• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.11
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• pp.5376-5383
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• 2011

The objective of this study is the development of carbon-recycle technology, that converts carbon dioxide captured from flue gas to carbon monoxide or carbon for reuse in industrial fields. It is difficult to decompose $CO_2$ because $CO_2$ is very stable molecule. And then metal oxide was used as an activation agent or catalyst for the decomposition of $CO_2$ at low temperature. Metal oxides, which converts $CO_2$ to CO or C, were prepared using Ni-ferrite by solid state method and hydrothermal synthesis in this study. TPR/TPO and TGA were used as an analysis method to analyze the decomposition characteristics of $CO_2$. As the results, the reduction area of $H_2$ was high value at 15 wt% of NiO and the decomposition area of $CO_2$ was superior capacity at 5 wt% of NiO. However, TGA data showed contrary results that reduction area of $H_2$ was 28.47wt% and oxidation area by $CO_2$ was 26.95wt% at 2.5 wt% of NiO, one of the Ni-ferrite powders synthesized using solid state method. $CO_2$ decomposition efficiency was 94.66% and it is excellent results in comparison with previous studies.

• Clean Technology
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• v.16 no.2
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• pp.132-139
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• 2010

The Cu-Mn mixed oxide catalysts with different molar ratios of Cu/(Cu+Mn) prepared by co-precipitation method have been investigated in CO oxidation at $30^{\circ}C$. The catalysts used in this study were characterized by X-ray Diffraction (XRD), $N_2$ sorption, X-ray photoelectron spectroscopy (XPS), and $H_2$-temperature programmed reduction $(H_2-TPR)$ to correlate with catalytic activities in CO oxidation. The $N_2$ adsorption-desorption isotherms of Cu-Mn mixed oxide catalysts showed a type 4 having pore range of 7-20 nm and BET surface area was increased from 17 to $205\;m^2{\cdot}g^{-1}$ with increasing of Mn content. The XPS analysis showed the surface oxidation state of Cu and Mn represented $Cu^{2+}$and the mixture of $Mn^{3+}$ and $Mn^{4+}$, respectively. Among the catalysts studied here, Cu/(Cu+Mn) = 0.5 catalyst showed the highest activity at $30^{\circ}C$ in CO oxidation and the catalytic activity showed a typical volcano-shape curve with respect to Cu/(Cu+Mn) molar ratios. The water vapor showed a prohibiting effect on the efficiency of the catalyst which is due to the competitive adsorption of carbon monoxide on the active sites of catalyst surface and finally the formation of hydroxyl group with active metals.

• Communications for Statistical Applications and Methods
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• v.20 no.3
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• pp.169-174
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• 2013

The ROC curve is drawn with two conditional cumulative distribution functions (or survival functions) of the univariate random variable. In this work, we consider joint cumulative distribution functions of k random variables, and suggest a ROC curve for multivariate random variables. With regard to the values on the line, which passes through two mean vectors of dichotomous states, a joint cumulative distribution function can be regarded as a function of the univariate variable. After this function is modified to satisfy the properties of the cumulative distribution function, a ROC curve might be derived; moreover, some illustrative examples are demonstrated.

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.108-114
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• 2020

In this study, NH₃-selective catalytic oxidation (SCO) efficiencies according to calcination/reduction conditions were compared when preparing various Ru[1]/TiO₂ catalysts. The Ru[1]/TiO₂ red catalyst had better NH₃ conversion and NH₃ to N₂ conversion than those of Ru[1]/TiO₂ cal. Physico-chemical properties of Ru[1]/TiO₂ catalysts were confirmed by Brunauer Emmett Teller (BET), X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and temperature programmed reduction (H₂-TPR) analyses, and the properties were shown to affect the dispersion and surface adsorption oxygen species (O_β) ratio of the active metal.

• Clean Technology
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• v.19 no.2
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• pp.128-133
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• 2013

Catalytic combustion of benzene over $CeO_2$-supported copper oxides has been investigated. The supported copper oxides catalysts were prepared using ball mill method and characterized by XRD, FT-IR, TEM and TPR. In the CuO/$CeO_2$ catalysts prepared using ball mill method, highly dispersed copper oxide species were shown at high loading ratio. The CuO/$CeO_2$ prepared using ball mill method showed the higher activity than those prepared using impregnation method. The catalytic activity increased with an increase in the CuO loading ratio, 10 wt% loaded CuO/$CeO_2$ catalyst giving the highest activity. In addition, the promoting of 10 wt% loaded CuO/$CeO_2$ catalyst with $Fe_2O_3$ and CoO enhanced the dispersion of CuO and then increased the catalytic activity.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.43 no.4 s.346
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• pp.67-74
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• 2006

