• 한국재료학회지
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• 제9권7호
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• pp.740-747
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• 1999

결정립 미세화는 강도와 인성을 동시에 향상시킬 수 있는 유일한 방법이다. 제어압연과 가속냉각은 공정 중에 재결정과 결정립 조대화 거동을 조절함으로써 기계적 성질을 향상시키는 효과적인 방법으로 알려져 있으며, 반복열처리에 의한 반복상변태는 결정립 미세화 방법 중의 하나이다. 본 연구에서는 제어압연과 반복열처리를 복합 적용하여 그 효과를 관찰하였다. Mo 첨가효과와 공정변수의 효과를 관찰하기 위해 Mo이 첨가된 저탄소강 시편을 준비하여 Gleeble로 가공열처리 모의실험을 하였다. Mo첨가는 결정립 조대화 온도를 상승시키고, 오스테나이트 재결정을 억제하는 효과를 나타내었다. 오스테나이트 결정립 미세화에 가장 효과적인 공정조건은 반복 열처리 제어압연을 두번 실시하는 것이고, 첫번째보다 두번째 압연율을 더 크게 하는 것이었다

• 한국도로학회논문집
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• 제2권1호
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• pp.147-156
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• 2000

다짐은 포장 공용성에 중요한 영향을 미친다고 알려져 있다. 따라서 이 다짐공정을 포장의 소성변형과 근본적으로 동일하다고 가정하여, 다짐밀도를 롤러다짐수의 항으로 표현하는 이론 모델링식을 정립하였다. 정립된 식의 우수한 데이터 예측능력은 유도과정에 세운 가정들의 검증과 더불어 이 식의 사용 정당화에 대해 확신시켜준다. 유도된 식에 의하면, 대수 밀도 차를 대수 다짐회수의 항으로 그림을 그리면 일차함수의 직선관계식이 주어진다. 그러나 이 직선관계는 공기온도에 의한 냉각과 진동롤러의 진폭과 주기 등의 효과가 존재하면 더 이상 성립되지 않음이 판명된다. 본 연구에서는 이러한 세 요인들에 대한 영향도 함께 연구하여 더 전반적이고 성공가능성을 보여주는 새로운 다짐밀도 식을 제안하였다. 이 제안식을 응용하여 특정다짐공정에 요하는 전체 롤러다짐회수와 최종다짐밀도를 구하는 관계식을 다짐 연구 중 최초로 제시하였다.

• 한국재료학회지
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• 제23권12호
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• pp.708-713
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• 2013

Graphene oxide has been synthesized by microwave-assisted exfoliation of graphite oxide prepared by modified Hummers method. Graphite was oxidized in a solution of $H_2O_2$ and $KMnO_4$ at $65{\sim}80^{\circ}C$, followed by 10 % $H_2O_2$ solution treatment at $80{\sim}90^{\circ}C$. The graphite oxide was exfoliated under microwave irradiation of 1 kW and was reduced to graphene effectively by hydrazine hydrate ($H_4N_2{\cdot}H_2O$) treatment. The exfoliation of graphene oxide was significantly affected by the microwave irradiation on (heating)/off (cooling) period. An on/off period of 10 s/20 s resulted in much more effective exfoliation than that of 5 s/10 s with the same total treatment time of 10 min. This can be explained by the higher exfoliation temperature of 10 s/20 s. Repetition of the graphite oxidation and exfoliation processes also enhanced the exfoliation of graphene oxide. The thickness of the final graphene products was estimated to be several layers. The D band peaks of the Raman spectra of the final graphene products were quite low, suggesting a high crystal quality.

