• Title/Summary/Keyword: Synthetic division

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Removal of As(III) and Phenol by Multi-functional Property of Activated Carbon Impregnated With Manganese (망간첨착 활성탄의 다기능성을 이용한 3가 비소 및 페놀 제거)

  • Yu, Mok-Ryun;Hong, Soon-Chul;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.13 no.3
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    • pp.52-58
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    • 2008
  • Mn-impregnated activated carbon (Mn-AC) prepared at different conditions was applied in the treatment of synthetic wastewater containing both organic and inorganic contaminants. Phenol and As(III) was used as the representative organic and inorganic contaminants, respectively. After evaluation of the physicochemical characteristic and stability of Mn-AC, oxidation of As(III) as well as adsorption of phenol by activated carbon(AC) and Mn-AC were investigated in a batch reactor. To investigate the stability of Mn-AC, dissolution of Mn from each Mn-AC was measured pH ranging from 2 to 4. Although Mn-AC was unstable at a strong acidic condition, the dissoluted Mn was below 3 ppm at pH 4. XRD analysis of Mn-AC indicated that the mineral type of the impregnated manganese was $Mn_2O_3$. From the simultaneous treatment of As(III) and phenol by AC and Mn-AC, As(III) oxidation by Mn-AC was greater than that by AC at lower pH, while the reverse order was observed at higher pH. After impregnation of Mn onto AC, 13% decrease of the surface area was observed, causing 8% reduction of phenol removal. Considering removal properties of As(III) and phenol, Mn-AC could be applied in the simultaneous treatment of wastewater contaminated with multi-contaminants.

Optimal Design of Stiffness of Torsion Spring Hinge Considering the Deployment Performance of Large Scale SAR Antenna (전개성능을 고려한 대형 전개형 SAR 안테나의 회전스프링 힌지의 강성 최적설계)

  • Kim, Dong-Yeon;Lim, Jae Hyuk;Jang, Tae-Seong;Cha, Won Ho;Lee, So-Jeong;Oh, Hyun-Ung;Kim, Kyung-Won
    • Journal of Aerospace System Engineering
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    • v.13 no.3
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    • pp.78-86
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    • 2019
  • This paper describes the stiffness optimization of the torsion spring hinge of the large SAR antenna considering the deployment performance. A large SAR antenna is folded in a launch environment and then unfolded when performing a mission in orbit. Under these conditions, it is very important to find the proper stiffness of the torsion spring hinge so that the antenna panels can be deployed with minimal impact in a given time. If the torsion spring stiffness is high, a large impact load at the time of full deployment damages the structure. If it is weak, it cannot guarantee full deployment due to the deployment resistance. A multi-body dynamics analysis model was developed to solve this problem using RecurDyn and the development performance were predicted in terms of: development time, latching force, and torque margin through deployment analysis. In order to find the optimum torsion spring stiffness, the deployment performance was approximated by the response surface method (RSM) and the optimal design was performed to derive the appropriate stiffness value of the rotating springs.

Lacquer as Adhesive : Its Historical Value and Modern Utilization (접착제로서의 옻; 역사성과 현대적 활용)

  • Jang, Sung Yoon
    • Korean Journal of Heritage: History & Science
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    • v.49 no.4
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    • pp.114-125
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    • 2016
  • Lacquer is one of the most widely used natural resin in East Asia since Neolithic Age. As a major ingredient of lacquerware, lacquer is waterproof, insect-proof and rot-proof to be durable and anti-abrasion, generally utilized for mainly painting purpose. According to lacquerware excavated from several sites of Japan and China, lacquerware seems to appear in Neolithic Age. On the other hand in case of excavation research in Korea, lacquerwares are found after the Bronze Age. The initial purpose of lacquer is estimated to be adhesive, regarding the literatures mentioning bitumen(Yeoksceong ), animal glue(Kyeo) and egg alumen(Nanbaek). Especially piece of jar coffin unearthed in Pyeongtaek Daechu-ri site had trace of restoration by lacquer and hemp as an evidence of lacquer for adhesion in Pre-Three Kingdoms period. Since then a trend to restore the broken ceramics with lacquer and decorate with golden foil lasted especially in Joseon Dynasty. In the field of gold plated lacquer method, mother-of-pearl inlaying technique for lacquerware and restoration of buildings, lacquer is still used as adhesive. Due to matter of reversibility lacquer is being avoided for conservation and restoration of cultural heritage. Lacquer as a traditional material for adhesive since ancient times, however, has advantage in adhesion strength and durability. Because synthetic resin adhesive has problem of emission of volatile organic compounds and aging over time, lacquer receives attention recently. On the contrary, by combination adhesive from mixing lacquer and animal glue, already proved the possibility of applicability and chemical modification. A research to utilize lacquer as modern paint or functional material is also conducted continuously also in China and Japan. To put traditional material into practical use and modernize, chemical research from the molecular level of the lacquer is necessary in the near future.

