• Environmental Engineering Research
• /
• 제16권3호
• /
• pp.137-148
• /
• 2011

In this study, a series of experiments was conducted on the relative degradation of commonly known endocrine-disrupting compounds such as bisphenol A (BPA) and $17{\alpha}$-ethinyl estradiol (EE2) in a single-component aqueous solution using 28 and 580 kHz ultrasonic reactors. The experiments were conducted with three different types of model water: deionized water (DI), synthetic brackish water (SBW), and synthetic seawater (SSW) at pH 4, 7.5, and 11 in the presence of inert glass beads and humic acids. Significantly higher sonochemical degradation (93-97% for BPA) occurred at 580 kHz than at 28 kHz (43-61% for BPA), regardless of water type. A slightly higher degradation was observed for EE2 compared to that of BPA. The degradation rate of BPA and EE2 in DI water, SBW, and SSW after 30 min of ultrasound irradiation at 580 kHz increased slightly with the increase in pH from 4 (0.073-0.091 $min^{-1}$ for BPA and 0.081-0.094 $min^{-1}$ for EE2) to 7.5 (0.087-0.114 $min^{-1}$ for BPA and 0.092-0.124 $min^{-1}$ for EE2). In contrast, significant degradation was observed at pH 11 (0.149-0.221 $min^{-1}$ for BPA and 0.147-0.228 $min^{-1}$ for EE2). For the given frequencies of 28 and 580 kHz, the degradation rate increased in the presence of glass beads (0.1 mm and 25 g) for both BPA and EE2: 0.018-0.107 $min^{-1}$ without beads and 0.052-0.142 $min^{-1}$ with beads for BPA; 0.021-0.111 $min^{-1}$ without beads and 0.054-0.136 $min^{-1}$ with beads for EE2. A slight increase in degradation of both BPA and EE2 was found as the concentration of dissolved organic carbon (DOC, humic acids) increased in both SBW and SSW: 0.107-0.115 $min^{-1}$ in SBW and 0.087-0.101 $min^{-1}$ in SSW for BPA; 0.111-0.111 $min^{-1}$ in SWB and 0.092-0.105 $min^{-1}$ in SSW for EE2. After 30 min of sonicating the humic acid solution, DOC removal varied depending on the water type: 27% (3 mg $L^{-1}$) and 7% (10 mg $L^{-1}$) in SBW and 7% (3 mg $L^{-1}$) and 4% (10 mg $L^{-1}$) in SSW.

• 한국산학기술학회논문지
• /
• 제13권6호
• /
• pp.2465-2471
• /
• 2012

선박이나 심해저 해양플랜트와 같이 가혹한 해양환경에서 사용되는 강구조물에서 부식피로는 설계수명과 관련하여 해결을 요하는 중요한 문제이다. 본 연구에서는 전기방식중 과도한 전기방식이 부식피로균열 전파거동에 미치는 영향을 고찰하기 위하여 근래 사용이 확대되고 있는 고장력 TMCP에 대하여 합성해수중 -950mV vs. SCE의 과방식 인가전압 환경에서 부식피로균열 전파시험을 실시하고 da/dN-${\Delta}K$ 선도를 구하였다. 이 선도에서 저 ${\Delta}K$ 영역에서는 해수중 전파속도보다 빠른 균열전파속도를 나타내었으나, 고 ${\Delta}K$영역으로 갈수록 해수중 보다 늦은 균열전파속도를 나타내었다. 부식피로균열 전파속도에 영향을 미치는 인자로서 가속요인과 감속요인으로 나누고 각각 수소기체와 석회질생성물의 역할에 대하여 고찰하였다.

