• Title/Summary/Keyword: Temperature reduction

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An Experimental Study on the Effect of Reduced Slag and Gypsum on Concrete at Low Temperature(-5℃) (저온(-5℃)에서의 환원슬래그 및 석고가 콘크리트에 미치는 영향에 관한 실험적 연구)

  • Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Min, Tae-Beom;An, Dong-Hee;Choi, Si-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.279-285
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    • 2017
  • In this study, the development of concrete preventing initial frost damage and durability about that were evaluated by using anti-aging agent and admixture(reduced slag). As a result of experiment, initial hydration heat was increased by $C_{12}A_7$ of reduced slag components but it was not effective to development of strength. Also fluidity decreased with increasing replacement of reduced slag. This suggested that fluidity was low by rapid setting due to absent of gypsum in reduced slag components. In case of CR2G specimen that added 4% gypsum, the flow ability was higher than plain. It is considered that concrete developed using reduced slag should use $SO_3$. Result of durability experiments, the durability decreased with increasing replacement amount of reduced slag.

The Photoluminescence Characteristic of Ba2-xSrxSiO4:Eu2+ Phosphor Particles Prepared by Spray Pyrolysis (분무열분해 공정에 의해 제조된 Ba2-xSrxSiO4:Eu2+ 형광체의 발광특성)

  • Kang, Hee Sang;Park, Seung Bin;Koo, Hye Young;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.609-613
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    • 2006
  • Ba2-xSrxSiO4:Eu2+ phosphor particles with the high photoluminescence (PL) intensity under long wavelength ultraviolet (UV) were prepared by spray pyrolysis. The photoluminescence, morphological and crystalline characteristics of $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ phosphor particles prepared by spray pyrolysis were investigated. $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ phosphor particles prepared by spray pyrolysis had various colors from bluish green to yellow by changing the ratio of barium and strontium of the host material. In case of x=0, the main emission peak of $Ba_2SiO_4:Eu^{2+}$ phosphor was 500 nm. In case of x=2, the main emission peak of $Sr_2SiO_4:Eu^{2+}$ phosphor was 554nm. $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ phosphor particles obtained by spray pyrolysis had spherical shape and hollow structure. On the other hand, the post-treated $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ phosphor particles had large size and irregular shape. The $Ba_{1.488}Sr_{0.5}SiO_4:Eu_{0.012}{^{2+}}$ phosphor particles had the maximum PL intensity after post-treatment at temperature of $1300^{\circ}C$ for 3h under reduction atmosphere.

Improvement of Structure and Electrochemical Properties of LiNi0.5Mn1.5O4 for High Voltage Class Cathode Material by Cr Substitution (Cr 치환을 이용한 고전압용 양극 활물질 LiNi0.5Mn1.5O4의 구조와 전기화학적 성능의 개선)

  • Eom, Won-Sob;Kim, Yool-Koo;Cho, Won-Il;Jang, Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.82-87
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    • 2005
  • The cathode material, $LiNi_{0.5}Mn_{1.5}O_4$, for high voltage applications of Li-ion batteries exhibits impurity phases due to oxygen deficiency during the high temperature heat treatment. The impurity phase reduces the electrochemical properties of the electrode since the deficiency spinel structure disturbs the lithium ion intercalation and deintercalation. In this study, Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4(0{\leq}x{\leq}0.05)$ powders are synthesized by a sol-gel method in order to reduce the amount of the impurity phases in the $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4$. Thermal analysis of the cathode material shows that the $LiNi_{0.5}Mn_{1.5}O_4$ without Cr substitution looses $2\%$ of its weight due to oxygen deficiency but the amount of weight loss is diminished when Cr is substituted. XRD analysis also supports the reduction of the impurity phases in the cathode after chromium substitution, suggesting that the improvement of the electrochemical properties such as the capacity retention and electrochemical stability are attributed to the low content of impurity phases in the Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4.$

Evaluation of Cold Tolerance of Blueberry (Vaccinium corymbosum L.) and Diagnosis of Freezing Injury Using Timber Moisture Meter (블루베리의 내한성 평가 및 목재수분계측기를 이용한 동해피해 진단)

  • Kim, Ki-Deog;Lee, Jun-Gu;Ryu, Myeong-Sang;Yoo, Dong-Lim;Kwon, Young-Seok;Lee, Jong-Nam
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.354-361
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    • 2012
  • This study was conducted to evaluate on the freezing tolerance of introduced blueberry cultivars in Korea and to investigate availability of portable timber moisture meter for simple and rapid diagnosis of blueberry-shoot damage by freezing during wintering. Frost tolerance of blueberry cultivars showed big difference that rates of blueberry-shoot death were widely distributed from about 0% to 100% after wintering. Optical density in TTC reduction of blueberry twig treated low temperature was low in order of $-40^{\circ}C$ < $-21^{\circ}C$ < $4^{\circ}C$. Hardiness evaluation of visible injury in the cross-sectional surface color did not agree with that of rates of blueberry-shoot death during wintering. Lowest water content of blueberry stem measured by timber moisture tester during wintering was about 15%. During wintering, water contents of blueberry stems were higher at lower part of tree, but were low at end part of stems, and then when the blueberry grew again for spring, the water content gradually increased to 20~40%. Water content of blueberry stem with freezing injury during wintering decreased to under 5% by desiccation. Therefore it is assummed that the moisture content of blueberry stem injured by freezing during wintering was about under 14%, and it is expected that portable timber moisture meter could be available for rapid diagnosis of blueberry freezing injury in field.

