• Journal of the Korean Electrochemical Society
• /
• v.11 no.4
• /
• pp.227-241
• /
• 2008

This article involves a unified treatment of equilibrium thermodynamics of the chemical reaction coupled with other interfacial (phase boundary) reactions. The modified (restrictive) chemical potential ${\mu}_k^+$, such as electrochemical potential, hydrostatic-chemical (mechanochemical) potential (exceptionally in the presence of the pressure difference) and surface-chemical potential, was first introduced under the isothermal and isobaric conditions. This article then enlightened the equilibrium conditions in case where the release of chemical energy is counterbalanced by the supply of electrical energy, by the supply of hydrostatic work (exceptionally in the presence of ${\Delta}p$), and finally by the release of surface energy, respectively, at constant temperature T and pressure p in terms of the modified chemical potential ${\mu}_k^+$. Finally, this paper focussed on the difference between chemical and electrochemical equilibria based upon the fundamentals of the isothermal and isobaric equilibrium conditions described above.

• Journal of Advanced Marine Engineering and Technology
• /
• v.39 no.10
• /
• pp.1062-1067
• /
• 2015

Floating architecture is a type of building that is geographically located on a sea or a river. It floats under the influence of buoyancy, and does not have an engine for moving it. Korea is a peninsula surrounded by sea except on the north side, so floating architectures have been mainly focused on two points: solving the issue of small territory and providing various leisure & cultural spaces. Floating architectures are expected to save energy effectively, if they use sea water heat, which is known to be clean energy with infinite reserves. To use sea water heat as the heat source and/or heat sink, this study proposes a model in which a sea water heat exchanger is embedded in the concrete structure in the lower part of the floating architecture that is submerged under the sea. Based on the results of performance evaluations of the sea water heat exchanger using CFD (computational fluid dynamics) analysis and mock-up experiments under various conditions, it is found out that the temperature difference between the inlet and outlet of the heat exchanger is in the range of $3.06{\sim}9.57^{\circ}C$, and that the quantity of heat transfer measured is in the range of 3,812~7,180 W. The CFD evaluation results shows a difference of 5% with respect to the results of mock-up experiment.

• Economic and Environmental Geology
• /
• v.24 no.3
• /
• pp.219-226
• /
• 1991

High quality quartz crystals are grown in 0.5N NaOH + LiOH solution on the seed crystal at $370-395^{\circ}C$ and $1200-1300kg/cm^2$ condition. Growth rates are determined by the crystal thickness grown on the seed crystals with Z(0001) and X($11\bar{2}0$) direction. Relatively high growth rate of Z(0001) direction gradually changes as the temperaure difference (${\Delta}$ Ti) between growth and dissolution zones from 25 to $10^{\circ}C$. The X axis direction is affeced by ${\Delta}$ Ti, and +X($11\bar{2}0$) direction shows a high growth rate than -X($\bar{1}\bar{1}20$) direction. According to the variation with kinds of solutions used, the crystal growth that in NaOH solution is found to be slower than that in $Na_2CO_3$ solution. However, for the case in the NaOH solution mixed with LiOH, it shows a favorable growth rate in terms of grown crystal quality.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.40 no.11
• /
• pp.1010-1015
• /
• 2012

In this study, a thin-film thermo-electrochemical cell that directly converts waste thermal energy into electrical energy was fabricated. Electrical conductivity of conducting carbon fiber, which was used as flexible electrode, was increased through coating of carbon nanotube, and resistance of the CNT-coated fiber electrode was not changed even after bending test with various curvatures. Maximum output power of the thermocell was increased quadratically with the temperature difference, and showed a value of about 2.5 mW/kg at temperature difference of $3.4^{\circ}C$. As a result of discharge test for 12 hours, it is confirmed that the cell can operates continuously. And thin-film thermocell wrapped around a pipe with hot liquid flowing within was demonstrated. Internal resistance of the cell was decreased with various curvature of heat pipe, and maximum output power was increased by 30 %. Therefore, the cell can be applied to various heat source.

