• Title/Summary/Keyword: Synthetic solution

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Removal of nitrogen and phosphorus of the secondary effluent by electro-coagulation (전기응집을 이용한 2차 유출수의 질소.인 제거 공정 연구)

  • Han, Song-Hee;Chang, In-Soung
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.4
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    • pp.579-589
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    • 2012
  • To reduce extensive energy costs of the internal recycling for the purpose of denitrification in the advanced wastewater treatment, a post-treatment process using an electro-coagulation to treat nitrate in the secondary effluents is evaluated in this study. Removals of phosphorus and organics in the secondary effluents by the electro-coagulation were also evaluated to propose an alternative advanced wastewatert treatment process. A series of experiments of the electro-coagulation were carried out with the following 4 different samples: synthetic solution containing nitrate only, synthetic solution containing nitrate as well as phosphorus, secondary effluents from activated sludge cultivated in laboratory, and secondary effluents from real wastewater treatment plants. Removals of nitrate and phosphorus in the synthetic solution were 30 and 97 % respectively, which verified the feasibility of the process. Removals of nitrate, phosphorus and COD in the secondary effluents from the cultivated sludge in laboratory were 49, 90 and 19 % respectively. Removal efficiency of the total nitrogen, nitrrate, phosphorus and COD in the secondary effluent from real wastewater treatment plant were 50, 61, 98 and 80 % respectively. The removal of the total nitrogen was less than the nitrate as expected, which is due to the formation of ammonia nitrogen in the cathode. But the proposed scheme could be an energy saving and alternative process for the advanced wastewater treatment if further studies for the process optimization are carried out.

A study on removal of cesium and strontium from aqueous solution using synthetic Na-birnessite (나트륨-버네사이트를 이용한 수용액상의 세슘 및 스트론튬 제거에 관한 연구)

  • Cho, Yunchul;Seol, Bit Na
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.2
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    • pp.155-164
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    • 2013
  • The main purpose of this research was to examine the adsorption/ion exchange characteristics of radioactive species such as cesium and strontium onto synthetic Na-birnessite (sodium-birnessite). As part of efforts to investigate the sorption behavior of cesium and strontium onto synthetic Na-birnessite, batch isotherm tests were performed under different experimental conditions. Na-birnessite was synthesized by the oxidation of $Mn^{2+}$ ions in sodium hydroxide solution. The synthetic Na-birnessite was characterized by powder x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and Brunauer-Emmett-Teller (BET) surface area analysis. Cesium and strontium concentrations were determined by atomic absorption spectroscopy (AAS). The removal efficiency of strontium by Na-birnessite was around 95 % which was much higher than that of cesium (~ 32 %). The results imply that strontium has a higher affinity for Na-birnessite than cesium because strontium, divalent cation leads to larger electrostatic attraction than monovalent cesium.

Effect of Synthetic Hydrotalcite on Salt Water Resistance of Chloroprene rubber Foam (Synthetic Hydrotalcite가 클로로프렌 고무 발포체의 내염수성에 미치는 영향 연구)

  • Park, Eun Young;Seo, Eun Ho;Lim, Sung Wook
    • Textile Coloration and Finishing
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    • v.31 no.3
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    • pp.177-186
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    • 2019
  • In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

Mapping Digital Manufacturing Simulation to Synthetic Environment using SEDRIS (SEDRIS를 이용한 디지털 생산 시뮬레이션과 합성 환경 매핑)

  • Moon, Hong-Il;Han, Soon-Hung
    • Journal of the Korea Society for Simulation
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    • v.14 no.2
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    • pp.15-24
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    • 2005
  • The goal of a distributed simulation such as battle field simulation is to combine all kinds of simulations in the same synthetic environment and to make people interact at the same time. It is a key issue to share the same synthetic environment among simulations. To support reusability and affordability in the modeling and simulation area, DMSO(Defense Modeling and Simulation Office) of USA developed concepts such as HLA(High Level Architecture) and SEDRIS (Synthetic Environmental Data Representation and Interchange Specification). In the industrial simulation area, the digital manufacturing is the main stream. To reduce cost and to reuse simulation environment, the standardization becomes the focus of digital manufacturing. This study proposes to use SEDRIS to improve interoperability of manufacturing data. The simulation data of DELMIA, which is a leading commercial digital manufacturing solution, is mapped and translated into the SEDRIS transmittal format. Mapping of the manufacturing simulation data and the synthetic environment are implemented and verified through experiments.