A Study on Characterization of Expansion Agent in Mortar with Light Burned Dolomite By-Product (경소백운석(輕燒白雲石) 부산물(副産物)을 활용(活用)한 바닥 몰탈용 팽창재(膨脹材)의 특성검토(特性檢討))

  • Lee, Keon-Ho;Min, Sung-Eoi;Lee, Hyoung-Woo;Cho, Jin-Sang;Cho, Kye-Hong;Han, Choon
    • Resources Recycling
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    • v.21 no.6
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    • pp.12-22
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    • 2012
  • This study investigated a utilization technology of light burned dolomite. light burned dolomite ($CaMg(CO_3)_2$) generated in furnace (steel manufacturer) is an alternative to quick lime. Using light burned dolomite has an effect on reducing the consumption of fluorite slag MgO concentration in supersaturated solution by prolonging the life of softening effect. Armophous MgO, not containing periclase is formed by firing dolomite under $800^{\circ}C$. It has larger surface area and higher reactivity than periclase, and also shows better expansion effect than quicklime. Due to those effects, therefore, armophous MgO produced from light burned dolomite is used as an alternative expansion agent in mortar. In the experiment, characteristics of light burned dolomite were compared to those of existing expansion agents such as anhydrite and quicklime. Then, each expansion and shrinkage rates were measured over a period of about 3 months in both of 1m Jis mold at labscale and apartment mortar flooring at field scale. In the result, it was observed that light burned dolomite in mortar flooring more compensates for the expansion and shrinkage rates than the existing expansion agents, showing low expansion rate of below 0.05% and also decreases the crack.

Drug Delivery into the Blood-Brain Barrier by Endogenous Substances-A Role of Amine and Monocarboxylic Acid Carrier Systems for the Drug Transport- (내인성물질의 수송계를 이용한 혈액-뇌관문에의 약물송달V-약물의 혈액-뇌관문 투과성에 대한 염기성 아민 및 모노카르본산 수송계의 역할-)

  • Kang, Young-Sook
    • Journal of Pharmaceutical Investigation
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    • v.20 no.4
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    • pp.223-228
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    • 1990
  • The contribution of endogenous transport systems to the blood-brain barrier (BBB) transport of basic and acidic drugs was studied by using a carotid injection technique in rats and an isolated bovine cerebrovascular disease state were compared between the normotensive rats (WKY) and stroke-prone spontaneously hypertensive rats (SHRSP) which have been well established as an animal model with pathogenic similarities to humans. Basic drugs such as eperisone, thiamine and scopolamine inhibited, in a concentration dependent manner the in vivo uptake of $[{^3}H]choline$ through BBB, whereas amino acids and acidic drugs such as salicylic acid and valproic acid did not inhibit the uptake. The uptake of $[^3H]choline$ by B-CAP increased with time and showed a remarkable temperature dependency. The uptake of $[^3H]choline$ by B-CAP showed the very similar inhibitory effects as observed in the in vivo brain uptake, and was competitively inhibited by a basic drug, eperisone. The in vivo BBB uptakes of $[^3H]acetic$ acid and $[^{14}C]salicylic$ acid were dependent on pH of the injectate and the concentration of drugs. Several acidic drugs such such as salicylic acid, benzoic acid and valproic acid inhibited the in vivo uptake of $[^3H]acetic$ acid, whereas amino acid, choline and a basic drug such as eperisone did not inhibit the uptake. The uptake of acetic acid by B-CAP was competitively inhibited by salicylic acid. The permeability surface area product (PS) through BBB for $[^3H]choline$ in SHRSP was significantly lower than that in WKY. The concentration of choline in the brain dialysate in SHRSP was about half of that in WKY, while no significant difference was observed in the plasma concentration of choline between SHRSP and WKY. No significant difference was observed in the transport of monocarboxylic acids, glucose and neutral amino acid through BBB between SHRSP and WKY. From these results, it was concluded that BBB transport system of choline contributes to the transport of basic drugs through BBB, that acidic drugs can be transported via a moncarboxylic acid BBB transport system and that the specific dysfuntion of the BBB choline transport in SHRSP was ascribed to the reduction of the maximum velocity of choline concentration in the brain interstitial fluids.

