• Title/Summary/Keyword: Synthesis condition

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Synthesis and Characterization of Copper Oxide nanowires by Facile Heating under Static Air Condition

  • Kwon, Tae-Ha;Choi, Hyek-Hwan;Chung, Wan-Young
    • Journal of information and communication convergence engineering
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    • v.8 no.1
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    • pp.99-102
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    • 2010
  • Large-scaled area and aligned copper oxide nanowires have been synthesized by a vapor-phase approach to the facial synthesis of copper oxide nanowires supported on the surface of a copper gasket. The effects of annealing temperature and time were investigated. Long and aligned nanowires can only formed within a narrow temperature range from 400 to $500^{\circ}C$ for 4 hrs. Annealing copper gasket in static air produces large-area, uniform, but not well vertically aligned nanowires along the copper gasket surface. The surface of copper gasket is converted into bicrystal CuO nanowires was observed after the copper gasket is annealed under static air condition.

Analysis of a Flexible Multi-body System with Over-constraints (여유구속을 갖는 유연체 기계시스템의 동역학 해석)

  • Seo, Jong-Hwi;Park, Tae-Won;Chae, Jang-Soo;Seo, Hyun-Seok
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.874-880
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    • 2003
  • Many mechanical systems are over-constrained if only rigid bodies are used to model the system. One example of such system is a satellite system with solar panels. To avoid this over-constrained problem, solar panels can be modeled as flexible bodies. The CMS(Component Mode Synthesis) method is widely used to analyze the flexible multi-body system because it can considerably approximate the deformation of the flexible bodies using small number of well-selected mode. However, it is very difficult to decide the boundary condition and the selection of modes. In this paper, the methods for mode synthesis and setting the boundary condition are presented to analyze the flexible multi-body system with over-constraints. Finally, the reliability of proposed method is verified by solar panel's deployment test.

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Stspension Culture of Betalain Producing Cell-Line and Characteristics of Hairy Root of Phytolacca esculenta V. Houtte (장록에서 유도한 Betalain 합성 세포주의 액체 배양과 모상근의 특성)

  • 양덕조;이성종윤길영강영희
    • KSBB Journal
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    • v.8 no.1
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    • pp.89-94
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    • 1993
  • Thc effect of light and phylohormonc on the belalaln synthesis was tested using the suspension culture of a rod(bclalaln produulng) cell line from Phytolacca esculenta V. Houtte. Betalain synthesis of rod-cell 1ine was strongly dependent on the irradiation of blue light, but induced by hormone, IAA and/or kinetin, in dark conditions. In a light condition, however, 2 mg/l of IAA increased the betalain content about 30% (per gram fresh weight), whereas more than 0.5mg/l of kinetin remarkably decreased. The hairy root derived from the same plant was also observed for the blue light-dependent pigmentation in the root-tips. When the hairy root grown in dark was transferred to the light condition, the accumulation of betalain was initiated after 12hours. Such pigmentation was completely inhabited by addition of a protein synthesis inhibitor.

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THE EFFECTS OF pH, TEMPERATURE AND TIME ON THE SYNTHESIS OF HYDROXYAPATITE (pH, 온도 및 시간이 수산화인회석의 합성에 미치는 영향)

  • Lee, Hee-Joo;Hur, Bock
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.27-44
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    • 1994
  • The purpose of this study was to determine the effects of pH, temperature and time on the synthesis of hydroxyapatite(HAP) by spontaneous precipitation under relatively physiologic condition. Specimens were obtained from aqueous system with various pH, temperature and experimental time. Chemical composition, crystallographic structure and crystallinity of the synthetic HAP were evaluated by Infrared spectroscopy and powdered X-ray diffraction method. The following results were obtained. 1. No precipitate was obtained under pH 5.5. 2. All the specimens were concluded as HAP except one that was obtained under the condition of pH 6.5, $25^{\circ}C$ and 1 day. It was concluded as dicalcium phosphate dihydrate(DCPD). 3. The crystallinity of HAP was enhanced by increases in pH, temperature and time of the preparation. But, the crystallinity of the synthetic HAP was lower than that of the mineral HAP. 4. Intermediates such as DCPD and octacalcium phosphate were formed on the process of the synthesis of HAP.

