• Journal of the Korean Vacuum Society
• /
• v.6 no.4
• /
• pp.326-336
• /
• 1997

From the concept that the ion implantation-induced defect is one of the major factors in determining source/drain junction characteristics, high quality ultra-shallow $p^+$-n junctions were formed through the control of ion implantation-induced defects in silicon substrate. In conventional process of the junction formation. $p^+$ source/drain junctions have been formed by $^{49}BF_2^+$ ion implantation followed by the deposition of TEOS(Tetra-Ethyl-Ortho-Silicate) and BPSG(Boro-Phospho-Silicate-Glass) films and subsequent furnace annealing for BPSG reflow. Instead of the conventional process, we proposed a series of new processes for shallow junction formation, which includes the additional low temperature RTA prior to furnace annealing, $^{49}BF_2^+/^{11}B^+$ mixed ion implantation, and the screen oxide removal after ion implantation and subsequent deposition of MTO (Medium Temperature CVD oxide) as an interlayer dielectric. These processes were suggested to enhance the removal of ion implantation-induced defects, resulting in forming high quality shallow junctions.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2004.02a
• /
• pp.245-256
• /
• 2004

The extraction of three kinds of amido podands, N,N,N'N'-tetrabutyl-3-oxa-pentanedi- amide (TBDGA), N,N,N'N'-tetra-isobutyl-3-oxa-pentanediamide(TiBDGA) and N,N,N'N'-tetra- butyl-3,6-dioxa-oct-anediam- ide(TBDOODA) on U(VI),Pu(IV), Am(III), Eu(III) and other metal ions is studied in nitric acid solutions. 40%octanol-kerosene is chosen as diluents to eliminate third phase and emulsion. TBDGA and TiBDGA show extraction selectivity to An(III) and Ln(III) much higher than to U(VI) and Pu(IV). Fe, Ru and Mo is poorly extracted by the three kinds of amid podands in 2~3mol/L $HNO_3$ solutions. Aiming to eliminate interface crude when using simulated HLLW solution in the system of 0.2mol/L TBDGA/Octanol＋kerosene, acetohydroxyamic acid was adapted. Distribution ratio of zirconium was decreased when adding acetohydroxyamic acid in aqueous solution, and interface crude disappeared as mixing extractant with HLLW. The counter-current extraction test is carried out in a set of miniature mixer-settler, with 0.2mol/L TBDGA/ 40% octanol-kerosene as extractant to separate U(VI), Pu(IV), Am(III) and Eu(III) from simulated high level liquid waste(HLLW) solution. In battery A, lanthanides and actinides are coextracted into organic phase with the recovery of 99.98% for U(Ⅵ), >99.99% for Pu(IV), and >99.99% for Am(III) and Eu(III) respectively. In battery R1, 99.99% U, 86.2% Pu and a part of Am or Eu are stripped into aqueous phase by 0.2mol/L acetohydroxyamic acid (AHA) in 0.01mol/L $HNO_3$ solution. In battery $R_2$, Am, Eu and remained Pu are completely back-extracted by 0.2mol/L AHA. This separation process contains no salt reagent, and it is not necessary to dilute HLLW feed.

• Carbon letters
• /
• v.13 no.2
• /
• pp.109-114
• /
• 2012

A nuclear, biological, chemical (NBC) canister was indigenously developed using active carbon impregnated with ammoniacal salts of copper (II), chromium (VI) and silver (I), and high efficiency particulate aerosol filter media. The NBC canister was evaluated against carbon tetra chloride ($CCl_4$) vapours, which were used as a simulant for persistent chemical warfare agents under dynamic conditions for testing breakthrough times of canisters of gas masks in the National Approval Test of Respirators. The effects of $CCl_4$ concentration, test flow rate, temperature, and relative humidity (RH) on the breakthrough time of the NBC canister against $CCl_4$ vapour were also studied. The impregnated carbon that filled the NBC canister was characterized for surface area and pore volume by $N_2$ adsorption-desorption isotherm at liquid nitrogen temperature. The study clearly indicated that the NBC canister provides adequate protection against $CCl_4$ vapours. The breakthrough time decreased with the increase of the $CCl_4$ concentration and flow rate. The variation in temperature and RH did not significantly affect the breakthrough behaviour of the NBC canister at high vapour concentration of $CCl_4$, whereas the breakthrough time of the NBC canister was reduced by an increase of RH at low $CCl_4$ vapour concentration.

