• Corrosion Science and Technology
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• 제18권5호
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• pp.155-167
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• 2019

In this study, two novel Schiff base compounds including (3-(4-Chlorophenyl isoxazole-5-yl) methanol and (3-(2,4 dichlorophenol isoxazole-5-yl) methanol as corrosion inhibitors for mild steel in 1 M hydrochloric acid solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and density functional theory (DFT) computations. The results showed that the corrosion inhibition efficiency (IE) is remarkably enhanced with the growing concentration of the Schiff base inhibitors. The results from Tafel polarization and EIS methods showed that IE decreases with gradual increments of temperature. This process can be attributed to the displacement of the adsorption/desorption balance and hence to the diminution of the level of a surface coating. Also, the adsorption of two inhibitors over mild steel followed the Langmuir adsorption isotherm. Too, the results of the scanning electron microscope (SEM) images showed that the Schiff base inhibitors form an excellent protective film over mild steel and verified the results by electrochemical techniques. Additionally, the results from the experimental and those from DFT computations are in excellent accordance.

• Corrosion Science and Technology
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• 제20권5호
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

• 한국표면공학회지
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• 제54권6호
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• pp.315-323
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• 2021

In general, surface treatments of electroless Ni-P coating are extensively applied in the industry due to their excellent properties for considerable wear resistance, hardness, corrosion resistance. This study aims to determine the effect of ultrasonic conditions on the morphology, alumina content, roughness, hardness, and corrosion resistance of electroless Ni-P-Al₂O₃ composite coatings. The characteristics were analyzed by Energy-dispersive X-ray spectroscopy (EDX), x-ray diffractions (XRD), and atomic force microscopy (AFM), etc. In this study, the effect of ultrasonic condition uniformly distributed alumina within Ni-P solution resulting in a smoother surface, lower surface roughness. Furthermore, the corrosion resistance behavior of the coating was analyzed using tafel polarization curves in a 3.5 wt.% NaCl solution at 25 ℃. Under ultrasonic, Al₂O₃ content in Ni-P composite solution increased from 0.5 to 5.0 g/L, Al₂O₃ content at 3.0 g/L was showed a significantly enhanced corrosion resistance. These results suggested that ultrasonic condition was an effective method to improve the properties of the composite coating.

• 한국표면공학회지
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• 제52권1호
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• pp.23-29
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• 2019

Electrolytic corrosion of the ship's hull can be occurred due to stray current during welding work using shore power and electrical leakage using shore power supply. The electrolytic corrosion characteristics were investigated for Al5083-H321 through potentiodynamic polarization and galvanostatic corrosion test in natural seawater. Experiments of electrolytic corrosion were tested at various current densities ranging from $0.01mA/cm^2$ to $10mA/cm^2$ for 30 minutes, and at various applied time ranging from 60 to 240 minutes. Evaluation of electrolytic corrosion was carried out by Tafel extrapolation, weight loss, surface analysis after the experiment. In the electrolytic corrosion characteristics of Al5083-H321 as the current density increased, the surface damage tended to proportionally increase. In the current density of $0.01mA/cm^2$ for a applied long time, the damage tended to grow on the surface. In the case of $10mA/cm^2$ current density for a applied long time, the damage progressed to the depth direction of the surface, and the amount of weight loss per hour increased to 4 mg/hr.

• Corrosion Science and Technology
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• 제20권2호
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• pp.85-93
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• 2021

The corrosion damage of materials in marine environment mainly occurs by Cl^- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

• Computers and Concrete
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• 제27권4호
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• pp.385-393
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• 2021