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Characterizations of Denitrifying Polyphosphate-accumulating Bacterium Paracoccus sp. Strain YKP-9

  • Lee, Han-Woong;Park, Yong-Keun
    • Journal of Microbiology and Biotechnology
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    • v.18 no.12
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    • pp.1958-1965
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    • 2008
  • A denitrifying polyphosphate-accumulating bacterium (YKP-9) was isolated from activated sludge of a 5-stage biological nutrient removal process with step feed system. This organism was a Gram-negative, coccus-shaped, facultative aerobic chemoorganotroph. It had a respiratory type of metabolism with oxygen, nitrate, and nitrite as terminal electron acceptors. The 16S rRNA gene sequence of strain YKP-9 was most similar to the 16S rRNA gene sequence of Paracoccus sp. OL18 (AY312056) (similarity level, 97%). Denitrifying polyphosphate accumulation by strain YKP-9 was examined under anaerobic-anoxic and anaerobic-oxic batch conditions. It was able to use external carbon sources for polyhydroxyalkanoates(PHA) synthesis and to release phosphate under anaerobic condition. It accumulated polyphosphate and grew a little on energy provided by external carbon sources under anoxic condition, but did neither accumulate polyphosphate nor grow in the absence of external carbon sources under anoxic condition. Cells with intracellular PHA cannot accumulate polyphosphate in the absence of external carbon sources under anoxic condition. Under oxic condition, it grew but could not accumulate polyphosphate with external carbon sources. Based on the results from this study, strain YKP-9 is a new-type denitrifying polyphosphate-accumulating bacterium that accumulates polyphosphate only under anoxic condition, with nitrate and nitrite as the electron acceptors in the presence of external carbon sources.

Hydrothemal Synthesis of $PbTiO_3$ Powders (수열법에 의한 $PbTiO_3$ 분말 합성)

  • 박병규;이태근;이기강
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.399-404
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    • 1996
  • Hydrothemal synthesis of PbTiO3 has been investigated. A comprehensive thermodynamic model for heteroge-nous reacting solid-aquous system has been used to predict the optimum condition for the synthesis. Synthesis were performed using lead acetate trihydrate as Pb source crystalline TiO2 as Ti source and KOH as minerali-zer. The synthesis has been examined at low temperature (16$0^{\circ}C$) Phase pure perovskite PbTiO3 has been obtained at high pH(above 0.5 mol KOH). The morphology of PbTiO3 was acicular shape. It has been found sible for a distortion in the c direction. The water is gradully released on annealing the powder to 40$0^{\circ}C$ and the normal crystallographic properties are restored.

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Hydrothermal Synthesis of 6mol% Yttria Stabilized Cubic ZrO2 Nano Powders (이트리아 안정화 지르코니아 나노 분말 합성)

  • Lee, Jae-Hoon;Bae, Sung-Hwan
    • Korean Journal of Materials Research
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    • v.27 no.8
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    • pp.445-450
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    • 2017
  • YSZ (Yttria-stabilized zirconia) is a ceramic material that is used for electronic and structural materials due to its excellent mechanical properties and specific electrical characteristics according to the Yttrium addition. Hydrothermal synthesis has several advantages such as fine particle size, uniform crystalline phase, fast reaction time, low process temperature and good dispersion condition. In order to synthesize YSZ nanoparticles with high crystallinity, hydrothermal synthesis was performed at various concentrations of NaOH. The hydrothermal process was held at a low temperature ($100^{\circ}C$), with a short process time (2,4,8 hours); the acidity or alkalinity of solution was controlled in a range of pH 2~12 by addition of NaOH. The optimum condition was found to be pH 12, at which high solubility levels of Y(OH) and Zr(OH) were reported. The synthesized nano powder showed high crystallinity and homogenous composition, and uniform particle size of about 10 nm.

