• 제목/요약/키워드: TN/TP ratio

검색결과 130건 처리시간 0.03초

강우시 포도밭에 대한 초기세척효과 분석 (Analysis of First Flushing Effects for the Vineyard Storm Runoff)

  • 윤영삼;권헌각;이재운;유재정;이재관
    • 한국환경과학회지
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    • 제20권8호
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    • pp.977-986
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    • 2011
  • This study analyzed the characteristics of stormwater runoff in the orchard areas and quantitatively estimated effluence of nonpoint source pollutants for the volume of runoff. Two target areas under vine cultivation were each $2,000m^2$ and $1,800m^2$, located in Gyeongju City. Since grape was the only crop on the target area, the characteristics of stormwater runoff at vineyard could be evaluated independently. A total of 51 rainfall events in the vineyard area during two years(2008-2009) was surveyed, and 19 of them became stormwater runoff, with rainfall ranging 16.5 - 79.7 mm and antecedent dry period of 1-13 days. The pollutant runoff loads by volume of stormwater runoff showed BOD ranging 19.5 - 45.3% in 30% of runoff volume. The average pollution discharge rate was 32.4%, indicating small first flush effect of BOD. The range of SS concentrations was 5 - 52.0% in 10% of runoff volume, showing the average 28.7% of discharge rate, about 3 times more than rainfall effluent. TOC and TN appeared to be similar to the results of BOD, the average discharge rate of 30.9% and 30.6% for TOC and TN, respectively, for 30% of stormwater runoff volume. Average discharge rate of COD and TP in the same runoff volume was 35.1% and 36%, respectively, showing comparatively high discharge ratio. As the targeted vineyard area was permeable land, the pollution load ratio against rainfall-runoff volume appeared to be 1:1, implying no strong first flush effect for all the survey items.

Modifications of nutrient regime, chlorophyll-a, and trophic state relations in Daechung Reservoir after the construction of an upper dam

  • Ingole, Neha P.;An, Kwang-Guk
    • Journal of Ecology and Environment
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    • 제40권1호
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    • pp.24-33
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    • 2016
  • Background: Previous numerous studies on watershed scale demonstrated that the constructions of upper dams may influence the below dams due to modifications of flow regime and nutrient inputs. Little is known about how the dam constructions influence the downstream lakes or reservoirs in the regional scale. This study demonstrates how the construction of upper dam (i.e., Yongdam Dam) influences nutrient regime, trophic relations, and empirical models in Daechung Reservoir (DR). Yongdam Dam was constructed at the upstream region of DR in year 2000. Results: The analysis of hydrological variables showed that inflow and discharge in the DR were largely reduced after the year 2000. The construction of upper dam construction also resulted in increases of water temperature, pH and conductivity (as an indicator of ionic content) in the DR. Empirical models of TP-CHL and N:P ratio-CHL suggested that stronger responses of CHL to the phosphorus were evident after the upper dam construction, indicating that algal production at a unit phosphorus increased after the upper dam construction. Mann-Kendall tests on the relations of N:P ratios to TN showed weak or no relations ($t_{au}=-0.143$, z = -0.371, p = 0.7105) before the dam construction, while the relation of N:P ratios to TP showed strong in the periods of before- ($t_{au}=-0714$, z = -2.351, p = 0.0187) and after the construction ($t_{au}=-0.868$, z = -4.270, p = 0.0000). This outcome indicates that TP is key determinant on N:P ratios in the reservoir. Scatter Plots on Trophic State Index Deviations (TSIDs) of "TSI(SD) - TSI(CHL)" against "TSI(TP) - TSI(CHL)" showed that the dominance of clay turbidity or light limitation was evident before the upper dam construction [TSI(TP) - TSI(CHL) > 0 and TSI(SD) - TSI(CHL) > 0] and phosphorus limitation became stronger after the dam construction [(TSI(TP) - TSI(CHL) < 0 and TSI(SD) - TSI(CHL) > 0]. Conclusions: Overall, our analysis suggests that the upper dam construction modified the response of trophic components (phytoplankton) to the nutrients or nutrient ratios through the alteration of flow regime, resulting in modifications of ecological functions and trophic relations in the low trophic levels.

