2008

Two stage startup of high thrust liquid rocket engine can reduce the abrupt impulse to the vehicle and engine by changing oxidizer flow rate to the combustion chamber. Also it ensures stable ignition of combustion chamber against hard start and to prevent pump stall by the sudden supply of large mass flow rate. However high discharge pressure of oxidizer pump or temperature rise in gas generator may be a problem in applying the preliminary stage. To solve this problem, we analyzed the effect of the slope of oxidizer pump's head curve and the oxidizer mass flow rate to combustion chamber during preliminary stage using the rocket engine startup analysis code. A moderate slope(${\circleddash}{\sim}$-3) of head curve and 80% mass flow rate during preliminary stage can reduce the oxidizer pump discharge pressure by 15 to 20% comparing with the condition of ${\circleddash}$=-4.37 head curve and 70% mass flow rate. Also it can maintain the turbine inlet temperature rise within 50K from the nominal value.

• Journal of Electrical Engineering and Technology
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• v.12 no.6
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• pp.2348-2352
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• 2017

The electrical contact characteristics including temperature rise, contact resistance and arc erosion rate of the $Ag-SnO_2$ materials with increased $SnO_2$ content were investigated during the repeated make-and-break operations. The thickness of arcing melting layer reduces by half and the arc erosion rate decreases more than 70% under 10000 times operations at AC 10 A with the $SnO_2$ content increasing from 15 wt.% to 45 wt.%, on one hand, temperature rise and contact resistance increase obviously but could be reduced to the same order of conventional $Ag-SnO_2$ materials by increasing the contact force. The microstructure evolution and the effect of $SnO_2$ on the arc erosion, contact resistance were analyzed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.11
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• pp.7736-7744
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• 2015

Considering the significant waste of industrial energy, effective use of low temperature waste heat is extremely important. In this study, a heat pump cycle with double effect and double stage was realized, which escalates the hot water temperature from $50^{\circ}C$ to $70^{\circ}C$ using $160^{\circ}C$ high temperature heat source and $17^{\circ}C$ low temperature heat source. The steam generated in the first generator condenses in the first condenser generating steam in the second generator. The steam condenses in the second condenser and is provided to the second evaporator. Part of the water out of the second evaporator is supplied to the first evaporator, which evaporates using low temperature waste heat. The evaporated steam enters the first absorber and the second evaporator. The steam out of the second evaporator is absorbed into the solution at the second absorber. The hot water temperature is raised in the second condenser and in the second absorber. Proper flow rates and UA values, which satisfied temperature lift $20^{\circ}C$ and COP 1.6, were deduced through trior and error. The COP increases as the temperature of the high temperature water increases, hot water temperature decreases and flow rate increases, waste water temperature and flow rate increases, solution circulation rate decreases. On the other hand, the temperature rise of the hot water increases as the temperature of the high temperature water increases, hot water temperature increases and flow rate decreases, waste water temperature and flow rate increases, solution circulation rate increases. In addition, the COP and hot water temperature rise increase as UAs of the heat exchangers increase.

• Journal of Korean Society on Water Environment
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• v.35 no.3
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• pp.234-247
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• 2019

In a deep lake and reservoir, thermal stratification is of great importance for characteristics of hydrodynamic mixing of the waterbody, and thereby influencesvertical distribution of dissolved oxygen, substances, nutrients, and the phytoplankton community. The purpose of this study, was to project the effect of a future climate change scenario on water temperature, stratification strength, and thermal stability in the Soyanggang Reservoir in the Han River basin of South Korea, using a suite of mathematical models; SWAT, HEC-ResSim, and CE-QUAL-W2(W2). W2 was calibrated with historical data observed 2005-2015. Using climate data generated by HadGEM2-AO with the RCP 4.5 scenario, SWAT predicted daily reservoir inflow 2016-2070, and HEC-ResSim simulated changes in reservoir discharge and water level, based on inflow and reservoir operation rules. Then, W2 was applied, to predict long-term continuous changes of water temperature, in the reservoir. As a result, the upper layer (5 m below water surface) and lower layer (5 m above bottom) water temperatures, were projected to rise $0.0191^{\circ}C/year$(p<0.05) and $0.008^{\circ}C/year$(p<0.05), respectively, in response to projected atmospheric temperature rise rate of $0.0279^{\circ}C/year$(p<0.05). Additionally, with increase of future temperature, stratification strength of the reservoir is projected to be stronger, and the number of the days when temperature difference of the upper layer and the lower layer becomes greater than $5^{\circ}C$, also increase. Increase of water temperature on the surface of the reservoir, affected seasonal growth rate of the algae community. In particular, the growth rate of cyanobacteria increased in spring, and early summer.

