• Title/Summary/Keyword: TMA

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A Study on the Thermal Life-Time Expectation of a NR Rubber Material using Isothermal TGA and TMA (등온 TGA 및 TMA를 이용한 NR고무소재의 내열수명 예측에 관한 연구)

  • Ahn, Won-Sool;Park, Ki-Ho
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.269-273
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    • 2009
  • A study on the life-time expectation of a CR-modified NR rubber composite through the change of thermal degradation characteristics was performed using both isothermal thermogravimetric analysis (TGA) and thermomechanical analysis (TMA). Master curves at reference temperature of $90^{\circ}C$ could be obtained with shift factor $a_T$, which was determined empirically using Time-Temperature Superposition Principle (TTSP). Activation energies could be calculated from the slope of Arrhenius plot of shift factor and showed similar values of $E_{a,TGA}$= 41.2 and $E_{a,TMA}$= 54.5 kJ/mol, respectively. It was considered from the results that chemical degradation resulting weight loss of the sample might be closely related to a physical degradation such as the dimensional change of the sample.

A Study on Cooling Characteristic of TMA-Water Clathrate Compound for Low Temperature Latent Heat Storage (저온잠열저장을 위한 TMA-물계 포접화합물의 냉각특성에 대한 연구)

  • Kim, Chang-Oh;Kim, Jin-Heung;Chung, Nak-Kyu
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2471-2475
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    • 2007
  • Clathrate compound is the material that host in hydrogen bond forms cage and guest is included into it and combined. Crystallization of hydrate is generated at higher temperature than that of ice from pure water. And physical properties according to temperature are stable and congruent melting phenomenon is occurred without phase separation. But clathrate compound still had supercooling problem occurred in the course of phase change and supercooling should be minimized because it affects efficiency of equipment very much. Therefore, various studies on additives to restrain this or heat storage methods are needed. In this study was investigated the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of 20${\sim}$25 wt% as a low temperature latent heat storage material. And ethanol$(CH_3CH_2OH)$ was added and its cooling characteristics were studied experimentally to restrain supercooling of TMA-water clathrate compound.

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Effect of Brine Mineral Water on TMA-Induced Contact Hypersensitivity Reaction in the Mouse Model (TMA로 유도된 접촉성 과민 반응 마우스 질환모델에서 해양성 광천수 도포시의 치료효과)

  • Kim, Jae-Jin;Kim, Wan-Jae;Sim, Jae-Man;Choi, Seon-Kang;Kwon, Soon-Sung;Kim, Jung-Duk;Lee, Kwang-Ho
    • The Korean Journal of Food And Nutrition
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    • v.23 no.4
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    • pp.440-445
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    • 2010
  • Effect of brine mineral water(BMW) on contact hypersensitivity reaction(CHR) was estimated using trimellitic anhydride (TMA) induced CHR in the mouse. BMW exhibited potent inhibitory activity on TMA induced CHR. BMW treatment suppressed the ear swelling, and attenuated hyper-activated lymph nodes stimulated by TMA challenge, thereby reduced their weight. The immunological index was analyzed after BMW administration in CHR. The level of serum IgE was significantly down regulated after BMW treatment. Furthermore, BMW showed inhibitory property of cytokine production. BMW treatment suppressed not only Th2 type cytokine, IL-4 but also pro-inflammatory cytokines such as TNF-${\alpha}$ and IL-6. From the histological analysis, the inflammatory context appeared by atopic dermatitis lesion after challenging with TMA are diminished by BMW treatment. Our results suggest that BMW may attenuate the development of CHR, and can be available for functional ingredient.

TMA-Water Clathrate Compound of Cooling Characteristics for Low Temperature Latent Heat Storage (저온잠열축열을 위한 TMA-물계 포접화합물의 냉각특성)

  • Kim, Chang-Oh;Chung, Hyoun-Ho;Chung, Nak-Kyu
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.296-301
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

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A Study on the Supercooling Improvement of TMA -Clathrate Compound by Ethanol (에탄올에 의한 TMA- 포접화합물의 과냉각 개선에 대한 연구)

  • Kim, Jin-Heung;Chung, Nak-Kyu;Kim, Chang-Oh
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.392-397
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    • 2005
  • This study is investigated the supercooling improvement and the phase change temperature of the TMA clathrate compound including TMA(Tri-Methyl-Amine, ($(CH_3)_3N$) of 25 wt% with additive as a low temperature storage material at $6^{\circ}C$ and $-7^{\circ}C$ of heat source. The additive is ethanol of 0.1, 0.3 wt% and 0.5 wt%. The results showed that as the concentration of ethanol is increased, the phase change temperature, the degree of supercooling and the retention time of liquid phase are decreased. Especially, TMA 25 wt% clathrate compound with ethanol of 0.5wt% has the average of phase change temperature of $3.8^{\circ}C$, degree of supercooling of $0.9^{\circ}C$, $0.8^{\circ}C$ and retention time of liquid phase for 6, 5 minutes at $-6^{\circ}C$, $-7^{\circ}C$ of heat source. From the results of this study, TMA 25wt% clathrate compound with ethanol 0.5wt% showed supercooling repression effect.

