• Economic and Environmental Geology
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• v.55 no.5
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• pp.511-519
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• 2022

In order to develop an air-stripping based remediation process to remove the TOC (Total Organic Carbon) in groundwater around the underground LPG storage cavern, the laboratory scale experiments at various conditions (change of air injection volume and temperature, the application of ultrasonic treatment, etc.) for two types of groundwater (initial TOC concentration of 608 mg/L and 153 mg/L, respectively). From results of experiment, as the air injection rate for stripping into groundwater increased from 2 L/min to 11 L/min and as the air-stripping time increased from 1 hour to 24 hour, the TOC removal efficiency of air-stripping increased. However, the TOC concentration of treated groundwater was higher than the discharge tolerance limit (100 mg/L) even after 24 hour stripping at the maximum air injection rate of 11 L/min. The main compounds of the TOC in groundwater were identified as methanol and propane and the long stripping time (more than 24 hour) was needed to separate the methanol from groundwater because of the affinity between water and methanol. At 20℃ and 4 L/min of air injection, the TOC removal efficiency increased to 59.1% after 24 hour air-stripping. When the temperature of groundwater increased to 30℃ and 40℃, the TOC removal efficiency increased up to 80.0% and 82.8%, suggesting that more than 24 hour air-stripping at 40℃ is needed to lower the TOC concentration to below 100 mg/L and the additional TOC removal process as well as the air-stripping is necessary. When the temperature increased to 60℃ and the ultrasonic treatment was conjugated with the air-stripping, the TOC removal efficiency increased to 87.8% within 5 hour stripping and the final TOC concentration (72.4 mg/L) was satisfied with the TOC discharge tolerance limit. The TOC removal efficiency for groundwater having low TOC concentration (153 mg/L) also showed similar removal efficiency of 89.7% (the final TOC concentration: 18.9 mg/L). Results in this study supported that the air-stripping conjugated with the ultrasonic treatment could remove successfully the TOC in groundwater around the underground LPG strorage cavern.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.413-416
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• 2004

TOC(total organic carbon)분석은 폐수 및 강수의 오염특성을 평가하기 위한 도구로서 BOD(biochemical oxygen demand), COD(chemical oxygen demand) 와 함께 사용되어 왔다. TOC 측정시간은 10분 정도로 BOD(5～6일), COD(2～3시간)에 비해 아주 짧은 시간에 측정할 수가 있으며, 전처리과정이 단순하고 정확도도 높은 것으로 알려져 있다. 본 연구는 지하수의 잠재오염성을 밝혀내기 위한 도구로 TOC를 활용하여 신뢰성 있는 분석 값을 얻기 위해서 시료의 채취, 보관, 측정까지의 최적 조건을 도출하는데 목적을 두었다. 아울러 시료 채취 후 일정 경과 시간에 따른 TOC의 변화를 관찰하였다. 시료채취 용기, 채취 후 산성화, 보관방법 및 기간에 대한 실험 결과, 대상 변수에 따라서 TOC의 농도변화에 커다란 차이점을 볼 수 있었다. TOC 농도가 낮은 지하수시료의 측정에서는 빛을 차단시킨 불투명 유리병을 사용해야만 하고 채취 즉시 산도를 높여(pH<2)주며 4$^{\circ}C$ 이하에서 보관하여야 한다. 지하수중 TOC 측정시료는 가능한 보관 기간에 있어서 채수 후 24시간 이내에 측정하는 것이 좋으나 1) 본 연구에서는 채취현장과의 거리를 고려하면 현실적으로 불가능하므로 기간에 따른 TOC 변화를 30일까지 측정, 조사하였다.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.731-739
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• 2007

In this study, water quality monitoring focused on TOC was performed at 5 points in Mihocheon (Stream) from January to December 2006. And 10 parameters (water temperature, pH, DO, EC, turbidity, SS, BOD, $PO_4-P$, TOC, TN) were monitored every month for one year. According to this study, TOC increased towards the lower stream (#4~#5). Correlation coefficients between TOC and DO, EC, turbidity, SS, BOD, $PO_4-P$, TN were -0.126, 0.351, 0.320, 0.286, 0.711, 0.525, 0.666. TOC was highly related to BOD. As a result of linear regression analysis, regression equation between BOD and TOC was BOD=0.58TOC+1.90 ($R^2=0.506$). In Mihocheon (Stream), BOD/TOC ratio decreased towards the lower stream. This results show decrease of ratio of biodegradable organic material to total organic pollutants towards the lower stream. This study is significant since it has revealed the potential value of TOC as organic material indicator for inquiry of water quality characteristics in the natural water system.