Effect of Intensity of Unconditional Stimulus on Reconsolidation of Contextual Fear Memory

  • Kwak, Chul-Jung;Choi, Jun-Hyeok;Bakes, Joseph T.;Lee, Kyung-Min;Kaang, Bong-Kiun
    • The Korean Journal of Physiology and Pharmacology
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    • v.16 no.5
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    • pp.293-296
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    • 2012
  • Memory reconsolidation is ubiquitous across species and various memory tasks. It is a dynamic process in which memory is modified and/or updated. In experimental conditions, memory reconsolidation is usually characterized by the fact that the consolidated memory is disrupted by a combination of memory reactivation and inhibition of protein synthesis. However, under some experimental conditions, the reactivated memory is not disrupted by inhibition of protein synthesis. This so called "boundary condition" of reconsolidation may be related to memory strength. In Pavlovian fear conditioning, the intensity of unconditional stimulus (US) determines the strength of the fear memory. In this study, we examined the effect of the intensity of US on the reconsolidation of contextual fear memory. Strong contextual fear memory, which is conditioned with strong US, is not disrupted by inhibition of protein synthesis after its reactivation; however, a weak fear memory is often disrupted. This suggests that a US of strong intensity can inhibit reconsolidation of contextual fear memory.

A Study on the Hydrothermal Synthesis of Clay Mineral (III) -Scale up Test for the Hydrothermal Synthesis of Clay Mineral from Anorthite and the Automatic Control System Development- (수열반응에 의한 인공점토의 합성연구(III) -경남 산청산 회장석으로부터 교반식 수열 반응장치에 의한 인공점토의 대량생산 실험 및 수열반응의 자동 조절 제어장치 개발-)

  • ;;Kunio Kimura
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.777-782
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    • 1995
  • The scale up production test for the hydrothermal synthesis of clay mineral from the anorthite, which is distributed in San Chung-District of Korea and called as the ground rock for halloysite-kaolin, has been investigated by using the gaitator type reactor. The automatic control system has been developed and applied for the more effective producibility and the reduction in the defect of this intermittent batch processing property, and finally for the feasibility of this system in actual use. It was observed that this agitator type reactor can reduce the synthesis reaction tme from 5 days to 3 days, only with the condition of 20rpm. The automatic control system could regulate the vessel temperature and pressure precisely at an optimum condition during the treatment. Therefore, from these test results the application-possibility for this system was found to be feasible in actual use.

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Synthesis of TiO2 Nanowires by Thermal Oxidation of Titanium Alloy Powder (타이타늄 합금 분말의 열적산화를 통한 TiO2 나노와이어의 합성)

  • Kim, Yoo-Young;Cho, Kwon-Koo
    • Journal of Powder Materials
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    • v.25 no.1
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    • pp.48-53
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    • 2018
  • One-dimensional rutile $TiO_2$ is an important inorganic compound with applicability in sensors, solar cells, and Li-based batteries. However, conventional synthesis methods for $TiO_2$ nanowires are complicated and entail risks of environmental contamination. In this work, we report the growth of $TiO_2$ nanowires on a Ti alloy powder (Ti-6wt%Al-4wt%V, Ti64) using simple thermal oxidation under a limited supply of $O_2$. The optimum condition for $TiO_2$ nanowire synthesis is studied for variables including temperature, time, and pressure. $TiO_2$ nanowires of ${\sim}5{\mu}m$ in length and 100 nm in thickness are richly synthesized under the optimum condition with single-crystalline rutile phases. The formation of $TiO_2$ nanowires is greatly influenced by synthesis temperature and pressure. The synthesized $TiO_2$ nanowires are characterized using field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and high-resolution transmission electron microscopy (HR-TEM).