• Journal of the Korea Construction Safety Engineering Association
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• s.41
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• pp.88-101
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• 2007

Recently, the condensation of walls often occurring in domestic high-rise apartment buildings is an important problem. The main purpose of this study is to develop the prediction method for the surface condensation on curtain wall in high-rise apartment buildings. Therefore, in this study, we first analyzed exterior climate factors through the analysis of the Seoul climate data and predicted the change of indoor temperature by using Apache program to find the cause of the condensation state and to prevent condensation. Also, according to this result, exterior climate factors and interior factors, which caused the condensation, was examined. The thermal performance of the curtain wall and the range of potential condensation were analyzed to focus on high-rise apartment buildings through computer simulation programs. The results are as $follows;^1$) The frame edge of curtain wall has a higher U-value than in the center by $30%^2$) Because of stack effect, the rooms on the higher floor have a lower external ventilation rate resulting to a higher relative humidity3) Installing a ventilation system($20m^3$/h. person) makes it possible to have a higher external ventilation rate, resulting to a lower relative humidity.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.895-904
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• 2011

Stratified charge has been thought as one of the ways to avoid a sharp pressure rise on HCCI combustion. The purpose of this study is to evaluate the potential of stratified charge for reducing PRR on HCCI combustion. The pre-mixture with thermal, mixing and EGR stratifications is charged in Rapid Compression Machine. After that, the pre-mixture is compressed and in that process, in-cylinder gas pressure and temperature are analyzed. Additionally numerical calculation with multi-zones modeling is run to know the potential of stratified charge for reducing PRR.

• Journal of Environmental Science International
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• v.14 no.9
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• pp.889-896
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• 2005

The nanosized $TiO_2$ photocatalysts were prepared by the hydrolysis of $TiCl_4$ and calcined at different temperatures. The resulting materials were characterized by TGA, DSC, XRD, and TEM testing techniques. XRD, TEM, and BET measurements indicated that the particle size of $TiO_2$ was increased with rise of calcination temperature and surface area was decreased with rise of it. The prepared $TiO_2$ photocatalysts were used for the photocatalytic degradation of congo red. The effects of calcination temperature, $TiO_2$ loading, the initial concentration of congo red, and usage frequencies were investigated and the rate constants were determined by regressing the experimental data. Calcination is an effective treatment to increase the photo activity of nanosized $TiO_2$ photocatalysts resulting from the improvement of crystallinity. The optimum calcination temperature of the catalyst for the efficient degradation of congo red was found to be $400^{\cric}C$. The rate constant was decreased with increase in the initial concentration of congo red and increased with increase in the $TiO_2$ loading. In the case of $TiO_2$ photocatalysts, the photocatalytic activity wasn't greatly affected by the usage frequencies.

• Journal of Power System Engineering
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• v.16 no.3
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• pp.10-15
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• 2012

Recently we have a growing interest in environmental pollution and alternative energy. Diesel engine is generally used to produce the power on the ground and the sea. However, the combustion characteristics are changed on account of the wear of fuel system and the altered ambient condition of the combustion chamber by the increment of the engine operation hour. Therefore combustion characteristics on fuel injection timing are experimentally investigated to find out the optimum fuel injection timing in the case of the aged diesel engine using biodiesel blend oil. Cylinder pressure, rate of pressure rise, rate of heat release and combustion gas temperature are risen by the advancing fuel injection timing, while the exhaust gas temperature and soot emission level are decreased by the advancing of fuel injection timing. The least specific fuel oil consumption is indicated at BTDC $26^{\circ}$ CA on the 75%load and at 1800rpm.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.2
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• pp.35-41
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• 2011

This work investigates the potential of in-cylinder thermal stratification and fuel stratification for extending the operating ranges in HCCI engines, and the coupling between thermal stratification and fuel stratification. Computational results areemployed. The computations were conducted using both a custom multi-zone version and the standard single-zone version of the Senkin application of the CHEMKINII kinetics rate code, and kinetic mechanism for di-methyl ether (DME). This study shows that the potential of thermal stratification and fuels stratification for extending the high-load operating limit by a staged combustion event with reduced pressure-rise rates is very large. It was also found that those stratification offers good potential to extend low-load limit by a same mechanism in high-load. However, a combination of thermal stratification and fuel stratification is not more effective than above stratification techniques for extending the operating ranges showing similar results of fuel stratification. Sufficient condition for combustion (enough temperature for) turns misfire in low-load limit to operate engines, which also leads to knock in high-load limit abruptly due to the too high temperature with high. DME shows a potential for maximizing effect of stratification to lower pressure-rise rate due to the characteristics of low-temperature heat release.