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A Study on the Cooling Characteristics of TMA by an Additive (첨가제에 의한 TMA의 냉각특성에 대한 연구)

  • Chung Nak-Kyu;Kim Jin-Heung;Kim Chang-Oh;Kang Seung-Hyun
    • Journal of Energy Engineering
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    • v.14 no.2 s.42
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    • pp.117-122
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    • 2005
  • This study is performed to investigate the cooling characteristics of TMA $25\;wt\%$ clathrate compound with an additive; the phase change temperature, the degree of supercooling, specific heat and the rate of volume change. The used additive is ethanol and the heat source temperature is $-7^{\circ}C$. Experimental results are as follows: 1) The phase change temperature is increased by $0.32\~0.96^{\circ}C$ during the cooling process of TMA $25\;wt\%$ clathrate compound with ethanol. 2) The degree of supercooling is repressed by $0.9^{\circ}C$ in case of TMA $25\;wt\%$ clathrate compound with $0.5\;wt\%$ ethanol. 3) The specific heat is increased by $0.19\;kJ/kg^{\circ}C$ in case of TMA $25\;wt\%$ clathrate compound with $0.l\;wt\%$ ethanol. 4) The rate of volume change is decreased by $1.15\~l.5\%$ in case of TMA $25\;wt\%$ clathrate compound with ethanol.

Determination of the Effect of Trimethylamine Reduction in Egg Yolk Following Supplementation of Laying-Hen Feed with Riboflavin

  • Park, Geon Woo;Park, Kyung Ho;Kim, Sang Gu;Lee, Sang Yun
    • Journal of Food Hygiene and Safety
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    • v.37 no.4
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    • pp.207-215
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    • 2022
  • The intensity of fishy odor in eggs, which differs depending on the poultry type and individual perception, can be due to many factors including trimethylamine (TMA) which has been identified as the main. Notably, riboflavin can increase the activity of flavin-containing monooxygenase 3, the enzyme responsible for converting TMA into odorless trimethylamine-N-oxide. This study aimed to analyze the TMA content in egg yolk, evaluate its contribution to fishy odor, and develop a method to prevent this undesired odor. Solid-phase microextraction-gas chromatography/mass spectrometry was used to detect and quantify volatile compounds in egg yolk from hens fed a standard TMA-rich diet and hens fed a riboflavin-supplemented diet. To compare the relative content of volatile substances between eggs, a correlation study was performed using an electronic nose. Higher concentration of TMA (1.06 ± 0.12 mg/kg) was detected in egg yolks obtained from hens fed a normal diet than those fed a riboflavin-supplemented diet. Overall, this study suggests that riboflavin affects the quantity and quality of volatile substances, including TMA, present in eggs and we expect these findings to improve the quality and reduce the fishy odor of eggs.

A Study on the Safety Performance of the Air Chamber TMA through Accident Analysis (사고분석을 통한 에어챔버 트럭충격흡수장치의 안전성능에 대한 연구)

  • Jo, Huichang;Park, Insong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.352-357
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    • 2016
  • More recently, workers and passengers of casualties has increased by rear-end collisions of unexpected while working on the road. Recently attracted air chamber TMA mounting car accidents which occurred in 3 years, and analyzed the effect of reducing the shock absorption and protection performance and casualties. There is a risk of the vehicle AIS4 more injury of high five accidents of casualties risk, also, was the analysis that there is risk of death was avoided by the air chamber TMA and SGT. Therefore, by mounting the TMA in the rear-end accident, so you can reduce the death and casualties, it must be increased this of attach rate for road construction vehicle.

Study on Bearing and Frequency Target Motion Analysis for Passive Line Array SONAR Using Accumulative Batch Estimation (누적 일괄추정 기법을 이용한 수동 선배열 소나 방위 주파수 - 표적기동분석 연구)

  • Kim, In-Soo
    • Journal of Institute of Control, Robotics and Systems
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    • v.22 no.10
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    • pp.788-796
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    • 2016
  • Bearing and frequency measurements of TMA (Target Motion Analysis) in passive line array SONAR have lower bearing rate and frequency doppler, and are not detected or tracked continuously because of various ocean environments. This is a main reason to effect the TMA performance and it takes a long time to get TMA solutions. We propose the bearing and frequency TMA(BFTMA) using accumulative batch estimation to solve the TMA problem of line array passive SONAR. The accumulative batch estimation structure is based on MLE (Maximum Likelihood Estimation) but used accumulative measurements. The accumulative batch estimation is applied for the BFTMA with nonlinear Kalman filter to estimate the target range, speed and course. Simulation and sea data analysis were carried out to verify the performance and applicability of the proposed techniques.