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http://dx.doi.org/10.5764/TCF.2008.20.4.021

Quantification for the Distribution of Hydrogen Bonding Species in Phenolic Model Compounds and Polybenzoxazines  

Kim, Ho-Dong (Dept. of Fiber System Engineering, Dankook University)
Moon, Hwa-Yeon (Dept. of Fiber System Engineering, Dankook University)
Publication Information
Textile Coloration and Finishing / v.20, no.4, 2008 , pp. 21-30 More about this Journal
Abstract
To understand the complex hydrogen bonding structure, several phenolic derivatives and benzoxazine model compounds are synthesized and characterized by Fourier transform infrared spectroscopy (FT-IR). The estimation of molar extinction coefficients for various types of hydrogen bonding species is systematically carried out by the curve-resolving of FT-IR spectra. The distribution of hydrogen bonding species in benzoxazine model dimers is quantitatively analyzed. It is revealed that benzoxazine dimers and BA-a polybenzoxazine are mainly composed of intramolecular interaction rather than intermolecular interaction.
Keywords
hydrogen bond; intermolecular interaction; intramolecular interaction; polybenzoxazine; phenol;
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