A Study on the Utilization of SAR Microsatellite Constellation for Ship Detection (선박탐지를 위한 초소형 SAR 군집위성 활용방안 연구)

  • Kim, Yunjee;Kang, Ki-mook
    • Korean Journal of Remote Sensing
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    • v.37 no.3
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    • pp.627-636
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    • 2021
  • Although many studies on ship detection using synthetic aperture radar (SAR) satellite images are being conducted around the world, there are still very few employing SAR microsatellites, as most of the microsatellites are optical satellites. Recently, the ICEYE and Capella Space have embarked on the development of microsatellites with SAR sensor, and similar projects are being initiated globally in line with the flow of the new space era [e.g., for the ICEYE: 18 satellites (~2021); Capella Space: 36 satellites (~2023); and the Coast Guard SAR: 32 satellites in the early development stage]. In preparation for these new systems, it is important to review the SAR microsatellite system and the recent advances in this technology. Accordingly, in this paper, the current status and characteristics of optical and SAR microsatellite constellation operation are described, and studies using them are investigated. In addition, based on the status and characteristics of the representative SAR microsatellites, specifically the ICEYE and Capella systems, methods for using SAR microsatellite data for ship detection applications are described. Our results confirm that the SAR microsatellites operate as a constellation and have the advantages of short revisit cycles and quick provision of high-resolution images. With this technology, we expect SAR microsatellites to contribute greatly to the monitoring a wide-area target vessel, in which the spatiotemporal resolution of the imagery is especially important.

Study on Material Characteristic of Daegu Modern History Museum Collection Rickshaw (대구근대역사관 소장 인력거 재질분석 연구)

  • Lee, Ui Cheon;Lee, Yeong Ju;Kim, Soo Chul
    • Journal of Conservation Science
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    • v.38 no.2
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    • pp.133-143
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    • 2022
  • In this study, we analyzed the rickshaw (Owned by the Daegu Modern History Museum) by measuring each material. The purpose of the study was to identify the materials in modern cultural assets that utilize a variety of materials in a complex way, and establish basic data for preservation and management. Using portable X-ray fluorescence analyzers (P-XRF), species identification, fiber identification, paint film analysis (microscope observation, SEM-EDS, FTIR) on metal, wood, fiber and paint was carried out. Brass, an alloy of Copper, Zinc and Iron, was measured in the metal parts. Further, wooden parts, such as Oak (Quercus acutissima), Japanese Cedar (Cryptomeria japonica), Bamboo (Bambusoideae). Torreya nucifera (Torreya spp.) were identified in the body. Fiber parts consisted mainly of cotton, but some parts were also made of leather. In terms of paint, rickshaws were applied with multiple layers, using cashew (synthetic paint used in place of lacquer). In sum, the rickshaw body part appeared to overlap with layers of fiber, metal (soild), paint, and colored (black, red) layer.