• Journal of the Korean Solar Energy Society
• /
• v.25 no.4
• /
• pp.37-44
• /
• 2005

An experimental study was conducted to analyze performance of a heating system with variation of control logic of the system. The system uses a solar as heat source and composed with heat pump that uses R-22 as working fluid. The difference between the developed system and the commercially available heating system is working fluid. The solar assisted heating system which was widely distributed in the market uses water as a working fluid. It could be freezing in case of the temperature drops down under freezing point. The anti-freezing fluids such as methyl-alcohol or ethylene-glycol are mixed with the water to protect the freezing phenomena. However, the system developed in this study uses a refrigerant as a working fluid. It makes the system to run under zero degree temperature conditions. Another difference of the developed system compare with commercial available one is auxiliary heating method. The developed system has removed an auxiliary electric heater that has been used in conventional solar assisted heating system. Instead of the auxiliary electric heater, an air source heat exchanger which generally used as an evaporator of a heat pump was adapted as a backup heating device of the developed system. As results, an efficiency of the developed system is higher than a solar assisted heat pump with auxiliary electric heater. The merit of the developed system is on the performance increment when the system operates at a lower solar energy climate conditions. In case of the developed system operates at a normal condition, COP of the solar collector driven heat pump is higher than the air source heat exchanger driven heat pump's.

• Journal of the Korean Association of Geographic Information Studies
• /
• v.13 no.2
• /
• pp.94-106
• /
• 2010

Understanding of the amount of energy resources and site selection are required prior to develop Ocean Thermal Energy (OTE). It is necessary to calculate the appearance probability of difference of seawater temperature(${\Delta}T$) between sea surface layer and underwater layers. This research mainly aimed to calculate the appearance probability of ${\Delta}T$ using frequency analysis(FA) and harmonic analysis(HA), and compare the advantages and weaknesses of those methods which has used in the South Sea of Korea. Spatial scale for comparison of two methods was divided into local and global scales related to the estimation of energy resources amount and site selection. In global scale, the Probability Differences(PD) of calculated ${\Delta}T$ from using both methods were created as spatial distribution maps, and compared areas of PD. In local scale, both methods were compared with not only the results of PD at the region of highest probability but also bimonthly probabilities in the regions of highest and lowest PD. Basically, the strong relationship(pearson r=0.96, ${\alpha}$=0.05) between probabilities of two methods showed the usefulness of both methods. In global scale, the area of PD more than 10% was less than 5% of the whole area, which means both methods can be applied to estimate the amount of OTE resources. However, in practice, HA method was considered as a more pragmatic method due to its capability of calculating under various ${\Delta}T$ conditions. In local scale, there was no significant difference between the high probability areas by both methods, showing difference under 5%. However, while FA could detect the whole range of probability, HA had a disadvantage of inability of detecting probability less than 10%. Therefore it was analyzed that the HA is more suitable to estimate the amount of energy resources, and FA is more suitable to select the site for OTE development.

• International Journal of Highway Engineering
• /
• v.16 no.6
• /
• pp.51-57
• /
• 2014

PURPOSES : An conventional method for electric power generation is converting thermal energy into mechanical energy then to electrical energy. Due to environmental issues such as global warming related with $CO_2$ emission etc., were the limiting factor for the energy resources which resulting in extensive research and novel technologies are required to generate electric power. Thermal energy harvesting using thermoelectric generator is one of energy harvesting technologies due to diverse advantages for new green technology. This paper presents a possibility of application of the thermoelectric generator's application in the direct exchange of waste solar energy into electrical power in road space. METHODS : To measure generated electric power of the thermoelectric generator, data logger was adopted as function of experimental factors such as using cooling sink, connection methods etc. Also, the thermoelectric generator、s behavior at low ambient temperature was investigated as measurement of output voltage vs. elapsed times. RESULTS : A few temperature difference between top an bottom of the thermoelectric generator is generated electric voltage. Components of an electrical circuit can be connected in various ways. The two simplest of these are called series and parallel and occur so open. Series shows slightly better performance in this study. An installation of cooling sink in the thermoelectric generator system was enhanced the output of power voltage. CONCLUSIONS : In this paper, a basic concepts of thermoelectric power generation is presented and applications of the thermoelectric generator to waste solar energy in road is estimated for green energy harvesting technology. The possibility of usage of thermoelectric technology for road facilities was found under the ambient thermal gradient between two surfaces of the thermoelectric module. An experiment results provide a testimony of the feasibility of the proposed environmental energy harvesting technology on the road facilities.

