• 멤브레인
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• 제26권1호
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• pp.76-85
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• 2016

반도체 및 디스플레이 공정에서 배출되는 $N_2/NF_3$ 혼합 가스 분리를 위한 폴리썰폰 중공사막 제조 연구를 수행하였다. 먼저 non-solvent induced phase separation (NIPS)와 vapor induced phase separation (VIPS) 혼합 공정을 이용하여 기체투과성이 높은 고분자 중공사막을 제조하였다. 제조된 중공사막 표면에 PDMS(polydimethylsiloxiane)와 Teflon AF1600(R) 고분자 소재를 이용하여 얇은 박막을 추가적으로 코팅하는 방법으로 기체 분리막을 완성하였다. 제조된 분리막은 코팅된 고분자 소재의 기체 분리 특성에 따라 상이한 $N_2/NF_3$ 분리 성능을 보여주었다. 특히 Teflon AF1600(R) 이 코팅된 중공사막의 경우 $N_2/NF_3$ 분리 성능(> 14)을 보여주었고, $N_2$ 투과도는 4.5 GPU를 나타내었다. 상용 폴리썰폰 막과 비교해 볼 때, 투과도는 약간 감소하였지만 기체 선택도는 크게 증가하였다. 이런 특징은 $N_2/NF_3$를 분리하는 분리막 구조로써 큰 가능성을 지니는 것으로 판단된다.

• 한국응용과학기술학회지
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• 제31권2호
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• pp.183-189
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• 2014

내화성 및 내화학성이 우수한 현무암사의 표면에 회분식 방법에 의한 테프론 코팅 연구의 결과를 토대로 연속식 코팅 공정 인자를 도출하기 위한 연구를 수행하였다. 현무암사를 7,5 wt% 트리에톡시트리플루오로실란(TMTFPS)으로 연속적으로 전처리 한 후, 침투제로 0.25 wt% bis(2-ethylhexyl)sulfo succinate (DOS-Na)가 함유된 20 wt% 테프론 수분산액으로 딥 코팅한 후 2 m의 $120^{\circ}C$ 건조 챔버에서 12 m/mim의 속도로 건조한 후 2 m의 $380^{\circ}C$ 소성 챔버에서 40초간 소성하여 최종 $3.4g_f/D$의 인장 강도와 $2.3g_f/D$의 루프강도를 가지는 테프론이 코팅된 고내열 재봉사용 현무암사를 제조하였다.

• Transactions on Electrical and Electronic Materials
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• 제8권1호
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• pp.15-20
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• 2007

Conditioner wear, copper polish rates, pad temperature and coefficient of friction (COF) are measured for two novel Mitsubishi Materials Corporation designs during an extended wear and polishing test. Both designs are coated with a $Teflon^{TM}$ film to reduce substrate wear and chemical attack. Using optical interferometry, changes in the coating that result in gradual changes in diamond exposure are measured. Theories of the COF, conditioning, and polishing are applied to explain the observed performance differences between the designs.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2001년도 제33회 춘계학술대회 개최
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• pp.149-155
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• 2001

New semi-fluorinated polyol esters were synthesized by condensation reaction of polyols (NPG and TMP) and carboxylic acids such as 2-ethylhexanoic acid, stearic acid and perfluorooctanoic acid. The structures of polyol esters were confirmed by FT-IR and H-NMR etc. And, the fluorinated polyol esters were insoluble in several oils, however, the semi-fluorinated polyol esters were soluble in several oils depended on the structure of polyol esters. The physical properties such as 4-ball wear property and extreme-pressure (EP) properties were characterized by measuring wear scar diameter through ASTM D2266 and by determining the load-carrying through ASTM D2783 method, respectively. As the results, wear scar diameters of oils in which the semi-fluorinated polyol esters were added were not changed compared to those of not added oils. While extreme-pressure properties remarkably Increased with fluorine contents of the esters depended on the structure of acid moiety and polyol moiety. Also, the extreme-pressure property of semi-fluorinated NPG polyol ester in gasoline engine oil was better than that of commercial Teflon coating additive.