• 대한원격탐사학회지
• /
• 제38권6_2호
• /
• pp.1709-1722
• /
• 2022

지구온난화로 인해 발생한 기온 상승은 엘니뇨, 라니냐 현상을 초래하였고, 해수의 온도를 비정상적으로 변화시켰다. 해수 온도의 비정상적인 변화는 특정 지역에 강우가 집중되는 현상을 발생시켜 이상 홍수를 빈번하게 일으킨다. 홍수로 인한 인명 및 재산 피해를 복구하고 방지하기 위해서는 침수피해 지역을 신속하게 파악하는 것이 중요한데 이는 합성개구레이더(synthetic aperture radar, SAR)를 통해 가능하다. 본 연구에서는 멀티 커널(kernel) 기반의 수정된 U-NET과 TerraSAR-X 영상을 활용하여 다양한 특성 맵 추출을 통해 반전 잡음(speckle noise)의 효과를 저감하고, 홍수 전, 후의 두 장의 영상을 입력자료로 활용해 홍수 발생 지역을 직접적으로 도출해내는 모델을 제작하고자 한다. 이를 위해 두 장의 SAR 영상을 전처리하여 모델의 입력자료를 제작하였고, 이를 수정된 U-NET 구조에 적용하여 홍수 탐지 딥러닝 모델을 학습시켰다. 해당 방법을 통해 평균 F1 score 값이 0.966으로 높은 수준으로 홍수 발생 지역을 탐지할 수 있었다. 이 결과는 수해 지역에 대한 신속한 복구 및 수해 예방책 도출에 기여할 것으로 기대된다.

• 한국생산제조학회지
• /
• 제6권3호
• /
• pp.65-72
• /
• 1997

The horizontal corrosion fatigue tester has been developed for investigating environmental strength. Using this tester, we investigated about corrosion fatigue caracteristics for A106-Gr B steel weldments in 3.5% synthetic seawater and room temperature. Considered parameter is only frequency of 1, 3 and 5Hz.. and Corrosion fatigue crack length was measured by DC potential difference method. From the results, we could find that the horizontal corrosion fatigue tester could be well applied to estimation of fatigue strength. and, In case of 5Hz., corrosion fatigue crack growth pate of A106-Gr B steel weldment was transgranular, and of 1 and 3Hz. showed that transgranular and interfranular was mixed. Also, Material constants of corrosion fatigue crack growth estimated in each frequency were C=9.33$\times$$10^{-9}$ and m=2.93 in 1Hz., C=9.77$\times$$10^{-10}$ and m=3.47 in 3Hz., C=1.02$\times$$10^{-10}$ and m=4.05 in 5Hz

• 한국공작기계학회:학술대회논문집
• /
• 한국공작기계학회 1997년도 춘계학술대회 논문집
• /
• pp.143-149
• /
• 1997

the horizontal corrosion fatigue tester has been developed for investigating environmental strength. Using this tester, we investigated about corrosion fatigue caracteristic for A106 GrB steel weldments in 3.5% synthetic seawater and room temperature. Considered parameter is only frequency of 1,3 and 5Hz. and Corrosion fatigue crack length was measured by DC potential difference method. From the results, we could find that the horizontal corrosion fatiued tester could be well applied to estimation of fatigue strength. and In case of 5Hz, corrosion fatigue crack growth path of A106 GrB steel weldment was transgranular, and of 1 and 3Hz showed that transgranular and intergranular was mixed. Also, Corrosion fatigue crack growth caracteristic values estimated in each frequency were C=9.33 x 10-9 and m=2.93 in 1Hz, C=9.77x10-10 and m=3.47 in 3Hz, C=1.02x10-10 and m=4.05 in 1Hz

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 1999년도 특별강연 및 춘계학술발표대회 개요집
• /
• pp.241-244
• /
• 1999

The purpose of this study is to examine the characteristics of stress corrosion cracking(SCC) and acoustic emission(AE) signals for the weld HAZ of HT-60 steel under corrosion control in synthetic seawater. Corrosive environment was controlled by potentiostat, and SCC experiment was conducted using a slow strain rate test method at strain rate of 10$^{-5}$ /sec. In order to verify the miroscopic fracture behaviour of the weldment during SCC phenomena, AE test was done simultaneously. Besides, correlationship between mechanical parameters and AE ones was investigated. In case of the parent, reduction of area(ROA) at -0.5V was samller than any other applied voltage such as -0.8V and -1.1V. In addition, reduction of area for the PWHT specimens at -0.8mV was larger than that of the weldment due to the softening effect according to PWHT. In case of the weldment, a lots of events was produced because of the singularities of the weld HAZ compared with the parent.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2013년도 춘계학술대회 논문집
• /
• pp.39-42
• /
• 2013

