• Title/Summary/Keyword: T1 relaxation time

Search Result 140, Processing Time 0.021 seconds

Structural nature of chemically inequivalent borons in the nonlinear optical material β-BaB2O4 studied using 11B MAS NMR and 11B single-crystal NMR

  • Kim, Woo Young;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.17 no.2
    • /
    • pp.86-91
    • /
    • 2013
  • Detailed information about the structural nature of three-coordinate borons in ${\beta}-BaB_2O_4$ is obtained through $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR. The three-coordinate $BO_3$ of the two borons B(1) and B(2) in ${\beta}-BaB_2O_4$ were distinguished. The spin-lattice relaxation time in the laboratory frame $T_1$ for B(1) and B(2) slowly decreases with increasing temperature, whereas the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for B(1) and B(2), which differs from $T_1$, is nearly constant. The B(1) and B(2) of the two types were distinguished by $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR.

[ $T_2$ ]-relaxation Time Measurement of ex vivo $^1H$ MR Metabolite Peaks for Evaluation of Human Stomach Cancer

  • Mun Chi-Woong;Choi Ki-Sueng;Shin Oon-Jae;Yang Young-Ill;Chang Hee-Kyung;Hu Xiaoping;Eun Chung-Ki
    • Journal of Biomedical Engineering Research
    • /
    • v.27 no.2
    • /
    • pp.53-58
    • /
    • 2006
  • In this study, transverse relaxation time (T2) measurement and the evaluation of the characteristics of the spectral peak related to stomach tissue metabolites were performed using ex vivo proton magnetic resonance spectroscopic imaging (MRSI) at 1.5-T MRI/S instruments. Thirty-two gastric tissues resected from 12 patients during gastric cancer surgery, of which 19 were normal tissue and 13 were cancerous tissue, were used to measure the $T_2$ of the magnetic resonance spectroscopy (MRS) peaks. The volume of interest data results from the MRSI measurements were extracted from the proper muscle (MUS) layer and the composite mucosa/submucosa (MC/SMC) layer and were statistically analyzed. MR spectra were acquired using the chemical shift imaging (CSI) point resolved spectroscopy (CSI-PRESS) technique with the parameters of pulse repetition time (TR) and echo times (TE) TR/(TE1,TE2)=1500 msec/(35 msec, 144 msec), matrix $size=24{\times}24$, NA=1, and voxel $size=2.2{\times}2.2{\times}4mm^3$. In conclusion, the measured $T_2$ of the metabolite peaks, such as choline (3.21ppm) and lipid (1.33ppm), were significantly decreased (p<0.01 and p<0.05, respectively) in the cancerous stomach tissue.

133Cs Nuclear Magnetic Resonance Relaxation Study of the Phase Transition of Cs2MnCl4·2H2O Single Crystals

  • Heo, Cheol;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.14 no.2
    • /
    • pp.76-87
    • /
    • 2010
  • The structural phase transition of $Cs_2MnCl_4{\cdot}2H_2O$ single crystals was investigated by determining the $^{133}Cs$ spin-lattice relaxation time $T_1$. The number of resonance lines in the $^{133}Cs$ spectrum changes from seven to one near 375 K, which means that above 375 K the Cs sites are symmetric. Further, the $T_1$ of the $^{133}Cs$ nucleus undergoes a significant change near 375 K, which coincides with the change in the splitting of the $^{133}Cs$ resonance lines. The change in $T_1$ near $T_C$ is related to the loss of $H_2O$, and means that the forms of the octahedra of water molecules surrounding $Cs^+$ are disrupted.

A Linearization Model of the Stress Relaxation Curves for Fruits and Vegetables (과일 및 채소의 응력완화 직선화 모델)

  • Yoo, Myung-Shik;Song, Woo-Jin;Rho, Young-Ta;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
    • /
    • v.24 no.3
    • /
    • pp.226-231
    • /
    • 1992
  • A generalized linearization model for stress relaxation curves of vegetative tissues was proposed as $[F_{(o)}t^n/(F_{(o)}-F_{(t)})=k_1+k_2t]$, taking into account internal structure changes under a constant strain. Where $F_{(o)}$ is the initial force, $F_{(t)}$ is the decaying force after time t, and $k_1$, $k_2$ and n are constants. This model was well fit to stress relaxation curves of a variety of raw and processed fruits and vegetables.

  • PDF

Theoretical Investigation of the Vibrational Relaxation of NO(${\upsilon}=1-7$) in Collisions with $O_{2}\;and\;N_{2}$

  • Jongbaik Ree
    • Bulletin of the Korean Chemical Society
    • /
    • v.14 no.1
    • /
    • pp.47-52
    • /
    • 1993
  • The vibrational relaxation rate constants of NO(v = 1-7) by $O_2\;and\;N_2$ have been calculated in the temperature range of 300-1000 K using the solution of the time-dependent Schrodinger equation. The calculated relaxation rate constants by $O_2$ increase monotonically with the vibrational energy level v, which is compatible with the experimental data, while those by $N_2$ are nearly independent of v in the range of $3.40 {\pm}1.60{\times}10_{-16} cm^3$/molecule-sec at 300 K. Those for NO(v) + $N_2$ are about 2-3 orders of magnitude smaller than those for NO(v) + $O_2$, because the latter is an exothermic processes while the former an endothermic. Relaxation processes can be interpreted by single-quantum V-V transition. The contributions of V-T/R transition and double-quantum V-V transition to the relaxation are negligible over the entire temperature range.