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Preparation of Fine Silk Powder and It′s Application for Surface Modification (폐견사류의 미세분말화 및 표면 가공제 적용)

  • 이용우;이광길;여주홍;김종호
    • Journal of Sericultural and Entomological Science
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    • v.43 no.1
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    • pp.41-48
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    • 2001
  • The purification, dissolution and powdering of stained waste silk obtained from weaving and dyeing process were studied for the surface modification of textile fabric and plastic materials. The whiteness of stained waste silk could be improved through degumming and bleaching with sodium hydrosulfite. The water-soluble fibroin solution can be obtained by dissoving the degummed waste silk in a boiling solution of 50% calcium chloride for 60 minutes. The salts and heavy metals contained in fibroin solution were removed by electric dialysis, wool fiber filtration and gel filtration chromatography. The fibroin powder was prepared by using a fine grinder after the alkali treatment for weakening the silk fiber. The fine fibroin powder of particle size around 30 ㎛ was obtained with a ultra fine-mill, while it was finer below 10 ㎛ with a ball-mill. The dissolved or powdered silk was applied to the surface of fabric with addition of the binder (a urethane resin). The moisture content of polyester and nylon fabrics treated with the silk solution was improved due to hygroscopic property of silk. The fine fibroin powder mixed with the binder ws coated on the surface of synthetic film by use of the air pressed sprayer. It was revealed that the hygroscopicity as well as the softness of fibroin powder coated film was much improved. Therefore, it is thought that the fine silk fibroin powder is applicable as an coating agent for the surface modification of plastic and synthetic leather.

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Experimental and computational insights into the adsorption of a hydrazone-based heterocyclic compound on steel rebar in synthetic concrete pore solution (합성 콘크리트 공극 솔루션에서 철근에 히드라존 기반 헤테로고리 화합물의 흡착에 대한 실험 및 계산 통찰력)

  • Lgaz, Hassane;Karthick, Subbiah;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.73-74
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    • 2022
  • The corrosion inhibitive effect of a new hydrazone-based heterocyclic compound for steel in simulated concrete pore solution with 3.5 wt.% sodium chloride was investigated by experimental and computational techniques. Electrochemical studies, up to 30 days of immersion, and surface analysis (X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscope (SEM)) were performed to assess the corrosion protection abilities of investigated compound for steel rebar. Results showed that adding the organic compound to the chloride contaminated concrete pore solution decreased the corrosion rate of the steel rebar thanks to the effective adsorption of inhibitor molecules. After 30 days of immersion of steel rebar in inhibited chloride contaminated synthetic concrete pore solution, the inhibition efficiency exceeded 80% at low concentration of 1 mmol/L. Computational studies by Density Functional based Tight Binding (DFTB) method revealed the formation of covalent bonds between the hydrazone molecule and the iron surface.

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A Comparative Study on the Injection Rate Characteristics of Conventional and F-T Synthetic Gasoline Under Various Fuel Temperatures (다양한 연료온도 조건에 있어서의 기존 가솔린과 F-T합성 가솔린의 분사율 특성 비교 연구)

  • Jihyun Son;Gyuhan Bae;Seoksu Moon
    • Journal of ILASS-Korea
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    • v.28 no.3
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    • pp.143-149
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    • 2023
  • Amidst the drive towards carbon neutrality, interest in renewable synthetic e-fuels is rising rapidly. These fuels, generated through the synthesis of atmospheric carbon and green hydrogen, offer a sustainable solution, showing advantages like high energy density and compatibility with existing infrastructure. The physical properties of e-fuels can be different from those of conventional gasoline based on manufacturing methods, which requires investigations into how the physical properties of e-fuels affect the fuel injection characteristics. This study performs a comparative analysis between conventional and Fischer-Tropsch (F-T) synthetic gasoline (e-gasoline) across various fuel temperatures, including the cold start condition. The fuel properties of F-T synthetic and conventional gasoline are analyzed using a gas chromatography-mass spectrometry technique and the injection rates are measured using a Bosch-tube injection rate meter. The F-T synthetic gasoline exhibited higher density and kinematic viscosity, but lower vapor pressure compared to the conventional gasoline. Both fuels showed an increase in injection rate as the fuel temperature decreased. The F-T synthetic gasoline showed higher injection rates compared to conventional gasoline regardless of the fuel temperature.