• Journal of Drive and Control
• /
• v.16 no.2
• /
• pp.66-71
• /
• 2019

In this study, flow analysis and dehumidification experiments were performed on hollow fiber membrane module to confirm the dehumidification characteristics for its different configurations. The CFD for the three different models was conducted using $30^{\circ}C$ temperature and 30%RH inlet humidity for quantitative analysis. Each model has different shape parameters i.e. the number of baffles. Comparison between flow analysis results and dehumidification experiment results revealed a percentage error of about 5%. The difference in relative humidity between the inlet and outlet for each model was calculated using flow analysis data. It was established that the difference in relative humidity of the inlet and outlet for the refined model with three baffles was highest among the three modeled modules of hollow fiber membrane module, i.e. around 9%.

• Transactions of the Korean hydrogen and new energy society
• /
• v.28 no.1
• /
• pp.56-62
• /
• 2017

Although most electricity production contributes to air pollution, the vehicle organizations and environmental agency categorizes all EVs as zero-emission vehicles because they produce no direct exhaust or emissions. Currently available EVs have a shorter range per charge than most conventional vehicles have per tank of gas. EVs manufacturers typically target a range of 160 km over on a fully charged battery. The energy efficiency and driving range of EVs varies substantially based on driving conditions and driving habits. Extreme outside temperatures tend to reduce range, because more energy must be used to heat or cool the cabin. High driving speeds reduce range because of the energy required to overcome increased drag. Compared with gradual acceleration, rapid acceleration reduces range. Additional devices significant inclines also reduces range. Based on these driving modes and climate conditions, this paper discusses the performance characteristics of EVs on energy efficiency and driving range. Test vehicles were divided by low / high-speed EVs. The difference of test vehicles are on the vehicle speed and size. Low-speed EVs is a denomination for battery EVs that are legally limited to roads with posted speed limits as high as 72 km/h depending on the particular laws, usually are built to have a top speed of 60 km/h, and have a maximum loaded weight of 1,400 kg. Each vehicle test was performed according to the driving modes and test temperature ($-25^{\circ}C{\sim}35^{\circ}C$). It has a great influence on fuel efficiency amd driving distance according to test temperature conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.28 no.10
• /
• pp.387-393
• /
• 2016

A ground source heat pump system maintains a constant efficiency due to its stable heat source and radiant heat temperature which provide a more effective thermal performance than that of the air source heat pump system. As an eco-friendly renewable energy source, it can reduce electric power and carbon dioxide. In this study, we analyzed one year of data from a web based remote monitoring system to estimate the thermal performance of GSHP with the capacity of 3RT, which is installed in a low energy house located in Daejeon, Korea. This GSHP system is a hybrid system connected to a solar hot water system. Cold and hot water stored in a buffer tank is supplied to six ceiling cassette type fan coil units and a floor panel heating system installed in each room. The results are as follows. First, the GSHP system was operated for ten minutes intermittently in summer in order to decrease the heat load caused by super-insulation. Second, the energy consumption in winter where the system was operated throughout the entire day was 7.5 times higher than that in summer. Moreover, the annual COP of the heating and cooling system was 4.1 in summer and 4.2 in winter, showing little difference. Third, the outlet temperature of the ground heat exchanger in winter decreased from $13^{\circ}C$ in November to $9^{\circ}C$ in February, while that in summer increased from $14^{\circ}C$ to $17^{\circ}C$ showing that the temperature change in winter is greater than that in summer.