Growth performance, carcass traits, muscle fiber characteristics and skeletal muscle mRNA abundance in hair lambs supplemented with ferulic acid

  • Pena-Torres, Edgar Fernando;Castillo-Salas, Candelario;Jimenez-Estrada, Ismael;Muhlia-Almazan, Adriana;Pena-Ramos, Etna Aida;Pinelli-Saavedra, Araceli;Avendano-Reyes, Leonel;Hinojosa-Rodriguez, Cindy;Valenzuela-Melendres, Martin;Macias-Cruz, Ulises;Gonzalez-Rios, Humberto
    • Journal of Animal Science and Technology
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    • v.64 no.1
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    • pp.52-69
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    • 2022
  • Ferulic acid (FA) is a phytochemical with various bioactive properties. It has recently been proposed that due to its phytogenic action it can be used as an alternative growth promoter additive to synthetic compounds. The objective of the present study was to evaluate the growth performance, carcass traits, fiber characterization and skeletal muscle gene expression on hair-lambs supplemented with two doses of FA. Thirty-two male lambs (n = 8 per treatment) were individually housed during a 32 d feeding trial to evaluate the effect of FA (300 and 600 mg d-1) or zilpaterol hydrochloride (ZH; 6 mg d-1) on growth performance, and then slaughtered to evaluate the effects on carcass traits, and muscle fibers morphometry from Longissimus thoracis (LT) and mRNA abundance of β2-adrenergic receptor (β2-AR), MHC-I, MHC-IIX and IGF-I genes. FA increased final weight and average daily gain with respect to non-supplemented animals (p < 0.05). The ZH supplementation increased LT muscle area, with respect to FA doses and control (p < 0.05). Cross-sectional area (CSA) of oxidative fibers was larger with FA doses and ZH (p < 0.05). Feeding ZH increased mRNA abundance for β2-AR compared to FA and control (p < 0.05), and expression of MHC-I was affected by FA doses and ZH (p < 0.05). Overall, FA supplementation of male hair lambs enhanced productive variables due to skeletal muscle hypertrophy caused by MHC-I up-regulation. Results suggest that FA has the potential like a growth promoter in lambs.

Covalent Organic Framework Based Composite Separation Membrane: A Review (공유 유기 골격체 기반 복합 분리막 : 고찰)

  • Jeong Hwan Shim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.149-157
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    • 2023
  • Covalent organic frameworks (COFs) have shown promise in various applications, including molecular separation, dye separation, gas separation, filtration, and desalination. Integrating COFs into membranes enhances permeability, selectivity, and stability, improving separation processes. Combining COFs with single-walled carbon nanotubes (SWCNT) creates nanocomposite membranes with high permeability and stability, ideal for dye separation. Incorporating COFs into polyamide (PA) membranes improves permeability and selectivity through a synthetic interfacial strategy. Three-dimensional COF fillers in mixed-matrix membranes (MMMs) enhance CO2/CH4 separation, making them suitable for biogas upgrading. All-nanoporous composite (ANC) membranes, which combine COFs and metal-organic framework (MOF) membranes, overcome permeance-selectivity trade-offs, significantly improving gas permeance. Computational simulations using hypothetical COFs (hypoCOFs) demonstrate superior CO2 selectivity and working capacity relevant for CO2 separation and H2 purification. COFs integrated into thin-film composite (TFC) and polysulfonamide (PSA) membranes enhance rejection performance for organic contaminants, salt contaminants, and heavy metal ions, improving separation capabilities. TpPa-SO3H/PAN covalent organic framework membranes (COFMs) exhibited superior desalination performance compared to traditional polyamide membranes by utilizing charged groups to enable efficient desalination through electrostatic repulsion, suggesting their potential for ionic and molecular separations. These findings highlight COFs' potential in membrane technology for enhanced separation processes by improving permeability, selectivity, and stability. In this review, COF applied for the separation process is discussed.