음식물류폐기물의 건식사료화 공정에서 발생되는 응축수로부터 유기탄소 추출 (Extraction of organic carbon from the condensate of food waste dry feed process)

  • 김민경;권기욱;모경;최봉호;박세용;김문일
    • 유기물자원화
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    • 제28권2호
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    • pp.41-48
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    • 2020
  • 본 연구에서는 음식물류폐기물 건조공정에서 발생하는 응축수에 포함된 유기탄소를 추출하여 외부탄소원으로서 적용 가능성을 평가하였다. 응축수의 성상은 COD, TN, TP 및 TS는 각각 21,374 (±3,238.3) mg/L, 148 (±32.6) mg/L, 4.19 (±1.5) mg/L, 455.7 (±0.015) mg/L로 나타났으며, 응축수에 포함된 생분해성 유기물의 함량은 47%였다. 응축수에 포함된 유기탄소 추출을 위하여 증발 농축 및 감압 증발 농축의 방법을 사용하였다. 본 연구에서 총 8가지 조건에서 수행 되었으나, 4가지 조건 (1. 상압 (0mmHg), 110℃ 2. 감압 (-600mmHg), 70℃ 3. 감압 (-500mmHg), 80℃ 4. 감압(-600mmHg), 80℃)에서 추출이 가능한 것으로 나타났다. 추출 결과, 추출된 4가지 조건 모두에서 유입 부피의 약 10% 추출하였을 때, 추출물의 유기물 농도가 가장 높고 추출 시간 대비 추출된 유기물의 양이 가장 많은 것으로 나타났다. 응축수에 포함된 유기탄소의 추출 최적 조건은 감압 (-600mmHg), 80℃로 판단하였으며, 유입 부피의 10% 추출이 적합한 것으로 평가하였다. 이때, 추출 농도, 추출량, 추출 효율, 추출시간, BOD/TCOD, TVFAs/TCOD의 비율 및 NH3-N의 값은 각각 174,200 mg/L, 8,710 mg, 46%, 10분, 0.97, 0.74, 75.5 mg/L로 나타났다. 따라서, 추출된 유기탄소는 외부탄소원으로 활용될 수 있을 것으로 판단된다.

Contribution of Non-Point Pollution to Water Quality and Runoff Characteristics from Agricultural Area of the Upstream Watersheds of Lake Chinyang

  • Lee, Chun-Sik;Jang, Seong-Ho
    • 한국환경과학회지
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    • 제22권3호
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    • pp.259-267
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    • 2013
  • In this study, non-point source(NPS) contribution was investigated based on flow rates and water qualities of streams into the lake during rainfall events. Event mean concentration(EMC) and the pollution loads were calculated to establish a database for NPS control measurement in the survey area, and so on. The runoff characteristics of NPS were investigated and estimated on the basis of the ratio of an agricultural to forest area in the stream of sub-catch basin during rainfall events. Non-point source pollution loads were also calculated to establish a database for NPS control measure in the upstream lake Chinyang. At a rainfall event, BOD concentrations rise sharply at the early peak time of runoff, however, peaks of TSS concentration were observed at the similar time of peak flow. This was a phenomenon shown at the watersheds caused by forest and geological types. The discharged EMC range was 2.9-4.8 mg/L in terms of BOD. The discharged EMC range was 6.2-8.2 mg/L in terms of SS. The discharged EMCs of T-N and T-P were 1.4-2.5 mg/L and 0.059-0.233 mg/L, respectively. Total BOD loading rate through the 3 tributaries to the lake Chinyang was 1,136 kg/d during dry weather. The upper watershed area of the Nam-river dam in this study was divided into 14 catchment basins based on the Korean guideline for total maximum daily load(TMDL) of water quality pollutants. The higher the agricultural land-use ratio, the more NPS loading rate discharged, but the more occupied a forest area, the lower more NPS loading rate discharged. In an agricultural land-use area more than 20%, the increase of NPS loadings might be dramatically diffused by increasing the integrated complex-use like vinyl-house facilities and fertilizer use etc. according to the effective land-use utilization. The NPS loading rates were BOD 0.3 $kg/ha{\cdot}day$, SS 0.21 $kg/ha{\cdot}day$, TN 0.02 $kg/ha{\cdot}day$, TP 0.005 $kg/ha{\cdot}day$ under less than 10% agricultural land-use. In agricultural land-use of 20%-50%, these values were investigated in the range of 0.32 $kg/ha{\cdot}day$-0.73 $kg/ha{\cdot}day$ for BOD, 0.92 $kg/ha{\cdot}day$-3.32 $kg/ha{\cdot}day$ for SS, 0.70 $kg/ha{\cdot}day$-0.90 $kg/ha{\cdot}day$ TN, 0.03 $kg/ha{\cdot}day$-0.044 $kg/ha{\cdot}day$ for TP.