We present the design of a radiometer in W-band which operates simultaneously with a single antenna configured FMCW radar. We choose a total power radiometer(TPR) which shares an antenna and a front-end with the radar for miniaturizing the system. We separate the radiometer signal from the radar signal using a diplexer in IF band. Because the radiometer has an unwanted transmitter section due to the common use of the MMW front-end with the radar, some additional noise signals caused by the transmitter degrade the sensitivity of the radiometer system. To compensate the degradation of sensitivity, we use matching circuits and a diode detector configured as the voltage doubler. Through some experiments, we have verified that the designed radiometer system has good performances in detecting metal targets tying at several hundred meters.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.21-30
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• 2006

[ $M/Fe_2O_3$ ] (M=Rh, Ce and Zr) mixed oxides were prepared using urea method to develop a medium for chemical hydrogen storage by their redox cycles. And their redox behaviors by repeated cycles were studied using temperature programmed reaction(TPR) technique. Additives such as Rh, Ce and Zr were added to iron oxides in order to lower the reaction temperature for reduction by hydrogen and re-oxidation by water-splitting. From the results, concentration of urea used as a precipitant had little effect on particle size and reduction property of iron oxide. TPR patterns of iron oxide consisted of two reduction peaks due to the course of $Fe_2O_3\;{\rightarrow}\;Fe_3O_4\;{\rightarrow}\;Fe$. The results of repeated redox tests showed that Rh added to iron oxide have an effect on lowering the re-oxidation temperature by water-splitting. Meanwhile, Ce and Zr additives played an important role in prevention of deactivation by repeated cycles. Finally, Fe-oxide(Rh, Ce, Zr) sample added with Rh, Ce and Zr showed the lowest re-oxidation temperature by water-splitting and maintained high $H_2$ recovery in spite of the repeated redox cycles. Consequently, it is expected that Fe-oxide(Rh, Ce, Zr) sample can be a feasible medium for chemical hydrogen storage using redox cycle of iron oxide.

• Journal of the Korea Institute of Information Security & Cryptology
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• v.28 no.5
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• pp.1197-1207
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• 2018

PowerShell is command line shell and scripting language, built on the .NET framework, and it has several advantages as an attack tool, including built-in support for Windows, easy code concealment and persistence, and various pen-test frameworks. Accordingly, malwares using PowerShell are increasing rapidly, however, there is a limit to cope with the conventional malware detection technique. In this paper, we propose an improved monitoring method to observe commands executed in the PowerShell and a deep learning based malware classification model that extract features from commands using Convolutional Neural Network(CNN) and send them to Recurrent Neural Network(RNN) according to the order of execution. As a result of testing the proposed model with 5-fold cross validation using 1,916 PowerShell-based malwares collected at malware sharing site and 38,148 benign scripts disclosed by an obfuscation detection study, it shows that the model effectively detects malwares with about 97% True Positive Rate(TPR) and 1% False Positive Rate(FPR).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.900-905
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• 2015

DeNOx catalysts composed of Mn, Cu and $TiO_2$ were prepared and tested for $NH_3$-SCR. The performance of each catalyst was studied for the NOx removal efficiency while changing the calcination temperature, reaction time, and oxygen concentration. The hydrogen conversion efficiency of a calcined catalyst was measured at the $H_2$-TPR system. The change in the specific surface area of catalyst according to the calcination temperature was analyzed. As a result, the proper calcination temperature was approximately $300^{\circ}C$. If the calcination temperature is increased to $500^{\circ}C$, the NOx removal efficiency of Mn and Cu constituents is largely decreased at the low temperature range. Oxygen in flue gas is an important parameter in the SCR reaction and optimal oxygen concentration is approximately 8 vol.%.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.12
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• pp.6575-6580
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• 2013

Various modified SCR catalysts were prepared and tested to improve the strength of catalysts for use under severe conditions. The SCR catalysts were modified with a binder and dispersion agent, and tested at the fixed bed reactor. FT-IR and $H_2$-TPR were used to analyze the degree of hydrogen use and ammonia adsorption by the modified catalysts. In the case of the SCR catalysts coated with 2.3g of the binder, 4.7g of ethanol, and 0.1g of dispersion agent, the strength of catalyst was increased by approximately 12%. On the other hand, despite the enhancement of strength, the activities of the SCR catalysts were decreased by 2-10%. When the mixed solution composed of binder, dispersion agent and $SiO_2$ solution was precipitated on the catalyst, the $NO_x$ conversion of the catalyst was decreased slightly. The Bronsted acid site and Lewis acid site worked as the activators for the SCR reaction, and were decreased by $SiO_2$.