Reinforcement corrosion is the main cause of the durability failure of reinforced concrete (RC) structure. In this paper, a three-dimensional (3D) numerical model of macro-cell corrosion is established to reveal the corrosion mechanisms of steel reinforcement in RC structure. Modified Direct Iteration Method (MDIM) is employed to solve the system of partial differential equations for reinforcement corrosion. Through the sensitivity analysis of electrochemical parameters, it is found that the average corrosion current density is more sensitive to the change of cathodic Tafel slope and anodic equilibrium potential, compared with the other electrochemical parameters. Furthermore, both the anode-to-cathode (A/C) ratio and the anodic length have significant influences on the average corrosion current density, especially when A/C ratio is less than 0.5 and anodic length is less than 35 mm. More importantly, it is demonstrated that the corrosion rate of semi-circumferential corrosion is much larger than that of circumferential corrosion for the same A/C ratio value. The simulation results can give a unique insight into understanding the detailed electrochemical corrosion processes of steel reinforcement in RC structure for application in service life prediction of RC structures in actual civil engineer.

• Corrosion Science and Technology
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• 제19권6호
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• pp.310-317
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• 2020

This study investigated the damage to the specimen due to liquid droplet impingement erosion corrosion, which improved the corrosion resistance and durability via hard anodization of 5083-H321 aluminum alloy, which is widely used for small ships and marine structures. The experiment combined liquid droplet impingement erosion and electrochemical equipment with the flow rates in natural seawater solution. Subsequently, Tafel extrapolation of polarization curves was performed to evaluate damage due to the liquid droplet impingement erosion corrosion. The damaged surface was observed using a 3D microscope and a scanning electron microscope. The degree of pitting damage was measured using the Image J program, and the surface hardness was measured using the micro-Vickers hardness tester. The corrosion current density, area, depth, and ratio of the damaged areas increased with the increase in flow rate. The grain size of the damaged area at a flow rate of 20 m s-1 showed fewer and minor differences in height, and a smooth curved shape. The hardness of the damaged surface tended to decrease with increase in flow rate.

• Corrosion Science and Technology
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• 제21권1호
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• pp.32-40
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• 2022

The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as E_HOMO, E_LUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

• Corrosion Science and Technology
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• 제20권6호
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• pp.347-360
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• 2021

Currently, the demand for eco-friendly energy sources is high, which has prompted research on polymer electrolyte membrane fuel cells. Both aluminum alloys and nickel alloys, which are commonly considered as materials of bipolar plates in fuel cells, oxide layers formed on the metal surface have excellent corrosion resistance. In this research, the electrochemical characteristics of 6061-T6 aluminum alloy and Inconel 600 were investigated with chloride concentrations in an acid environment that simulated the cathode condition of the PEMFC. After potentiodynamic polarization experiments, Tafel analysis and surface analysis were performed. Inconel 600 presented remarkably good corrosion resistance under all test conditions. The corrosion current density of 6061-T6 aluminum alloy was significantly higher than that of Inconel 600 under all test conditions. Also, 6061-T6 aluminum alloy and Inconel 600 presented uniform corrosion and intergranular corrosion, respectively. The Ni, Cr, and Fe, which are the main chemical compositions of Inconel 600, are higher than Al in the electromotive force series. And a double oxide film of NiO-Cr₂O₃, which is more stable than Al₂O₃, is formed. Thus, the corrosion resistance of Inconel 600 is better.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.663-668
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• 2021

For the development of highly efficient quantum dot-sensitized solar cells (QDSCs), it is important to enhance the electrocatalytic activity of the counter electrodes (CEs). Herein, a fabrication process of Cu₂S CEs are optimized for the development highly efficient QDSCs. The surface of brass film is treated with HCl solution to prepare the Cu₂S CEs, and the concentraion as well as the temperature of HCl solution are controlled. It is found that the uniformity for the thickness of prepared Cu₂S CEs is enhanced when the diluted HCl solution is used, compared to the HCl solution of standard concentration. In addition, the electrocatalytic activity of the Cu₂S CEs is also increased with the modificed process, which is confirmed by impedance data and Tafel polarization curves. As a result, the photoconversion efficiency of QDSCs is improved from 4.49% up to 5.73%, when the concentraion and temperature of the HCl treatment are efficiently optimized.