• 제목/요약/키워드: TCF4

검색결과 364건 처리시간 0.019초

자외선 경화형 인계 단량체를 이용한 면직물의 방염가공 (Flame-retardant Finish of Cotton Fabrics Using UV-curable Phosphorous-containing Monomers)

  • 장진호;정용균
    • 한국염색가공학회지
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    • 제20권4호
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    • pp.8-14
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    • 2008
  • Flame-retardant cotton fabrics were prepared by UV curing of photocurable aqueous formulations of phosphorous-containing methacrylate monomers and 2-hydroxy-2-methyl-1-phenyl-1-propanone as flame retardants and a photoinitiator respectively, which is an environmentally friendly and energy-saving process. The characterization of the UV-coated cotton fabric was made by ATR, TGA and limited oxygen index measurement. UV cured coating onto cotton fabrics reduced the first thermal decomposition temperature and mass loss as well as increase in the amount of char residue compared with the untreated cotton fabric presumably due to modified thermal decomposition process. The LOI values up to 28.5 and 27.2 were obtained by the UV curing of MMEP and TMEP respectively. The treatment was durable to five laundering cycles, which was more prominent in the case of trifunctional TMEP treatment.

Methacryloxypropyltrimethoxysilane(MAPTMS)의 광그라프트에 의한 PET직물의 열적 안정성 향상 (Improved Thermal Stability of PET Fabrics by Photografting of Methacryloxypropyltrimethoxysilane(MAPTMS))

  • 장진호;손정아
    • 한국염색가공학회지
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    • 제20권4호
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    • pp.1-7
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    • 2008
  • Methacryloxypropyl trimethoxysilane (MAPTMS), a hybrid organic-inorganic monomer, was photografted onto PET fabric using benzophenone (BP) as a photoinitiator. It was found that a UV energy of 43.2J/$cm^2$ was required to optimally photograft the MAPTMS onto PET fabrics which was applied with an aqueous formulation of 10% MAPTMS, 20% BP and 0.5% N-Methyldiethanol amine (MDEA). The MDEA additive was efficient in reducing atmospheric oxygen inhibition of polymer radicals which eliminated compulsory nitrogen inerting. The surface grafting of PET fabrics was verified by fourier transform infrared spectroscopy (FT-IR) and scanning electron spectroscopy (SEM). The grafted PET fabrics with the hybrid monomer showed higher thermal stability due to the introduced silane component in the monomer as ascertained by higher char content at 800$^{\circ}C$, which increased to 14.5% for the 15.8% grafting compared to 8.2% for the untreated.

DCCA 처리와 저온플라즈마 처리가 양모직물의 염색성에 미치는 영향 (Effect of Low Temperature Plasma and DCCA treatment on the Dyeing Properties of Wool Fabric)

  • 정영진
    • 한국염색가공학회지
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    • 제20권4호
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    • pp.53-59
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    • 2008
  • For the modification of wool surface, wool fabrics treated with oxygen low-temperature plasma(LTP) and dichloroisocyanuric acid(DCCA) were dyed with milling type acid dye. The difference of dyeing properties on modified and control wool fabric were investigated. DCCA treated wool showed that saturation dye uptake and dyeing desorption ratio were higher than LTP treated wool. Dyeing transition temperatures of DCCA and LTP treated wool fabrics were 20$^{\circ}C$ degree lower than control wool fabric. In light color fastness test, DCCA treated wool fabric was 1 grade lower than LTP or control wool fabric.

페놀계 모델 화합물 및 폴리벤조옥사진 수지에 대한 수소결합분포의 정량화 (Quantification for the Distribution of Hydrogen Bonding Species in Phenolic Model Compounds and Polybenzoxazines)

  • 김호동;문화연
    • 한국염색가공학회지
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    • 제20권4호
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    • pp.21-30
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    • 2008
  • To understand the complex hydrogen bonding structure, several phenolic derivatives and benzoxazine model compounds are synthesized and characterized by Fourier transform infrared spectroscopy (FT-IR). The estimation of molar extinction coefficients for various types of hydrogen bonding species is systematically carried out by the curve-resolving of FT-IR spectra. The distribution of hydrogen bonding species in benzoxazine model dimers is quantitatively analyzed. It is revealed that benzoxazine dimers and BA-a polybenzoxazine are mainly composed of intramolecular interaction rather than intermolecular interaction.

DCCA 처리와 산소 저온플라즈마 처리가 양모직물의 형태안정성과 태에 미치는 영향 (Effect of Low Temperature Plasma and DCCA treatment on the Dimensional Stability and Hand of Wool Fabric)

  • 정영진
    • 한국염색가공학회지
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    • 제20권4호
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    • pp.43-52
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    • 2008
  • Wool fabric was treated with oxygen low-temperature plasma (LTP) and dichloroisocyanuric acid. The effect of dimensional stability (relaxation shrinkage, hygral expansion, felting shrinkage), tensile strength and elongation, crease recovery, and hand of wool fabric between LTP, DCCA treated wool fabrics and control wool fabric were investigated. SEM photograph showed that a little micro crack was formed on the fiber surface by plasma treatment with hard condition and epicuticle scale was damaged by DCCA treatment. Felting shrinkage, tensile strength and total hand value were much different in each samples.