• Journal of Welding and Joining
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• 제17권1호
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• pp.97-103
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• 1999

Ships, structures on the ocean, bridges, and other structures tend to be large by the development of industry. These ultra thick plate were welded with large heat input, which causes welding stresses, deformation and buckling, so it has to be considered the weld design, safety, reliability. The welded residual stresses were produced and redistributed due to the effect of large heat input. The mechanical phenomenon has not been surely identified yet. In spite of the lack of the study on the box column, there are various types of steel frame such as I type, H type, + type and $\bigcirc$ type, used in high story building. In this study, we performed computer simulation with two dimensional heat conduction and plane deformation thermal elasto-plastic finite element computer program as changing the plate thickness to 100mm, 150mm and groove angle to $60^{\circ}C$, $45^{\circ}C$, $30^{\circ}C$ of corner joint in box column. And then, to identify mechanical phenomenon such as the phenomenon of thermal distribution, welding residual stresses and deformation and to decide optimum groove angle and welding condition. The main conclusion can be summarized as follows: 1) Since the groove angle has became cooling down rapidly due to its smaller value, the temperature slope was steeped somewhat. 2) The tensile stress within the welding direction stresses was somewhat decreased at the weld metal and HAZ, increasing of the groove angle. 3) The local stress concentration of the groove angle $60^{\circ}C$ was appeared smaller than groove angle $30^{\circ}$.

• 한국세라믹학회지
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• 제32권12호
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• pp.1323-1330
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• 1995

The effects of various additives on the microstructures of sintered ZnO varistors were examined. Bi2O3, Sb2O3 and Cr2O3 were added to ZnO step by step to identify the effect of each component. The specimens were prepared by sintering at 110$0^{\circ}C$ and 120$0^{\circ}C$ in ambient atmosphere. In ZnO-Bi2O3-Sb2O3 ternary system, decrease of averge grain size due to antimony oxide addition depends on sintering temperature as well as Bi2O3 content. When Sb2O3 was partly or completely replaced by Cr2O3, grain size was further reduced. A significant amount of pyrochlore phase which was not transformed to spinel and Bi2O3-rich liquid phase seemed to remain during sintering at 110$0^{\circ}C$. Unlike ZnO-Bi2O3-Sb2O3 system, the $\alpha$-spinel phase containing significant amount of Cr did not transform to pyrochlore during furnace cooling. Fine spinel particles around 1${\mu}{\textrm}{m}$ size were ovserved within ZnO grains and grain boundaries, which were believed to be responsible for grain-growth inhibition in ZnO-Bi2O3-Sb2O3.

• 한국식품과학회지
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• 제28권3호
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• pp.514-520
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• 1996

감마선 조사기법을 사용하여 새로운 건식공정의 공업용 변성전분 생산 기술개발을 위한 기초연구로서, 시판 옥수수 전분에 직접 감마선을 조사하여 감마선 조사 전분(0-110 kGy)의 이화학적 성질을 검토하였다. 감마선 조사선량이 증가함에 따라 blue value가 직선적으로 감소하였으며, alkali number와 용해도는 크게 증가하였다. $65-95^{\circ}C.$의 온도범위에서 전분용액의 광투과도 또한 감마선 조사선량이 증가함에 따라 현저히 증가하였으며, 물결합능력과 팽윤력은 각각 30 kGy 및 10kGy에서 최대값을 나타내다가 다시 감소하는 경향을 나타내었다. 비조사 전분에 비해 감사선 조사 전분의 호화점도는 현저한 감소 현상을 나타내었다. peak 점도의 경우 7,000 B.U.(비조사 전분)에서 60 B.U.(110kGy)로 그 값이 100배 이상 현저히 감소하였으며 $30^{\circ}C$의 냉각점도도 약 300배 이상 급격한 감소를 나타내었다. 현재 시판중인 산처리 전분은 30kGy의 감마선조사 전분과 유사한 특성을 나타내었으며, 산화전분은 100kGy의 감마선 조사전분과 유사한 성질을 나타내었다.

• Elastomers and Composites
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• 제40권3호
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• pp.212-221
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• 2005

유연사슬길이가 6인 4,4'-bis(6-hydroxy hexoxy)biphenyl (BP-6)의 메소겐 디올을 합성하였고, 이것을 4,4'-diphenylmethane diisocyanate (MDI)와 용액축중합하여 폴리우레탄 (MPU-6)을 합성하였다. 합성된 MPU-6는 $0.23{\sim}0.56 dL/g$의 고유점도를 보였다. MPU-6는 X-ray, 편광현미경으로부터는 액정을 형성할 수 있었으나, DSC로 분석 시에는 액정거동을 관찰할 수 없는 '가상액정'의 거동을 보였다. 또한 MPU-6의 분자량이 낮을수록 결정화 속도와 결정화 온도가 높음을 알 수 있었으며 이는 분자량이 낮을수록 고분자의 mobility가 증가함으로써 메소겐기의 배향이 용이하고, 이것이 기핵으로 작용하였기 때문으로 생각된다.