자동차 및 에너지 산업의 적용을 목표로 고망간강의 기계적 성질 향상 연구가 활발히 진행된 반면 내식성 연구는 미비하다. 본 연구에서는 염수 환경 및 H2S 환경에서 4종의 고망간강의 내식성에 미치는 크롬 및 망간의 영향을 조사하였다. 비교재로 사용된 탄소강 대비 실험재의 부식 속도는 침지 실험을 통해 얻어졌다. 또한 내식성 기구 고찰을 위하여 상평형 프로그램을 통하여 녹 층을 예측하고, 침지실험으로부터 얻어진 녹 층을 XRD, SEM-EDS 및 TEM-EDS로 분석하였다. 3.5% NaCl 용액에서 크롬 및 망간이 모두 내식성을 향상시킨 반면, synthetic seawater에서는 크롬만이 내식성을 향상시켰다. 또한 이들 염수 환경과 달리 H2S 환경에서 크롬과 망간 모두 내식성을 향상시키지 못했다. 환경에 따라 강의 내식성에 미치는 합금 원소의 영향이 상이한 원인은 각각의 환경에서 형성된 녹층의 구성 물질의 차이에 의한 것으로 이에 대하여는 본문의 된 녹 층 분석 결과에서 자세히 설명되었다.

• 한국양식학회지
• /
• 제16권4호
• /
• pp.203-209
• /
• 2003

Nitrification efficiency of fixed film biofilters with sand, loess bead, and styrofoam bead in biofilter columns of 1-m height and 30 cm width was studied. Synthetic wastewater was continuously supplied to the culture tank to maintain total ammonia nitrogen (TAN) concentration in the inflow water at around 8 mg/L. The hydraulic loading rate was set at 200 ㎥/$m^2$/day. TAN conversion was stabilized after about 90 day conditioning for all the selected filter media but with net accumulations of nitrite. On the volumetric basis, conversion rates of TAN and nitrite were the highest in styrofoam bead filter. Mean volumetric TAN conversion rates in the final samples were 682, 269, and 79 g TAN/㎥/day in the styrofoam bead, sand and loess bead filters, respectively. Low gravity and cost of styrofoam bead render the handling easier and more cost-effective.

• 한국해양공학회지
• /
• 제7권1호
• /
• pp.147-155
• /
• 1993

The effect of stress waveforms on corrosin fatigue and the role of dissolution mechanism in 3NilCr steel and 20Ni maraging steel have been investigated in aerated 3% NaCl solution and synthetic seawater under sinusoidal, triangular, square, positive sawtooth, negative sawtooth, and trapezoidal stress waveforms with open circuit at frequency of 1Hz and stress ratio of 0.1. The crack growth rates under square waveform were substantially lower than under sinusoidal and triangular waveforms, but the crack growth rates under sinusoidal waveform were slightly higher under triangular waveform. For a given frequency the growth rates under the positive sawtooth waveform are higher than those under the negative sawtooth waveform. The fatigue crack growth rates of most specimens were in good agreement with the values calculated by the model based on the dissoultion mechanism.

• 한국막학회:학술대회논문집
• /
• 한국막학회 1996년도 제5회 산학협동 심포지움 (먹는 물과 막분리공정)
• /
• pp.121-145
• /
• 1996

Due to more stringent regulations in drinking water, membrane separation has been playing an increasingly important role. Seawater desalination by reverse osmosis is a typical example and has been used world-wide. Although the existing technology based on coagulation and media filtration is well established and reliable technology, with the advance of industrial and agricultural activities it is difficult for this technology to remove contaminants such as nitrate and synthetic organic chemicals. To meet the drinking water standards and produce higher quality water, several membrane filtration research programs have been initiated which include Japanese MAC21 and New MAC21 projects. In this paper, potable water application of reverse osmosis (RO) and nanofiltration(NF) and their case histories will be explained in more detail.