MPCE copolymer와 습식 폴리우레탄의 블렌드에 의한 투습방수 나일론 직물의 제반 물성변화에 관한 연구 (Property Evaluation of Breathable Blend Fabric of MPCE Copolymer and Wet Coagulated Polyurethane)

  • 이종우;채애정;배진석
    • 한국염색가공학회지
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    • 제26권4호
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    • pp.322-330
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    • 2014
  • The phospholipid-based MPCE(2-Methacryloxyethyl Phosphoryl Chlorine) copolymer was mixed with wet polyurethane for coating of nylon fabrics. The substitution rate of water in coagulation bath with DMF was changed under control of the size of formed hydrophilic microporous cell enable to manufacture excellent breathable, anti-bacterial and moisture control fabrics. Biocompatible property, vapor permeability, hydrostatic pressure, moisture management and anti-bacterial property were investigated for treated nylon fabrics. In result, increased moisture transmission rates, decreased water resistance and outstanding moisture control property could be confirmed by enhanced hydrophilicity of wet-coated nylon fabric with MPCE copolymer.

Structural Analysis for the Single Crystal of 2-(4-(9H-carbazol-9-yl)benzylidene) based Dye Compound

  • Hwang, Jiyong;Son, Young-A
    • 한국염색가공학회지
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    • 제26권2호
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    • pp.143-149
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    • 2014
  • The designed dye material, namely 2-(4-(9H-carbazol-9-yl)benzylidene) compound, was synthesized. After the reaction, the solid was filtered and purified by recrystalization with acetone/water. To confirm and analyze its synthesis and structural formation, the single crystal was prepared and its measurement was carried out. A yellow needle crystal of $C_{22}H_{13}N_3$ were made on a Rigaku R-AXIS RAPID diffractometer using graphite monochromated CuK${\alpha}$ radiation. All details were suggested and introduced to support and communicate this study.

극초경량 실리카 에어로겔의 폴리우레탄 멤브레인 적용 특성 (Application Properties of Ultra Light Weight Silica Aerogel to Polyurethane Membrane)

  • 민문홍;정천희;윤석한;양정한;김태경
    • 한국염색가공학회지
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    • 제25권4호
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    • pp.279-286
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    • 2013
  • Application properties of ultra light weight silica aerogel toward polyurethane membranes were investigated. From the results of pre-milling process of the silica aerogel, the solvent for dispersion of the aerogel was determined for methyl ethyl ketone and its content in the solvent was determined by 30%. Using this aerogel dispersion, the polyurethane membranes were prepared according to the mixing amount of silica aerogel and various properties of the membranes were investigated. As results, the optimum mixing amount of silica aerogel inside polyurethane membranes was decided at 11%, because the improvement of light weight property, air permeability, and moisture vapor permeability were improved upto 11% of silica aerogel content, maintaining the water penetration resistance almost unchanged.

RFID 안테나용 전도성 프린팅을 위한 PET 직물의 최적 전처리 공정연구 및 성능평가 (A Study on Pre-treatment and Performance Evaluation for Printing RFID Antenna with Conductive Paste)

  • 홍진표;정찬도;윤석한;최상현
    • 한국염색가공학회지
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    • 제25권4호
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    • pp.287-291
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    • 2013
  • Nowadays, terms such as 'Smart Textile', 'Intelligent Textile' and 'Wearable Computing' are commonly used in everyday contexts. And radio-frequency identification (RFID) is the use of a wireless non-contact system that uses radio-frequency electromagnetic fields to transfer data from a tag attached to an object, for the purposes of automatic identification and tracking. These products are required technologies which are textile treatments, printing, ink, etc. Durability of textile substrates is an essential marker for conductive ink printing process. Especially, heat stability is important, since conductive ink should be processable (annealing, curing) at temperatures below $150^{\circ}C$. This study was application of RFID on textiles. The textile pre-treatment processes should be carried out to use RFID antenna on textiles.

일시적 수용성 반응성 분산염료를 이용한 메타 아라미드 섬유의 염색성 연구 (Dyeing of meta-Aramid Fabric with Temporarily Solubilized Reactive Disperse Dyes)

  • 이연주;이정진
    • 한국염색가공학회지
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    • 제25권4호
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    • pp.262-270
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    • 2013
  • Temporarily solubilized reactive disperse dyes containing ${\beta}$-sulfatoethylsulfonyl group were applied to 100% meta-aramid knitted fabric and their dyeing properties were investigated. Reactive disperse dyes showed relatively high K/S values on meta-aramid fabric when compared with conventional disperse dye or reactive dye, which showed very low K/S values. Color yields of reactive disperse dyes were highly dependent on dyeing pH and optimum results were obtained at pH 6. Percent exhaustion of reactive disperse dye on meta-aramid fabric was over 80% at 2% o.w.f of dye concentration. Wash fastness of pyridone-based reactive disperse dyes was very good to excellent while that of aminoazobenzene reactive disperse dyes was medium to good. Light fastness of all the reactive disperse dyes was very poor which seems to be due to the low photostability of meta-aramid fiber itself.