• 제목/요약/키워드: Synthesis mechanism

검색결과 995건 처리시간 0.03초

Reaction Mechanism for Zeolite A Synthesis from Hadong Kaolin (하동 고령토로부터 Zeolite A 합성 반응기구)

  • 권영수;김면섭
    • Journal of the Korean Ceramic Society
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    • 제20권3호
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    • pp.255-259
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    • 1983
  • Am(rphous aluminosilicate zeolite A and hydroxysodalite were obtained by reaction of Hadong kaolin(halloysite) with IN sodium hydroxide solntion in the temperature range of 60 to 10$0^{\circ}C$ For determination of the mechanism of the reaction Various possible mechanisms were compared with the experimental results. It was observed that the reaction mechamism of zeolite A synthesis from Hadong kaolin was first order consecu-tive reaction as follows : halloysitelongrightarrowamorphous aluminosilicatelongrightarrowzeolite Alongrightarrowhydroxysodalite

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Role of Intracellular $Ca^{2+}$ in the Lovastatin-Induced Stimulation of Melanin Synthesis in B16 Melanoma Cells (B16 흑색종세포에서 로바스타틴에 의한 멜라닌 합성 촉진효과에 미치는 세포내 칼슘의 역할)

  • Lee, Yong Soo
    • YAKHAK HOEJI
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    • 제57권1호
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    • pp.24-31
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    • 2013
  • Although statins, inhibitors of 3-hydroxy-3-methylglutaryl-coenzyme A (HMG-CoA) reductase, have been shown to increase melanin synthesis, the exact mechanism of this action is not fully understood. In this study we investigated the possible involvement of intracellular $Ca^{2+}$ signal in the mechanism of stimulation of melanin synthesis induced by lovastatin in B16 cells. Lovastatin stimulated the production of melanin in a dose-dependent manner in the cells. Treatment with mevalonate, FPP and GGPP, precursors of cholesterol, did not significantly suppress the lovastatin-induced melanin production, suggesting that inhibition of cholesterol synthesis may not be involved in the mechanism of the action of lovastatin. In addition, lovastatin did not significantly alter the cAMP concentration and the stimulated production of melanin by lovastatin was not significantly changed by treatment with H89, a potent inhibitor of protein kinase A, which demonstrates that cAMP pathway may not be involved. However, lovastatin increased intracellular $Ca^{2+}$ concentration in a dose-related fashion. Treatment with EGTA, an extracellular $Ca^{2+}$ chelator did not significantly alter the lovastatin-induced intracellular $Ca^{2+}$ increase and melanin synthesis, whereas intracellular $Ca^{2+}$ reduction with BAPTA/AM and intracellular $Ca^{2+}$ release blockers (dantrolene and TMB-8) completely blunted these actions of lovastatin. Taken together, these results suggest that the intracellular $Ca^{2+}$ release may play an important role in the lovastatin-induced stimulation of melanin synthesis in B16 cells. These results further suggest that lovastatin may be useful for the treatment of hypopigmentation disorders, such as vitiligo.

Dimensional Syntheris and Kinematic Analysis of RSCS-SSP Spatial Mechanism with use of the Displacement Matrix Method (변위행렬법을 이용한 RSCS-SSP 공간기구의 치수합성과 운동해석)

  • 강희용
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 한국공작기계학회 1997년도 춘계학술대회 논문집
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    • pp.113-118
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    • 1997
  • This paper presents the dimensional synthesis and kinematic analysis of the RSCS-SSP motion generating spatial mechanism using the displacement matrix method. This type of spatial mechanisms is used for the Mcpherson suspension in small automobiles. It is modeled for the wheel bump/rebound and steering motion. First, the suspension is modeled as a multiloop spatial rigid body guidance mechanism for the two major motions. Then the design equations for SSP, RS, and SC strut links are applied to synthesize an RSCS-SSP for up to three prescribed positions for the steering motiom from the suspension design specification. Thus a RSCS-SSP mechanism which is synthesized is also analyzed for the displacement during the steering motion.

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ACCURATE SYNTHESIS OF SEEDLING SEPARATING-PLANTING MECHANISM OF RICE TRANSPLANTER

  • Hu, Hanxiang;Chen, Dejun;Wang, Changbing;Li, Zhenyong;Wu, Jienian;Xu, Jinda
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
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    • pp.284-290
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    • 1993
  • In order to improve the adaptability of rice transplanter to seeding with different length when transplanting multicropping rice in south China. The seedling separating planting mechanism is resynthesized in the paper. According to the agronomy requirements of seedling's transplanting, optimum motional path of the tip point of planting needle is obtained. by applying the established kinematic model of the separating planting mechanism, the relevant software is compiled. On the basis of the features of the problem, the constrained optimization method is utilized to solve the problem with 24 restrictions. Thus, the optimum structure parameters are obtained to satisfy the path points accurately.