Nuclear Magnetic Resonance Study of the Raman Spin-Phonon Processes in the Relaxation Mechanisms of Double Sulfate Li3Rb(SO4)2 Single Crystals

  • Heo, Cheol;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.15 no.1
    • /
    • pp.40-53
    • /
    • 2011
  • The NMR spectra of $Li_3Rb(SO_4)_2$ crystals and their relaxation processes were investigated by using $^7Li$ and $^{87}Rb$ NMR. The relaxation rates of the $^7Li$ and $^{87}Rb$ nuclei in the crystals were found to increase with increasing temperature, and can be described by the relation $T_1^{-1}{\propto}AT^2$. The dominant relaxation mechanism for these nuclei with electric quadrupole moments is provided by the coupling of these moments to the thermal fluctuations of the local electric field gradient via Raman spin-phonon processes.

Magnetic relaxation measurement of infinite layer superconductor Sr$_{0.9}$La$_{0.1}$CuO$_2$

  • Kim, Heon-Jung;Kim, Mun-Seog;Cung, C.U.;Kim, Ji-Yeon;Lee, Sung-Ik
    • 한국초전도학회:학술대회논문집
    • /
    • v.10
    • /
    • pp.121-124
    • /
    • 2000
  • The time dependence of irreversible magnetization of grain aligned infinite layer superconductor Sr$_{0.9}$La$_{0.1}$CuO$_2$ was measured in temperature range of 2 K < T < 30 K for H= 0.5 T, 1.0 T and 1.5 T parallel to c-axis. From this, we calculated normalized flux creep rate S(T) ${\equiv}$ dlnM/dlnt and found that the temperature independent region in S(T) is significantly wide in comparision with other cuprate superconductors. Using the method of Maley et al., we also deduce the current density dependence of pinning potential and glassy exponent ${\mu}$.

  • PDF

Determination of Bulk Density and Internal Structure of Red Ginseng Root Using NMR (NMR을 이용한 홍삼의 용적밀도 측정 및 내부 조직 판별)

  • ;R. Ruan
    • Journal of Ginseng Research
    • /
    • v.22 no.2
    • /
    • pp.96-101
    • /
    • 1998
  • This paper describes the determination of bulk density and the discrimination of internal structure of red ginseng by nuclear magnetic resonance (NMR). The 102 red ginseng roots were tested for bulk density. The NMR properties measured by NMR parameters such as spin-lattice relaxation time ($T_1$) and spin-spin relaxation time ($T_2$) were determined using the low field proton NMR analyzer. Bulk density of red ginseng root showed a highly negative significant correlation (r=-0.8934) with the value of $T_1$, but a highly positive significant correlation (r=0.7672 and 0.5909) with the value of T21 (short T2) and T22 (long T2), respectively. Multiple regression equation, Y=-0.0069.$T_1$+0.3044.$T_{21}$-0.0156.$T_{22}$-0.6368, using the MNR parameter values of 80 red ginseng roots can effectively predict the bulk density of 22 red ginseng roots with the correlation coefficient of 0.9396 and the standard error of 0.086. The differences in the internal structure of normal and inside white part of red ginseng were easily found by the signal intensity of NMR image based on magnetic properties of proton nucleus.

  • PDF

A Study on the Mathematical Modeling of Human Pharyngeal Tissue Viscoelasticity (인두조직의 점 탄성특성의 수학적모델링에 관한 연구)

  • 김성민;김남현
    • Journal of Biomedical Engineering Research
    • /
    • v.19 no.5
    • /
    • pp.495-502
    • /
    • 1998
  • A mathematical model of viscoelasticity on the material property of human pharyngeal tissue utilizing Y.C. Fung's Quasi-linear viscoelastic theory is proposed based on cyclic load, stress relaxation, incremental load, and uniaxial tensile load tests. The material properties are characterized and compared with other biological materials' results. The mathematical model is proposed by combining two characteristic functions determined from the stress relaxation and uniaxial tensile load tests. The reduced stress relaxation function G(t) and elastic response function S(t) are obtained from stress relaxation test and uniaxial tensile load test results respectively. Then the model describing stress-time history of the tissue is implemented utilizing two functions. The proposed model is evaluated and validated by comparing the model's cyclic behaviour with experimental results. The model data could be utilized as an important information for constructing 3-dimensional biomechanical model of human pharynx using FEM(Finite Element Method).

  • PDF