식생이 조성된 LID 시설의 효율 평가 (Assessment of Performances of Low Impact Development (LID) Facilities with Vegetation)

  • 홍정선;김이형
    • Ecology and Resilient Infrastructure
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    • 제3권2호
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    • pp.100-109
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    • 2016
  • 도시 지역의 물순환 구축과 비점오염물질 저감을 위해 구축되는 LID 시설의 지속적 효율은 주요 내부 구성요소(식물, 토양, 여재, 미생물 등)의 최적화된 상호작용에 의하여 나타난다. 본 연구는 식생이 조성된 4가지 LID 기술 (식생체류지, 소규모 인공습지, 빗물정원 및 나무여과상자)의 실제 도시 강우유출수의 유입으로 인한 식물의 성장상태 변화와 물순환 효과 및 비점오염물질 저감능력을 평가하기 위하여 수행되었다. 도시지역의 강우유출수의 약 40% 이상의 유출저감을 위한 적정 SA/CA (facility surface area / catchment area) 비는 시설마다 차이는 있지만 1~5% 범위가 적당한 것으로 평가되었다. 강우시 LID 시설에서의 유출저감은 비점오염물질 저감효율 향상에 중요한 영향을 끼치는 기작으로 나타났으며, SA/CA는 LID 시설의 중요한 설계인자로 도출되었다. 유출저감에 효과적인 시설은 빗물정원 > 나무여과상자 > 식생체류지 > 소규모 인공습지 순으로 나타났으며 입자상 물질 (TSS)의 제거능력은 빗물정원 > 나무여과상자 > 소규모 인공습지 > 식생체류지 순으로 분석되었다. 유기물 (COD, TOC), 영양물질 (TN, TP) 및 중금속 (Cu, Pb, Cd, Zn) 제거에는 빗물정원 > 나무여과상자 > 식생체류지 > 소규모 인공습지 순으로 조사되었으며 이러한 결과들은 향후 도시지역의 물순환 구축 및 비점오염물 제거에 적용되는 LID 시설의 설계에 중요한 자료로 활용 가능할 것으로 판단된다.

한강 하류에서 환경요인의 변동과 식물플랑크톤의 군집 동태 (Fluctuation of Environmental Factors and Dynamics of Phytoplankton Communities in Lower Part of the Han River)