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Growth mechanism of InP and InP/ZnS synthesis using colloidal synthesis (반응 용기법을 이용한 InP/ZnS 양자점 합성과정에서 InP 코어의 성장기구)

  • Seo, Han wook;Jeong, Da-woon;Lee, Bin;Hyun, Seoung kyun;Kim, Bum Sung
    • Journal of Powder Materials
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    • 제24권1호
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    • pp.6-10
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    • 2017
  • This study investigates the main growth mechanism of InP during InP/ZnS reaction of quantum dots (QDs). The size of the InP core, considering a synthesis time of 1-30 min, increased from the initial 2.56 nm to 3.97 nm. As a result of applying the proposed particle growth model, the migration mechanism, with time index 7, was found to be the main reaction. In addition, after the removal of unreacted In and P precursors from bath, further InP growth (of up to 4.19 nm (5%)), was observed when ZnS was added. The full width at half maximum (FWHM) of the synthesized InP/ZnS quantum dots was found to be relatively uniform, measuring about 59 nm. However, kinetic growth mechanism provides limited information for InP / ZnS core shell QDs, because the surface state of InP changes with reaction time. Further study is necessary, in order to clearly determine the kinetic growth mechanism of InP / ZnS core shell QDs.

Functional Verification of the Solar Panel Separation Mechanism for Pico-Class Satellite Applications Using Spring-loaded Pogo-pin (포고핀을 활용한 극초소형 위성용 태양전지판 분리장치의 기능검증)

  • Kim, Su-Hyeon;Jeon, Young-Hyeon;Kim, Hong-Rae;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • 제12권5호
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    • pp.69-75
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    • 2018
  • In this study, we proposed a nylon wire cutting-type solar panel separation mechanism for CubeSat applications using spring-loaded pogo-pins, which has been widely used as temporary electrical interface between two separate electronics. The mechanism proposed in this study has great advantages of higher holding capability, ability to constrain along in-plane and out-of-plane directions of solar panels, simplicity in tightening of nylon wire and synchronous separation of multiple panels. In addition, the pogo-pins used for the proposed mechanism act as electrical power interface, separation status switch and separation spring. In this study, the functionality of the proposed mechanism was validated through the separation tests with various number of nylon wire windings.

Inhibitory Effect of Persimmon Leaves on Melanin Synthesis and its Action Mechanism in B16F10 cells (시엽(枾葉)의 멜라닌 생성 억제와 작용기전에 관한 연구)

  • Jang, Du-Hyun;Yoo, Dong-Youl
    • The Journal of Korean Obstetrics and Gynecology
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    • 제22권2호
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    • pp.43-59
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    • 2009
  • Purpose: This study was performed to determine the inhibitory effect of Persimmon Leaves extract (PL) on melanin synthesis in B16F10 melanoma cells B16F10. Methods: The inhibitory effects of PL on melanin synthesis were determined by in vitro assay. To elucidate inhibitory effects of PL on melanin synthesis, we determined the melanin release and melanin production in B16F10. And to investigate the action mechanism, we assessed the gene expression of tyrosinase, TRP-1, TRP-2, PKA, PKC${\beta}$, ERK-1, ERK-2, AKT-1, MITF in B16F10. Results: 1. PL inhibited melanin release, melanin production in B16F10. 2. PL inhibited tyrosinase activity in vitro and in B16F10. 3. PL suppressed the expression of tyrosinase, TRP-1, TRP-2 in B16F10. 4. PL suppressed the expression of PKA, PKC${\beta}$ in B16F10. 5. PL increased the expression of ERK-1, ERK-2, AKT-1 in B16F10. 6. PL suppressed the expression of MITF in B16F10. Conclusion: From these results, it may be concluded that PL is possesed of the antimelanogenetic effects.

Exploration of growth mechanism for layer controllable graphene on copper

  • Song, Woo-Seok;Kim, Yoo-Seok;Kim, Soo-Youn;Kim, Sung-Hwan;Jung, Dae-Sung;Jun, Woo-Sung;Jeon, Cheol-Ho;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.490-490
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    • 2011
  • Graphene, hexagonal network of carbon atoms forming a one-atom thick planar sheet, has been emerged as a fascinating material for future nanoelectronics. Huge attention has been captured by its extraordinary electronic properties, such as bipolar conductance, half integer quantum Hall effect at room temperature, ballistic transport over ${\sim}0.4{\mu}m$ length and extremely high carrier mobility at room temperature. Several approaches have been developed to produce graphene, such as micromechanical cleavage of highly ordered pyrolytic graphite using adhesive tape, chemical reduction of exfoliated graphite oxide, epitaxial growth of graphene on SiC and single crystalline metal substrate, and chemical vapor deposition (CVD) synthesis. In particular, direct synthesis of graphene using metal catalytic substrate in CVD process provides a new way to large-scale production of graphene film for realization of graphene-based electronics. In this method, metal catalytic substrates including Ni and Cu have been used for CVD synthesis of graphene. There are two proposed mechanism of graphene synthesis: carbon diffusion and precipitation for graphene synthesized on Ni, and surface adsorption for graphene synthesized on Cu, namely, self-limiting growth mechanism, which can be divided by difference of carbon solubility of the metals. Here we present that large area, uniform, and layer controllable graphene synthesized on Cu catalytic substrate is achieved by acetylene-assisted CVD. The number of graphene layer can be simply controlled by adjusting acetylene injection time, verified by Raman spectroscopy. Structural features and full details of mechanism for the growth of layer controllable graphene on Cu were systematically explored by transmission electron microscopy, atomic force microscopy, and secondary ion mass spectroscopy.

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