• 대한건축학회논문집:계획계
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• 제35권6호
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• pp.27-37
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• 2019

This study focused on the possibility of reducing the cooling load through the change of micro climate in the outdoor space during summer season. This study proposes an efficient planning model by comparing the effects of urban heat island mitigation through wind path planning, outdoor space vegetation, and exterior material change by using the basic model of the street-oriented block housing proposed in the previous research by the same author. As a result, the most effective wind path planning strategy in the street-oriented block housing was the change of the air flow through the mass height adjustment. When the tall building masses were staggered and arranged in a balanced manner, the overall wind environment could be improved. The greater the height difference between low and high masses, the better the air flow was shown. It was also important to arrange the building masses so that the inlet of the main wind was open and to allow the external space to connect to the adjacent block to create a continuous flow. The change of outdoor space vegetation and flooring, and the formation of wind paths through the opening of lower part also showed the effect of heat island reduction. In addition, the change of PMV in summer was the biggest influence of shadow by tall building mass. Attention should be paid to the fact that high-albedo exterior materials are adversely affected by multiple reflections in dense street-oriented block housing. The use of albedo of the exterior material showed that it is necessary to pay attention to apply in the high density block housing. This is attributed to the rise of the temperature due to the absorption of energy into the low-albedo flooring, where the high-albedo exterior causes multiple reflections.

• 대한금속재료학회지
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• 제47권1호
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• pp.13-20
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• 2009

This work presents functionally graded coatings (FGC) of hydroxyapatite (HA) and metallic powders on Ti-6Al-4V implants using plasma spray coating method. HA has been the most frequently used coating material due to its excellent compatibility with human bones. However, because of the abrupt changes in thermomechanical properties between HA and the metallic implant across an interface, and residual stress induced on cooling from coating temperture to room temperature, debonding at the interface occurs in use sometimes. In this work, FGC of HA and Ti or Ti-alloy powders is made to mitigate the abrupt property changes at the interface and the effect of FGC on residual stress release is investigated by evaluating the mechanical bond strength between the implant and the HA coating layers. Thermal annealing is done after coating in order to crystallize the HA coating layer which tends to have amorphous structure during thermal spray coating. The effects of types and compositional ratio of metallic powders in FGC and annealing conditions on the bond strength are also evaluated by strength tests and the microstructure analysis of coating layers and interfaces. Finally, biocompatibility of the coating layers are tested under ISO 10993-5.

• Nuclear Engineering and Technology
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• 제55권6호
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• pp.2315-2324
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• 2023

Space nuclear reactors are becoming popular in deep space exploration owing to their advantages of high-power density and stability. Following the fourth-generation nuclear reactor technology, a conceptual design of the dual drum-controlled space molten salt reactor (D²-SMSR) is proposed. The reactor concept uses molten salt as fuel and heat pipes for cooling. A new reactivity control strategy that combines control drums and safety drums was adopted. Critical physical characteristics such as neutron energy spectrum, neutron flux distribution, power distribution and burnup depth were calculated. Flow and heat transfer characteristics such as natural convection, velocity and temperature distribution of the D²-SMSR under low gravity conditions were analyzed. The reactivity control effect of the dual-drums strategy was evaluated. Results showed that the D²-SMSR with a fast spectrum could operate for 10 years at the full power of 40 kWth. The D²-SMSR has a high heat transfer coefficient between molten salt and heat pipe, which means that the core has a good heat-exchange performance. The new reactivity control strategy can achieve shutdown with one safety drum or three control drums, ensuring high-security standards. The present study can provide a theoretical reference for the design of space nuclear reactors.