  • 서미연;김백호;배경석
    • 생태와환경
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    • 제40권3호
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    • pp.395-402
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    • 2007
  • 한강하류에서 환경요인에 따른 식물플랑크톤의 변화를 조사하기 위하여 2006년 1월부터 12월까지 총 35회 채수하여, 분석하고 동정한 결과 다음과 같은 결론을 얻었다. 환경요인의 변화에서는 모든 항목에서 지점간에 큰 차이가 없는 것으로 조사됐으나, BOD와 TN, TP등에서 St. 2지점이 높은 농도를 나타냈으며 집중 강우가 있었던 시기에 비교적 낮은 농도 분포를 나타냈다. 식물플랑크톤은 총 88종이 출현하였으며, 현존량은 $1{\sim}41$,104 cells $mL^{-1}$ 범위로써 계절과 조류종에 따라 변동이 큰 것으로 나타났다. 강별로는 남조류, 규조류, 녹조류가 서로 다른 경향을 나타냈는데, 남조류는 여름에서 가을로 접어드는 시기에(5월${\sim}$9월) 현존량이 낮은 반면,녹조류와 규조류의 출현이 우세하였고, 특히 규조류 중 Cyclotella sp.는 주로 봄철에, Aulacoseira granulata는 가을철에 주요 우점종으로 출현하면서 하절기인 6월을 기점으로 종 천이가 일어났다. 강우기에 현저하게 감소하였던 남조류는 강우가 끝난 후 수온이 $20^{\circ}C$ 이상 지속되면서 질소/인 비가 가장 낮아지는 시기인 10월$(9.4{\sim}18.9)$에 현존량이 급격하게 증가하여 대발생을 야기하였다. 주로 한강하류에서 식물플랑크톤의 천이가 일어날 수 있는 환경요인은 집중강우로 인한 팔당댐의 방류량과, 수온, 질소/인 비에 의해 영향을 받는 것으로 판단되었다.

신구저수지 식물플랑크톤성장에 대한 제한 영양염 분석 (Analysis of Algal Response Effects Using Nutrient Enrichment Bioassays in Shingu Reservoir)

  • 이재연;이상재;이재훈;배대열;최지웅;황순진;안광국
    • 생태와환경
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    • 제41권spc호
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    • pp.35-41
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    • 2008
  • 본 연구는 2006년 6월 22일부터 28일까지 식물성 플랑크톤의 1차 생산력을 알아보기 위하여 영양염 첨가 실험을 실시하였다. 평가를 위한 샘플은 저수지 중앙부에서 총 10L를 채수하였으며, Cubitainer에 각각 2.5L씩 분배하였다. 대조군은 원수를 그대로 사용하였으며, 처리군 1에는 $KH_2PO_4$을 첨가하였고, 처리군 2에는 2배 더 많은 $KH_2PO_4$을 첨가하여 각각 P, 2P가 되도록 하였다. 또한 처리군 3에는 $KNO_3$를 첨가하여 $NO_3-N$가 되도록 하였으며, 처리군 4에는 $KH_2PO_4$$KNO_3$을 첨가하여 $P+NO_3-N$가 되도록 하여 7일 동안 변화를 관찰하였다. P(T1)와 2P(T2)가 처리된 Cubitainer의 엽록소-${\alpha}$ 농도는 실험기간 동안 점점 감소하였고, 초기의 농도에 비하여 훨씬 낮은 수치를 보였다. 그러나, $NO_3$(T3)와 $P+NO_3$(T4)가 처리된 Cubitainer의 경우, 초기의 엽록소-${\alpha}$ 농도에 비하여 뚜렷하게 증가하는 것으로 나타났다. 단기 실험의 경우 질소가 일차적인 제한요인으로 작용한 것으로 사료되었다. 장기간에 걸친 TP, TN, TN: P mass ratios의 자료에 따르면, 인이 식물 플랑크톤의 성장에 제한요인으로 작용하였고, 채집된 시기와 장소에 따라 제한염류가 변하는 것으로 연구되어 졌다. 본 연구에서 질소는 1차 제한영양염류로 작용하였고 계절적인 영향에 의한 것으로 사료되었다.

호알칼리미생물을 이용한 슬러지감량형 하수처리공정 연구 (A Study on the Sludge-reduced Sewage Treatment Process Combined with Sludge Solubilization Technique Using Alkalophiles)