• Journal of Korean Association for Spatial Structures
• /
• v.9 no.2
• /
• pp.77-82
• /
• 2009

ETFE is the abbreviation of Ethlene Tetra Fluoro Ethlene, a sort of colorless and transparent granules. The advantage of ETFE film has chemical resistance, anti-stick property, very lightly material. The thickness of ETFE film is used to from 50 ${\mu}m$ to 300 ${\mu}m$ and have superior ability of daylight transmission and elongation, while the strength is lower than of fabric membrane. The tensile strength of ETFE film changes from 40Mpa to 60Mpa and the tensile strain at break can get to about 300-400%. The mechanical characteristic test of ETFE film is described in this paper. The tensile strain at break, the tensile strength and the stress-strain curve are obtained from the test. And then it was analyzed stress-strain characteristic by temperature and mechanical characteristic by cycling load.

• 한국전산유체공학회:학술대회논문집
• /
• 2008.03a
• /
• pp.177-180
• /
• 2008

The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

• 한국전산유체공학회:학술대회논문집
• /
• 2008.10a
• /
• pp.177-180
• /
• 2008

The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

• Journal of the Korean Chemical Society
• /
• v.45 no.2
• /
• pp.131-137
• /
• 2001

The protonation and stability constants of complexation of Zn(II), Cd(II) and Pb(II), Hg(II) ion with sulfur-containing podand ligands such as tri(phenylthio-2-ethy1)amine (Podand N$_1$S$_3$)tetra(phenylthio-2-ethyl)ethylenediamine (Podand N$_2$S$_4$) , tris(1-benzylaminoethyl)amine (Podand N$_4$) have been determined by potentiometric titration in 95% methanol at variable temperatures, From these studies, we observed that podand N$_4$ ligand showed the largest protonation constant. Protonation constant, stability constant, enthalpy, entropy of Zn(II), Cd(II) and Pb(II), Hg(II),ions increased with the following order podand N$_1$S$_3$$_2$S$_4$$_4$.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.5
• /
• pp.694-698
• /
• 2004

A new method for the simultaneous determination of seven transition metal ions in water and food by microcolumn high-performance liquid chromatography has been developed. The lead, cadmium, mercury, nickel, cobalt, silver and tin ions were pre-column derivatized with tetra-(4-aminophenyl)-porphyrin ($T_4$-APP) to form the colored chelates which were then enriched by solid phase extraction with $C_{18}$ cartridge. The enrichment factor of 50 was achieved by eluted the retained chelates from the cartridge with tetrahydrofuran (THF). The chelates were separated on a ZORBAX Stable Bound microcolumn ($2.0{\times}50\;mm,\;1.8\;{\mu}m$)with methanol-tetrahydrofuran (95 : 5, v/v, containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) as mobile phase at a flow rate of 0.5 mL/min and detected with a photodiode array detector from 350-600 nm. The seven chelates were separated completely within 2.0 min. The detection limits of lead, cadmium, mercury, nickel, cobalt, silver and tin are 4 ng/L, 3 ng/L, 6 ng/L, 5 ng/L, 5 ng/L, 6 ng/L, 4 ng/L respectively in the original samples. This method was applied to the determination of the seven transition metal in water and food samples with good results.

• Korean Journal of Organic Agriculture
• /
• v.23 no.4
• /
• pp.951-962
• /
• 2015

To develop environment-friendly agricultural products with anti-microbial activity against Sclerotinia sclerotiorum as a pathogen of sclerotium disease, Aristolochia tagala Champ. was extracted by methanol and its extract was fractionated into several solvent fractions. The chloroform fraction, which showed the highest antimicrobial activity, was separated by column chromatography and obtained forty three subfractions. The forty three fractions were searched the anti-fungal activities by bioassay. The most active No. 26 subfraction was analyzed by GC-MS. Each mass spectra, corresponding to each peak of chromatogram, was compared to MS database of Wiley library. As a result, 2,4-di-tetra-butyl-phenol, 2-mono-palmitin, 1-mono-stearin were profiled as maine compounds in No. 26 subfraction. Bioassay using commercial 1-mono-stearin to test for the anti-microbial activity conformed the antimicrobial active compound. In conclusion, 1-mono-stearin identified from Aristolochia tagala Champ. was antimicrobial chemical against Sclerotinia sclerotiorum.

• Korean Journal of Materials Research
• /
• v.9 no.5
• /
• pp.452-459
• /
• 1999

To develop advanced cladding materials, the effect of Nb addition on the microstructure and corrosion characteristics of Zr-0.8Sn-xNb alloys was investigated. As the Nb content increased, the grain size decreased and the volume fraction of precipitates increased. It was observed from the corrosion test at $360^{\circ}C$ that the corrosion resistance increased with decreasing Nb content. The best corrosion resistance was obtained in Zr-0.8Sn-0.2Nb alloy with high volume fraction of tetra-$ZrO_2$in the oxide. Therefore, it is suggested that Nb in theZr-0.85Sn-xNb system should be added within the solubility limit of Nb from the viewpoint of alloy design.