• Title/Summary/Keyword: TETRA

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Reversed-Phase High Performance and Liquid Chromatographic Separation of the Enantiomers of Terbutaline by Derivatization with 2,3,4-Tetra-o-acetyl-\beta-glucopyranosyl Isothiocyanate

  • Kim, Kyeong-Ho;Kim, Dong-Sig;Hong, Seon-Pyo;Keon, Oh-Seung
    • Archives of Pharmacal Research
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    • v.23 no.1
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    • pp.26-30
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    • 2000
  • The enantiomers of the bronchodilator terbutaline were separated by reversed-phase high performance liquid chromatograhy after derivatization with 2,3,4,6-tetra-O-acetyl-\beta-D-glucopyranosyl isothiocyanate(GITC) reagent. The derivatization proceeded quantitatively within 1 h at room temperature. The corresponding diastereomeric thiourea derivatives were well resolved on an ODS column with acetonitrile-acetate buffer as a mobile phase. Elution orders of the diastereomers were confirmed by derivatization of R-(-)-terbutaline and S-(+)-terbutaline which were collected by semi-preparative chiral HPLC using Sumichiral OA-4700 column. The native fluorescence of terbutaline was quenched by derivatization with GITC. The detection limit was 25ng when monitored at UV 278 nm.

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Preparation and Characterization of Chemically Stable PVDF-HFP Asymmetric Microfiltration (MF) Membranes

  • Lee, Yeon-Ee;JeGal, Jong-Geon
    • Membrane Journal
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    • v.22 no.2
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    • pp.104-112
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    • 2012
  • Chemically stable Polyvinylidene fluoride-hexa-fluoropropane (PVDF-HFP) copolymer asymmetric membranes were prepared by the conventional phase inversion process, using Dimethyacetamide (DMAc) as a solvent and water as a non-solvent. To control the pore size and porosity of the PVDF-HFP membranes, tetra-ethoxysilane (TEOS) was used as a pore-forming agent. The prepared membranes were characterized, using several analytical methods such as Fourier Transform Infrared spectroscopy (FTIR), Thermo-gravimetric analyzer (TGA), Field Emission Scanning Electronic Microscopy (FESEM). TEOS turned out to increase porosity and make homogeneous pores on the membranes. Depending on the composition of the dope solutions, the pore size was ranged from 0.1 to 1.0 ${\mu}m$. The flux of the PVDF-HFP membranes prepared by using TEOS as a pore forming agent was increased substantially without much decrease in the rejection. When 15 wt% PVDF-HFP solution was blended with 13 wt% TEOS solution at composition ratio of 70/30 in wt%, the water flux at 2 bars was about 2 $m^3/m^2day$.

A Study on the Necessity of Integrated Radio Networks for Domestic Railways (철도 통합무선망 구축 필요성에 관한 연구)

  • Kim, Cheol-Hwan;Kim, Bum-Gon;Lee, Seoung-Cheol
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.2808-2813
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    • 2011
  • According to opening the domestic existing lines and High-Speed Lines(HSL) depending on each section and phase-in, there were constructed in railway over state-of-the-art radio communication networks. Therefore, there have been 3 wireless communication networks in domestic railways in accordance with running sections as like VHF, TRS-ASTRO and TRS-TETRA. For instance, the VHF networks were constructed in exsiting lines and TRS-ASTRO were Kyungbu HSL phase-1 except Seoul-Kwangmyung section, downtown in Daejeon City and that of Daegu City. And it was constructed in DongDaegu-Busan section of Kyungbu HSL phase-2, Osong-Kwangju section of Honam HSL phase-1 and would be done in Kwangju-Mokpo of Hanam HSL phase-2 and Soosu-Pyungtaek of Metropolitan Area Line by TRS-TETRA. In this paper, we described some important problems of radio communication management and investigated current state of radio communication for railways. Moreover, we presented the necessity of integrated radio networks for domestic railways.

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Effect of irradiation on the oxidation kinetics of TODGA-based extraction mixtures at atmospheric pressure

  • Skvortsov, I.V.;Belova, E.V.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.52 no.9
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    • pp.2034-2040
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    • 2020
  • The gas evolution from mixtures consisting of 0.2 M solution of N,N,N',N'-tetra-n-octyldiglycolamide (TODGA) in n-alcohol (n-decanol or n-nonanol) with Isopar-M diluent was investigated during thermal oxidation. The effect of ionizing radiation on their thermal stability has been studied. It has been determined that the volume of gaseous thermolysis products increases by 260% in the case of n-nonanol and 80% in the case of n-decanol compared to non-irradiated solutions. It has been shown that the gas evolution rate and gas volume increase when the irradiated mixture saturated with nitric acid is heated. However, there are no prerequisites for the development of autocatalytic oxidation.

Highly Selective Triiodide Polymeric Membrane Electrode Based on Tetra(p-chlorophenyl)porphyrinato Manganese (Ⅲ) Acetate

  • Farhadi, Khalil;Shaikhlouei, Hossain;Maleki, Ramin;Sharghi, Hashem;Shamsipur, Mojtaba
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1635-1639
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    • 2002
  • A new solvent polymeric membrane sensor based on tetra(p-chlorophenyl)porphyrinato manganese (III) acetate is described which demonstrates excellent selectivity toward the triiodide ion. The electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-2}$ M and 7.0 ${\times}$$10^{-6}$M with a Nernstian slope of $-59.6{\pm}1$ mV per decade and a detection limit of 5.0 ${\times}$$10^{-6}$M. The proposed sensor revealed good selectivities for triiodide over a wide variety of other anions and could be used in a pH range 2-9. The electrode can be used for at least two months without any considerable divergence in potential. It was applied as indicator electrode in potentiometric titration of the triiodide and As(III) ions.

The Electrochemical Properties of Supercapacitor for Smart Grid Energy Storage System with Variation of MWCNT/Super P Content (스마트 그리드 에너지 저장시스템 슈퍼커패시터의 MWCNT/Super P 함량에 따른 전기 화학적 특성)

  • Lee, Du-Hee;Lee, Kyoung-Min;Yoon, Jung-Rag
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.843-847
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    • 2010
  • This paper in concerned with the electrochemical properties for supercapacitor of composition with variation of super P/MWCNTs(multi-walled carbon nanotubes) contents. Electrochemical properties of the super P/MWCNTs were measured by cyclic voltammetry at the scan rates of 0.5 mV/s is $TEABF_4$(tetra-ethyl-ammonium-tetra-fluoro-borate) as electrolytes. As a result, the composition for 6 wt% content of MWCNTs led to an increase of capacitance, but DC resistance were decreased. It was found that the content and dispersion appearance of MWCNTs was attributed to the increase in capacitance and lower DC resistance.

Polishing Mechanism of TEOS-CMP with High-temperature Slurry by Surface Analysis

  • Kim, Nam-Hoon;Seo, Yong-Jin;Ko, Pil-Ju;Lee, Woo-Sun
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.164-168
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    • 2005
  • Effects of high-temperature slurry were investigated on the chemical mechanical polishing (CMP) performance of tetra-ethyl ortho-silicate (TEOS) film with silica and ceria slurries by the surface analysis of X-ray photoelectron spectroscopy (XPS). The pH showed a slight tendency to decrease with increasing slurry temperature, which means that the hydroxyl $(OH^-)$ groups increased in slurry as the slurry temperature increased and then they diffused into the TEOS film. The surface of TEOS film became hydro-carbonated by the diffused hydroxyl groups. The hydro-carbonated surface of TEOS film could be removed more easily. Consequently, the removal rate of TEOS film improved dramatically with increasing slurry temperature.