• 대한치과보철학회지
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• 제44권2호
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• pp.229-242
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• 2006

Statement of problem: In order to increase preload with reducing the friction coefficient, abutment screws coated with pure gold and Teflon as dry lubricant coatings have been introduced. But the reported data indicate that if screw repeated tightening and loosening cycle, an efficiency of increasing preload was decreased by screw surface wearing off. Purpose: This study was to evaluate the influence of tungsten carbide/carbon coating, which has superior hardness and frictional wear resistance, on the preload of abutment screws and the stability of coating surface after repeated closures. Material and method: The rotational values of abutment screws and the compressive forces between abutment and fixture were measured in implant systems with three different joint connections, one external butt joint and two internal cones. Moreover the stability and the alteration of coating surface were examined by comparison of the compressive force and the removable torque values during 10 consecutive trials, observation with scanning electron microscope and analyzed the elemental composition with energy dispersive x-ray spectroscopy Results and conclusion: 1. Application of coating resulted in significant increase of compressive force in all implant systems(P<.05). The increasing rate of compressive force by coating in external butt joint was gloater than those in internal cones (P<.05). 2. Coated screw showed the significant additional rotation compared to non-coated screw in all implant systems (P<.05). There were no significant differences in the increasing rate of rotation among implant systems (P>.05). 3. Removable torque values were greater with non-coated screw than that with coated screw (P<.05). 4. Coated screw showed insignificant variations in the compressive forces during 10 consecutive trials(P>.05) 5. After repeated trials, the surface layer of coated screw was maintained relatively well. However surface wearing and irregular titanium fragments were found in non-coated screw.

• The Journal of Advanced Prosthodontics
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• 제6권6호
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• pp.434-443
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• 2014

PURPOSE. The purpose of this study was to evaluate and compare the effects of different surface pretreatment techniques on the surface roughness and shear bond strength of a new self-adhering flowable composite resin for use with lithium disilicate-reinforced CAD/CAM ceramic material. MATERIALS AND METHODS. A total of one hundred thirty lithium disilicate CAD/CAM ceramic plates with dimensions of $6mm{\times}4mm$ and 3 mm thick were prepared. Specimens were then assigned into five groups (n=26) as follows: untreated control, coating with $30{\mu}m$ silica oxide particles ($Cojet^{TM}$ Sand), 9.6% hydrofluoric acid etching, Er:YAG laser irradiation, and grinding with a high-speed fine diamond bur. A self-adhering flowable composite resin (Vertise Flow) was applied onto the pre-treated ceramic plates using the Ultradent shear bond Teflon mold system. Surface roughness was measured by atomic force microscopy. Shear bond strength test were performed using a universal testing machine at a crosshead speed of 1 mm/min. Surface roughness data were analyzed by one-way ANOVA and the Tukey HSD tests. Shear bond strength test values were analyzed by Kruskal-Wallis and Mann-Whitney U tests at ${\alpha}=.05$. RESULTS. Hydrofluoric acid etching and grinding with high-speed fine diamond bur produced significantly higher surface roughness than the other pretreatment groups (P<.05). Hydrofluoric acid etching and silica coating yielded the highest shear bond strength values (P<.001). CONCLUSION. Self-adhering flowable composite resin used as repair composite resin exhibited very low bond strength irrespective of the surface pretreatments used.

• 한국구조물진단유지관리공학회 논문집
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• 제22권4호
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• pp.68-75
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• 2018

기존의 정수처리 방법으로는 제거되지 않는 물질이 발생함에 고도정수 처리 시설의 도입이 증가하고 있다. 그러나 오존을 이용한 고도정수처리 시설의 내부 방수 방식재는 오존의 산화력에 의해 열화되며 콘크리트까지 영향을 미쳐 내구성 저하의 원인이 된다. 본 연구에서는 내오존성 및 내화학성이 뛰어난 금속 패널을 기존의 시공법 보다 손쉬운 방법으로 시공하기 위한 방법으로 금속용사 공법을 이용하여 수처리 시설 콘크리트 구조물의 열화를 원천적으로 방지하기 위한 마감공법 개발 연구의 일원으로 용사금속 종류 및 피막의 표면처리 방법에 따른 내오존성 평가를 실시하였으며, 오존처리 후의 부착강도를 평가하였다. 실험결과 용사금속 Ti이 용사 후에도 내오존성이 뛰어난 것으로 나타났으며 표면처리 방법으로는 테프론계 봉공처리제를 사용하여 마감하는 것이 내오존성 및 부착성능 확보에 가장 적합한 방법이라 판단된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.365-365
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• 2010