• Journal of Korean Society on Water Environment
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• v.28 no.6
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• pp.813-818
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• 2012

BOD and COD are currently used for water quality indices, but adoption of TOC for TMDL (Total Maximum Daily Load) is being suggested. Estimation of TOC using existing BOD and COD data is very important to diagnosis water quality trend when TOC is used for water quality index of organic matter in the future. The relationships between BOD COD and TOC in runoff from paddy fields were investigated during 2008-2011. The observed mean concentration of EMCs (Event Mean Concentration) for BOD, COD, TOC were 3.87, 10.97, 7.26 mg/L respectively. The correlation coefficients between BOD-TOC and COD-TOC were 0.42, 0.73, respectively. The coefficient of determination of regression equation for BOD-TOC and COD-TOC were 0.18, 0.53 respectively. Even though, conversion of COD data to TOC seems to be rather reliable than that of BOD-TOC, further monitoring is recommended to ensure better interpretation of relationship among BOD, COD and TOC.

• Journal of Korean Society on Water Environment
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• v.30 no.5
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• pp.512-516
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• 2014

Two different methods for TOC (Total Organic Carbon) analysis of livestock manure including high strength solid organics were evaluated. Firstly, an analyzing method by dilution after pre-treated by Ultrasonicator and 100 mesh sieve for homogenization was defined as TOC 1; and secondly method divided by particulate organic carbon (POC) and dissolved organic carbon (DOC) was defined as TOC 2. 116 samples collected from 56 farms were analyzed in TOC1, TOC2, BOD and VSS. TOC1 method showed higher accuracy at less than 30,000 mg/L of TOC while TOC2 method presented significant reliability at over that concentration. Regarding to the sample with the same VSS concentration, the correlation between TOC 2 and VSS (${\rho}$: 0.806) was slightly higher than that between TOC 1 and VSS (${\rho}$: 0.784), resulted from a relatively low loss of solids and a low error probability (dilution and homogenization effects) in the analyzing procedures. In addition, the reliability between POC and VSS in TOC2 was high and the POC was about 4.4 fold that of the VSS. Consequently, TOC 2 without dilution effect was assessed as a proper method to increase the analyzing accuracy of swine manure including high solid organics.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2006.05a
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• pp.1251-1254
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• 2006

이 논문은 TOC 제약이론을 산업체에 적용한 사례를 바탕으로, 그 적용 과정과 적용 성과를 정리한 것이다. 이 사례에서는 TOC-DBR 과 TOC-TP가 적용되었다. TOC-DBR 은 공구제조업체, 모터조립업체, 그리고 직물제조업체에 적용되었으며, 재고 감축과 납기 단축의 성과를 얻었다. TOC-TP 는 영업부문의 정책 수립을 위해 적용되었다. 이런 일들은 체계적인 교육과 적절한 응용 지도 과정을 통해 추진되었다.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.6
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• pp.657-668
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• 2014

Under Korea's Enforcement Decree of the Framework Act on Environmental Policy amended in 2013, total organic carbon (TOC) is newly added as water quality parameter to assess organic pollution in water and aquatic ecosystem. To meet the TOC requirement and improve quality of effluent discharged into public watershed, it is also necessary to develop standards for TOC in effluent from public sewage treatment works (PSTWs). In this study, we reviewed the characteristics and removal efficiency of TOC in influent and effluent of PSTWs. The study found that phosphorus treatment process removed not only soluble phosphorus but also a portion of TOC remaining after the secondary treatment process. TOC concentration in effluent from PSTWs operated in tandem with industrial wastewater treatment work was higher due to influx of insoluble substances from the industrial wastewater treatment work. In order to lay a foundation for the management of TOC from PSTWs, it is necessary to carry out research on TOC from different perspectives. For example, studies on the generation mechanism of TOC and the impact of TOC on drinking water resources, assessment of effluent qualities through monitoring, and development of measures to control TOC for the preservation of aquatic ecosystem are needed.