Soft Solution Processing : Low-Energy Direct Fabrication of Advanced Inorganic Materials

  • Masahiro Yoshimura;한규승;Wojciech Suchanek
    • Bulletin of the Korean Chemical Society
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    • v.20 no.8
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    • pp.875-878
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    • 1999
  • A new concept ??soft solution processing?? has been introduced to fabricate advanced solid state materials in an economical, environmentally friendly, and energy and material efficient way. The prepared films show the desired and prospective properties despite of low temperature synthesis and no post-synthesis annealing. Successful examples demonstrate that soft solution processing is capable of preparing advanced materials with planned properties through the easy control of reaction conditions in a suitable aqueous solution in a single synthetic step without huge energy consumption and without any sophisticated equipment.

The Removal of Surfactants and Commercial Detergents by Oenanthe javanica (미나리를 이용한 계면활성성분 및 합성세제 제거에 관한 연구)

  • 김경민;최한영;신정식;나규환;이장훈
    • Journal of Environmental Health Sciences
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    • v.23 no.4
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    • pp.115-120
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    • 1997
  • The purpose of thesis was to investigate the removal efficiency of surfactants and commercial detergents by Oenanthe javanica that is one of aquatic plants in Korea. The experiment is concerned with measuring the concentrations of surfactants and commercial detergents in different media: 1) in pure water, 2) in water containing Oenanthe javanica, 3) in water containing Oenanthe javanica and commercial nutrients. The surfactants used in this research include linear alkylbenzene sulfonates (LAS), $\alpha$-sulfo fatty acid methyl esters(MES), and alkylbenzene sulfonates(ABS). Two commercial detergents designated as A and B were in the forms of power and liquid. The results showed that LAS and MES were more effectively removed by Oenanthe javanica probably because these have a chain of linear carbon than on ABS with a branched carbon structure. In the case of commercial detergents, when the except was performed on the basis of surfactants proportion, the removal trends were similar to LAS and MES. The 5-day cultivating test with initial concentration of 0.5-1.0 ppm surfactants showed that less than 10% was removed if no nutrients an Oenanthe javanica were added. When Oenanthe javanica was added into the sample solution containing surfactants, the removal efficiency was increased 100% for the solution containing 0.5-1.0 ppm 60-70% for 5-10 ppm. In addition, chlorisis on Oenanthe javanica was observed due to surfactants and commercial detergents for all three cases. To test the dependence of population density on nutrients, the initial population density was made 300 g/0.4 m$^2$. Throughout the 5-day experiment, the on Oenanthe javanica grew 20-25% with 0.5-1.0 ppm without the synthetic nutrients but by 5% with a high concentrations of 5-10 ppm. The population density was appeared to be independent of synthetic nutrients. The leaves were to be grown with synthetic nutrients, while roots were grown without synthetic nutrients. Based on this research, the fundamental data concerning cultivation and an adequate adjustment of the water condition can provide for the utilization of Oenanthe javanica in real water treatment system.

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Characteristics of the Sinusoidal Flux Continuous Operation Mode for the Submerged Flat-sheet Membrane Module in Cutting Oil Solution (절삭유 수용액내 침지식 평막 모듈에 대한 사인파형 투과유속 연속운전 방식의 특성)

  • Won, In Hye;Chung, Kun Yong
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.646-652
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    • 2015
  • In this study transmembrane pressure (TMP) was measured with respect to permeate flux through the submerged flat sheet membrane for the emulsion and semi-synthetic cutting oil solutions. The effective area and nominal pore size of the used microfiltration membrane were $0.02m^2$ and $0.15{\mu}m$, respectively. The experiments were carried out simultaneously for run/stop (R/S) and sinusoidal flux continuous operation (SFCO) modes using two submerged membrane module in the reservoir. TMP for the case of SFCO was maintained under 60% of R/S, and the effect on TMP drop decreased as the permeate flux increased for emulsion cutting oil solution. Membrane fouling for the semisynthetic solution showing low turbidity was induced lower comparing to the emulsion solution. Also, the effect on TMP drop for SFCO decreased during long-term operation.