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Manufacturing Techniques and Provenance of Earthen Wares in Daecheonri Prehistory Site of Okcheon County, Korea (옥천 대천리 유적지 토기의 제작기법 및 원료산지 분석)

  • Lee, Hyo-Min;Yang, Dong-Yun;Gu, Ja-Jin;Kim, Ju-Yong;Han, Chang-Gyun;Choe, Seok-Won
    • The Korean Journal of Quaternary Research
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    • v.18 no.1 s.22
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    • pp.1-20
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    • 2004
  • A geoscientific research was performed on 12 samples of comb-pattern potteries which were excavated at Daecheonri neolithic site, Korea. The texture and compositions of 12 potteries and surrounding metrix of soil and rocks were compared with the help of petrographic microscope, XRD and REE data. As to the manufacturing techniques thick potteries are caused by the amount and number of coarse grains which are assumed to be added shards when their distributional pattern are considered. DC1, DC3, DC 7 and DC11 samples have clearly oriented textures, and the orientation of vesicles in DC3 and DC11 samples arranged in the same direction with those on the pottery surface. This indicates the use potter's wheel technique in manufacturing potteries. Burning temperature is assumed over $800^{/circ}C$, particularly under reduction environment. As to the source, raw materials of pottery matrix are derived from the bottom of excavation site, or in an extracted outcrop of the northwestern foothill from site, while the shard materials are very similar with those extracted from sandy loams near sites. Finally any use pattern of pottery may control the pottery thickness, shard addition, and matrix selection.

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Air Drying Technology for Dewatered Cake from Wastewater and Waterworks Sludge (상.하수 슬러지 탈수케이크의 공기건조에 관한 연구)

  • Lee, Jung-Eun;Cho, Eun-Man;Kim, Bong-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1154-1161
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    • 2006
  • Air drying equipment was built as a device for reduction of dewatered cake from wastewater and waterworks sludge and to reproduce it by reusable matter. Dewatered cake was supplied into the air drying equipment which operated by air velocity of 80 m/sec, air rate 30 $m^3/min$ and air temperature of $40^{\circ}C$, and dried to produce the dried powder. The air drying equipment was composed of the air ejector which made high-speed fluid field, and cyclone which made circling fluid field. Dewatered cake was crushed at the high-speed zone as first step, and formed into dried powder of sphere shape by the collision between particles at the circling fluid zone.. Wastewater sludge with water content of 82.5 wt% was supplied 1.0 kg/min into air drying equipment and produced the dried powder which had the water content of 62.3 wt% and mass median diameter of 2.4 mm after process. At that time, it was analyzed that water removal rate was 0.1 $H_2O{\Delta}kg/min{\cdot}DS$ kg and air consumption was 170 $m^3/DS$ kg. Under same experimental conditions, when waterworks sludge was dried, water content of dried powder decrease to 47.5 wt% and mass median diameter decrease 2.1 mm and water removal rate increase 0.13 $H_2O{\Delta}kg/min{\cdot}DS$ kg. Air consumption increase 180 $m^3/DS$ kg with comparison to the results of wastewater sludge. Therefore, this technology was evaluated that drying the dewatered cake of waterworks sludge was more efficient than wastewater sludge, and also economical sludge handling technology due to drying the cake by only air.

Effect of Alkaline Activator and Curing Condition on the Compressive Strength of Cementless Fly Ash Based Alkali-Activated Mortar (시멘트를 사용(使用)하지 않은 플라이애시 알칼리 활성(活性) 모르타르의 압축강도(壓縮强度)에 미치는 알칼리 활성제(活性劑) 및 양생조건(養生條件)의 영향(影響))

  • Kang, Hyun-Jin;Ryu, Gum-Sung;Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Kim, Sung-Wook;Lee, Jang-Hwa
    • Resources Recycling
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    • v.18 no.2
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    • pp.39-50
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    • 2009
  • Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

Analysis of Trench Slope Stability in Permafrost Regions According to the Vertical and Horizontal Angle of Slope (동토지반에서 종방향 및 횡방향 사면의 경사에 따른 트렌치 안전성 분석)

  • Kim, Jong-Uk;Kim, Jung-Joo;Jafri, Turab H.;Yoo, Han-Kyu
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.27-33
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    • 2017
  • In this study, the stability of trench slope was analysed in summer and winter seasons for the construction of pipelines in permafrost regions. The construction standards of Korea, Russia and UK were compared for obtaining an optimum trench shape for a pipeline of 30 in. diameter. Using the geotechnical properties of soil in Yakutsk (Russia), the stability of trench slope was analysed using Strength Reduction Method (SRM) according to the horizontal slope angle values of $0^{\circ}$, $10^{\circ}$, $20^{\circ}$ and $30^{\circ}$ and vertical slope angle values of $20^{\circ}$, $30^{\circ}$ and $40^{\circ}$. In both seasons, an increase in the slope angle results in a decrease in the factor of safety. The results show that horizontal slope angle of $30^{\circ}$ was not safe in summer season. At the vertical slope angle of $20^{\circ}$, trench side failure was observed, whereas, ground slope failure was observed at the vertical slope angles of $30^{\circ}$ and $40^{\circ}$. Due to the solidification of pore water at temperatures below $0^{\circ}C$, cementation of soil particles take place. Therefore, the trench slope was found to be stable in the winter season at all vertical and horizontal slop angles, except for special load cases and abrupt temperature changes.