Similar to the superhydrophobic surfaces of lotus leaf, water strider leg is attributed to hierarchical structure of micro pillar and nano-hair coated with low surface energy materials, by which water strider can run and even jump on the water surface. In order to mimick its leg, many effort, especially, on the fabrication of nanohairs has been made using several methods such as a capillarity-driven molding and lithography using poly(urethane acrylate)(PUA). However most of those effort was not so effective to create the similar structure due to its difficulty in the fabrication of nanoscale hairy structures with hydrophobic surface. In this study, we have selected a low surface energy polymeric material of polytetrafluoroethylene (PTFE, or Teflon) assisted with surface modification of CF4 plasma treatment followed by hydrophobic surface coating with pre-cursor of hexamethyldisiloxane (HMDSO) using a plasma enhanced chemical vapor deposition (PE-CVD). It was found that the plasma energy and duration of CF4 treatment on PTFE polymer could control the aspect ratio of nano-hairy structure, which varying with high aspect ratio of more than 20 to 1, or height of over 1000nm but width of 50nm in average. The water contact angle on pristine PTFE surface was measured as approximately $115^{\circ}$. With nanostructures by CF4 plasma treatment and hydrophobic coating of HMDSO film, we made a superhydrophobic nano-hair structure with the wetting angle of over $160^{\circ}C$. This novel fabrication method of nanohairy structures has been applied not only on 2-D flat substrate but also on 3-D substrates like wire and cylinder, which is similarly mimicked the water strider's leg.

• Tribology and Lubricants
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• 제32권6호
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• pp.201-206
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• 2016

In this study, we attempt to produce a semi-elliptical riblet with a shark skin-like surface using wire electrical discharge machining (WEDM) and micro molding techniques. Our design for the production of the semi-elliptical mold includes an electrode, a winding roller, and a guide on the WEDM system. A replication mold with negative riblets is machined using WEDM, and a shark skin inspired surface with positive riblets is fabricated using a micro molding technique. For a comparison with the original shark skin, a shark skin replica is also produced using the micro molding technique directly from a shark skin template. Droplet contact angles on a flat surface, the shark skin replica, and the epoxy resin-based micro riblet shark skin-like surface are evaluated. The effect of a Teflon coating on the contact angles for the three different surfaces is also investigated. The results show the micro riblet with a shark skin-like surface has a similar contact angle as the shark skin replica, which means that the simplified riblet shark skin surface strongly influences the performance of wettability. This study confirms the effectiveness of using the WEDM method to prepare hydrophobic surfaces with diverse surface patterns.

• Tribology and Lubricants
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• 제35권2호
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• pp.94-98
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• 2019

The riblet structure like shark skin has been widely studied owing to its drag reduction and anti-fouling properties. In this study we simulated the wettability of an oil droplet on a riblet surface. We developed a numerical analysis method using the Wenzel equation and Cassie-Baxter equation that can estimate the contact angle with a penetrated depth of the droplet on rough surfaces. Riblet surfaces with nine scales composed of five hemi-elliptical ribs are generated numerically. The variation of contact angles with fractional depth of penetration for the generated riblet surfaces with and without coatings is demonstrated in the condition of solid-air-oil and solid-water-oil interfaces. The contact angle for the uncoated surface decreases with increasing fractional depth of penetration more drastically than that for the coated surface. For the effect of surface roughness on the contact angle of the droplet, the oleophilic surface gives lower contact angle when the surface is rougher, whereas the oleoophobic surface gives higher contact angle with higher roughness To verify the analysis results, the wetting angle was measured in the solid-air-oil interface and solid-water-oil interface for the shark-skin template and shark-skin replica. The effects of teflon coating were also evaluated. It is shown that the simulation results cover the experimental ones.