• Journal of Korean Society on Water Environment
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• v.35 no.3
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• pp.271-277
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• 2019

Korean Trophic State Index ($TSI_{KO}$) was developed in 2006, and was composed of COD ($COD_{Mn}$ based on permanganate method), Chlorophyll a (Chl.a) and total phosphorus (TP). However, $COD_{Mn}$ usually represents only 50-60% of total organic matter in stream or lake water due to low oxidizing power of permanganate. This study investigated the relationship between TOC and $COD_{Mn}$ based on the average data for the whole layer in 81 lakes in Korea, during the period 2013-2017. As a result, $COD_{Mn}$ was found to be 1.54 times more than TOC in 66 of the freshwater lakes and 3 brackish lakes (TOC measured using thermo-oxidation method). TOC was about a quarter of $COD_{Mn}$ in 8 coastal lakes (TOC measured using UV-persulfate oxidation method), and it appeared to be underestimated due to chloride interference. Using the data of 69 lakes with exception of 12 brackish lakes, $TSI_{KO}$(TOC) was developed based on the correlation between TOC and $COD_{Mn}$, while $TSI_{KO}$(COD) was replaced with $TSI_{KO}$(TOC). However, for trophic state assessment of brackish lakes, the $TSI_{KO}$(TOC) can only be utilized in case that TOC is measured through thermo-oxidation method. The determination coefficient of $TSI_{KO}$(Chl) to $TSI_{KO}$(COD) in 66 freshwater lakes and 3 brackish lakes was 0.83, while that to $TSI_{KO}$(TOC) was 0.68. This difference could be attributed to the recalcitrant organic part of TOC.

• Journal of Wetlands Research
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• v.20 no.2
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• pp.173-180
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• 2018

The utilization of TOC(Total organic carbon), a new environmental standard, was evaluated for 30 lakes in the Nakdong River Basin, which is used for drinking and agricultural usage. The active use of water resources begins with securing satisfactory water quality. Since this allows people and nature to maintain stability of quality, water quality standards are being tightened to ensure good water quality. In order to improve the pollution level of organic matter in lakes in the living environment, it is important to use the appropriate organic substance index. The relationship between the newly introduced TOC and the existing COD(Chemical oxygen demand) in the targeted lake was positively correlated with the possibility of replacing the TOC with COD. However, the environmental grade standard using TOC is better than the environmental grade standard using COD, so it has the same effect as that of the grade of water quality using TOC as an organic substance factor. This indicates the limitation of TOC to directly replace existing COD when trying to determine or improve the quality level using organic indicators of lakes. Therefore, in order to secure the qualitative safety of the lake, it is required to strengthen environmental standards of TOC in terms of water quality grade. In addition, the correlation between TOC and COD shows a great difference depending on the utilization characteristics of the lake. This requires clear scientific identification, and it requires continuous monitoring of COD that has been used to accumulate indicators of lake organic matter.

• Journal of the Korean Society for Library and Information Science
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• v.49 no.3
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• pp.109-133
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• 2015

The purpose of this study is to develop a model of the TOC (Table of Contents)-based research record system and to comparatively analyze its usability, in order to comprehensively and systematically manage and practically use the various research records generated from the entire process of research and development. For this purpose, the templates for technical recording and the components of each item were proposed to enable technical recording based on TOC, and structured contents were designed to organically connect between these TOC technical records and existing research records. Also, a database logical schema was developed to design a database, and a test collection was constructed on the basis of research records and TOC technical records. Finally, the model of research record system was constructed by designing TOC record search system and user interface including integrated search system. Based on this model, the usability assessment was performed by comparing the existing distributed general systems with the TOC-based research record system. As a result of the comparative analysis of these two systems, the TOC-based research record system showed generally higher utilization of research records than the general systems.