  • 신경숙;김윤석;한대훈;한운우;이영하;허형우
    • 상하수도학회지
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    • 제21권6호
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    • pp.737-744
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    • 2007
  • Recently, one of the most interesting topic in the field of wastewater treatment is the disposal of excess sludge. The new concept of excess sludge reduction with recirculation of solubilized sludge via effective microorganisms for cell disruption within the wastewater treatment process has been developed in this study. The alkalophiles for degradation of sludge cell wall were isolated as Exiguobacterium sp., which could be more effectively solubilized sludge in the anaerobic condition. The SCOD of solubilized excess sludge by Exiguobacterium sp. was up to about 2,000mg/L and average TN and TP concentration of solubilized component were 117mg/L and 58mg/L, respectively and C/N ratio was more than 17. To investigate the effects of solubilized sludge by alkalophiles on excess sludge reduction and nutrient removal efficiency, the pilot plant of $DF^{(S)}-MBR$ process, combined with membrane bioreactor and sludge solubilization tank, was operated. In the control run(without sludge solubilization), the daily sludge production was about 4.54 kgMLVSS/day. However, in the $DF^{(S)}-MBR$(with sludge solubilization), the daily sludge production was decreased to 1.39kgMLVSS/day. The effluent quality satisfied the effluent regulation in both cases. Furthermore, the $DF^{(S)}-MBR$ showed relatively better TN removal efficiency in spite of high influent loading. So we concluded that the solubilized excess sludge by alkalophiles was effectively degraded in the MBR process as the carbon source and 70% of sludge reduction efficiency can be achieved.

낙동강 상류 수역에서 남조류 발생과 천이패턴 - Aphanizomenon 속을 중심으로 - (Occurrence and Succession Pattern of Cyanobacteria in the Upper Region of the Nakdong River : Factors Influencing Aphanizomenon Bloom)

  • 류희성;박혜경;이혜진;신라영;천세억
    • 한국물환경학회지
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    • 제32권1호
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    • pp.52-59
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    • 2016
  • This study investigated the occurrences and succession patterns of harmful cyanobacteria, as well as environmental factors, during a 3-year period (September 2012 to August 2015) in the upper region of the Nakdong River around Sangju weir. A total of 27 cyanobacterial taxa were observed in this study, and classified into 26 species and 1 variety belonging to 11 genera, 5 families, and 3 orders. Cell density ranged from 24 to 42,001 cells/ml, with a geometric mean of 33 cells/ml, during the survey period. The dominant orders differed depending on the survey year; order Oscillatoriales in 2013, Chroococcales in 2014 and Nostocales in 2015. An Aphanizomenon bloom occurred in June 2015 at which time the highest cell density of 36,873 cells/ml was detected in the upper region of the Nakdong River, where as the Aphanizomenon spp. cell density (190-1,704 cells/ml) had been low prior to that time. An Aphanizomenon bloom also occurred at around the same time downstream in the Young River, a major inflow branch of the Nakdong River. The Aphanizomenon cell density along the Nakdong River increased markedly after joining of the YoungRiver, indicating that the Aphanizomenon bloom in the YoungRiver caused a bloom in the Nakdong River. Meteorological and environmental parameters, such as very low precipitation, higher water temperature, pH, and TP concentration, and lower TN/TP ratio, in May and June of 2015 than in 2013 and 2014 exerted marked effects on the Aphanizomenon bloom in June 2015 in the Young River.

낙동강수계 수질오염총량관리를 위한 시범소유역 유황별 유달율 산정방법 연구 (A Study on Estimation of the Delivery Ratio by Flow Duration in a Small-Scale Test Bed for Managing TMDL in Nakdong River)

  • 손태석;박재범;신현석
    • 한국물환경학회지
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    • 제25권5호
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    • pp.792-802
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    • 2009
  • The objective of this study is to construct the watershed management system with link of the non-point sources model and to estimate delivery ratio duration curves for various pollutants. For the total water pollution load management system, non-point source model should be performed with the study of the characteristic about non-point sources and loadings of non-point source and the allotment of pollutant in each area. In this study, daily flow rates and delivered pollutant loads of Nakdong river basin are simulated with modified TANK model and minimum variance unbiased estimator and SWAT model. Based on the simulation results, flow duration curves, load duration curves, and delivery ratio duration curves have been established. Then GIS analysis is performed to obtain several hydrological geomorphic characteristics such as watershed area, stream length, watershed slope and runoff curve number. As a result, the SWAT simulation results show good agreements in terms of discharge, BOD, TN, TP but for more exact simulation should be kept studying about variables and parameters which are needed for simulation. And as a result of the characteristic discharges, pollutants loading with the runoff and delivery ratios, non-point sources effects were higher than point sources effects in the small-scale test bed of Nakdong river basin.