[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5229/JKES.2008.11.4.227

Equilibrium Thermodynamics of Chemical Reaction Coupled with Other Interfacial Reactions Such as Charge Transfer by Electron, Colligative Dissolution and Fine Dispersion: A Focus on Distinction between Chemical and Electrochemical Equilibria

Pyun, Su-Il (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Lee, Sung-Jai (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Kim, Ju-Sik (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)

Publication Information

Journal of the Korean Electrochemical Society / v.11, no.4, 2008 , pp. 227-241 More about this Journal

Abstract

This article involves a unified treatment of equilibrium thermodynamics of the chemical reaction coupled with other interfacial (phase boundary) reactions. The modified (restrictive) chemical potential ${\mu}_k^+$ , such as electrochemical potential, hydrostatic-chemical (mechanochemical) potential (exceptionally in the presence of the pressure difference) and surface-chemical potential, was first introduced under the isothermal and isobaric conditions. This article then enlightened the equilibrium conditions in case where the release of chemical energy is counterbalanced by the supply of electrical energy, by the supply of hydrostatic work (exceptionally in the presence of ${\Delta}p$ ), and finally by the release of surface energy, respectively, at constant temperature T and pressure p in terms of the modified chemical potential ${\mu}_k^+$ . Finally, this paper focussed on the difference between chemical and electrochemical equilibria based upon the fundamentals of the isothermal and isobaric equilibrium conditions described above.

Keywords

Modified (restrictive) chemical potential; Hydrostatic-chemical (mechanochemical) potential; Surface-chemical potential; Electrochemical potential; Modified (restrictive) Gibbs free energy;

Citations & Related Records

Reference

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