Current Status and Management of Nanoplastics Exposed in Environment (환경 중 노출되는 나노플라스틱의 현황 및 관리실태)

  • Ha-neul Park;Jeonggue Park;Younghun Kim
    • Clean Technology
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    • v.30 no.1
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    • pp.1-12
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    • 2024
  • Nanoplastics (NP) exhibit distinct material properties compared to microplastics (MP), necessitating their separate recognition. Review of research outcomes and policy documents on NP reveals that most policy frameworks predominantly define MPs as solid synthetic polymer materials measuring 5 mm or less, but do not distinguish them from NP. However, recent revisions in regulations by the EU classify NPs as particles that range in size from 1 to 1,000 nm, as confirmed by some academic studies. Research on NPs often relies on experimental investigations centered around water systems, with a focus on high-concentration experimental conditions using spherical polystyrene-based NPs in behavior and impact studies. Notably, the environmental behavior characteristics of NP show differences in influence depending on the NP type, emphasizing the need for field simulation research. These challenges are mirrored in Korean society, so it is necessary to redefine NP to be distinct from MP in both research and policy. This study aimed to assess the current state of NP management globally and domestically and highlight policy considerations and issues in the existing response to NP. Upon comprehensive review, it becomes apparent that reaching an international agreement on MP faces methodological limitations, which could potentially burden efforts to precisely define NP size. Therefore, referencing the EU's recent regulatory revisions is crucial in domestic policy. Specific adjustments should commence from the MP concept through insights from the domestic industry, guidance from the academic community, and thorough discussions to ensure social acceptance.

Geochemical exploration for REE occurrence in Nghe An Area within Northern Vietnam (베트남 북부 네안 희토류 산출지의 지구화학탐사)

  • Heo, Chul-Ho;Chung, Ho Tien;Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.599-622
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    • 2012
  • The phase I soil geochemical exploration was carried out targeting around Chau Binh area far from about 14 km with southeastern direction from Quy Chau within Nghe An province. The interval of sampling are horizontal 300 m with 14 line and longitudinal 500 m with 15 line, resulting in 194 soil samples. Based on the result of the phase I soil geochemical exploration, the phase II detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 56 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and Dai Loc gneissic granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite(about 300 g/t) and xenotime(about 10 g/t) to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the phase I soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.84 times). As a analysis result with ICP-MS on the soil samples from the phase II soil detailed pit survey, we identified outcrop considering as economic ore body at the grid point 4-7 pit with N40W attitude. As a synthetic consideration on the phase I soil geochemical exploration and phase II detailed pit survey, we tentatively designated areas considering as the extension of economic ore body with REE anomaly. In the near future, we have the plan to carry out the geophysical exploration and test drilling targeting the interval anticipated to the economic ore body.

Residual Toxicity of Bifenthrin and Imidacloprid to Honeybee by Foliage Treatment (Bifenthrin과 Imidacloprid의 작물잎에서의 잔류량과 꿀벌에 대한 독성)

  • Cho, Kyung-Won;Park, Hyun-Ju;Bae, Chul-Han;Kim, Yeon-Sik;Shin, Dong-Chan;Lee, Seung-Yeol;Lee, Suk-Hee;Jung, Chang-Kook;Park, Yeon-Ki;Kim, Byung-Seok;Lee, Kyu-Seung
    • The Korean Journal of Pesticide Science
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    • v.14 no.3
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    • pp.226-234
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    • 2010
  • Foliage residue toxicity experiment was performed against honeybee (Apis mellifera) with bifenthrin, a synthetic pyrethroid insecticide with strong acute contact toxicity and imidacloprid, a neo-nicotinoid insecticide with strong acute oral toxicity to know the honeybee toxicity at the residue level on the leaves of alfalfa and apple. Also, the formulation differences to honeybee toxicity were investigated with WP (2%) and EC (1%) of bifenthrin and WP (10%) and SL (4%) of imidacloprid. Generally, foliage residual toxicity of honeybee and residual amounts of tested insecticides was higher in alfalfa leaves with large leaf area per unit weight than in apple leaves. While on the other hand, the only bifenthrin WP treatment showed higher honeybee toxicity on apple leaves than alfalfa. Although imidacloprid showed higher residue amounts ranged $4.9{\sim}25.4\;mg{\cdot}kg^{-1}$ than bifenthrin ranged $0.6{\sim}12.7\;mg{\cdot}kg^{-1}$ on the leaves, the residual toxicity to honeybee was lower than bifenthrin because of its strong penetration character. In conclusion, the residual toxicity of insecticide to honeybee could be affected by the contact and vaporized toxicity of chemical, the residual amounts on the surface of leaves, and the leaf area per unit weight and formulation differences.