• 한국분말재료학회지
• /
• 제19권6호
• /
• pp.442-445
• /
• 2012

The quantum dots (QD) have unique electrical and optical properties due to quantum dot confinement effect. The optical properties of QDs are decided by various synthesis conditions. In a prior QDs study, a study on the QDs size with synthesis condition such as synthesis time and temperature is being extensively researched. However, the research on QDs size with composition ratio has hitherto received scant attention. In order to evaluate the ratio dependence of CdSe crystal, synthesis ratio of Se precursor is changed from 16.7 mol%Se to 44 mol%Se. As the increasing Se ratio, the band gap was increased. This is caused by red shift of emission. We confirmed optical property of CdSe QDs with composition ratio.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 하계학술대회 논문집
• /
• pp.554-557
• /
• 2001

In this work, we had synthesis the GaN powder by direct reaction between Ga and NH$_3$at the temperature range of 1000∼1150$^{\circ}C$, and investigated the reaction condition dependence of the GaN yield and some properties of GaN powder. The synthesized powder had Platelet and prismatic shape and showed hexagonal crystalline structure with the lattice constants of a= 3.1895 ${\AA}$, c= 5.18394 ${\AA}$, and the ratio of c/a = 1.6253. The GaN powder synthesis processes were examined based on the oxidation process of mater, and found as combined with mass transport process for the initial stage and diffusion-limited reaction for the extended reaction.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 1996년도 춘계학술대회 논문집
• /
• pp.437-442
• /
• 1996

The paper presents a design method of dynamic positioning control system for floating platform with rotatable and retractable thruster using $H_{\infty}$control technique. The norm band of uncertaintyis captured by multiplicative perturbation between nominalmodel and reduced order model. A controller robust to theuncertainty is designed applying $H_{\infty}$synthesis. The control law satisfying robust stability and nominal performance condition is determined through the mixed sensitivity approach. The evaluation for the resultant controller obtained by $H_{\infty}$synthesis is done through simulations of the closed loop system. The results of $H_{\infty}$synthesis are compared to those of the traditional LQ synthesis method. method.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2007년도 추계학술대회 논문집
• /
• pp.109-110
• /
• 2007

Pyrrole and DNA can be used for synthesis of conducting nanowires. Protonated pyrrole and negatively charged DNA are absorbed by electrostatic interaction. The level of absorbance is related to pH of pyrrole. Therefore, DNA immobilized and aligned on the 3-aminopropyltrimethoxysi1ane (APTES) modified Si surface. Positive pyrrole monomers was deposited on aligned DNA for the synthesis of nanowire in various pH condition. And polypyrrole nanowires were synthesized by polimerization with ammonium persulfate (APS). These polypyrrole nanowires were measured by AFM, and then we found optimal pH level for the synthesis of nanowires.

• 제어로봇시스템학회논문지
• /
• 제7권11호
• /
• pp.896-903
• /
• 2001

This study investigates the use of mixed $H_2/H_{$\infty}$ and $\mu$-synthesis to construct a robust controller for the benchmark problem. The model treated in the problem is a coupled three-inertial system that reflects the dynamics of mechanical vibrations. This kind of problem requires to be satisfied the robust performance (both in the time and frequency-domain specifications). We, first, adopt the mixed $H_2/H_{$\infty}$ theory to design a feedback controller K(s). Next, $\mu$-synthesis method is applied to the overall system to make use of structured parametric uncertainty. This process permits higher levels of controller authority and reduces the conservativeness of the controller. Finally, the feedforward controller is also used to improve the transient response of the output. We confirm that all design specifications except a complementary sensitivity condition can be achieved.

• 한국세라믹학회지
• /
• 제22권6호
• /
• pp.29-36
• /
• 1985

This study was carried out to research on the optimum condition of $MgAl_2O_4$ spinel synthesis and the chara-ceteristics of its sintered bodies. In this study the used materials-MgO $Al_2O_3$-were prepared from the extragrade chemicals $Mg(OH)_2 Al(OH)_3$ respectively. The tendency to spinel synthesis and sintering condition were discussed about additives of SEM and the characteristics of sintered bodies were measured by TMA etc, The results were as follows ; 1. The addion of $TiO_2$ promoted more effectively the sinterbility than that of $MnO_2$. 2. Residual $\alpha$-$Al_2O_3$ and MgO in theorectical composition samples were disappeared at 1$600^{\circ}C$ 3. When added MnO2 residual $\alpha$-$Al_2O_3$ and MgO were disappeared at 150$0^{\circ}C$ and 1$600^{\circ}C$ respectively. 4, . When added $TiO_2$ residual $\alpha$-$Al_2O_3$ and MgO were disappeared at 150$0^{\circ}C$ and 134$0^{\circ}C$ respectively.

• 한국소음진동공학회논문집
• /
• 제16권8호
• /
• pp.814-821
• /
• 2006

A structural coupling method is developed for the dynamic analysis of a nonlinear structure with concentrated nonlinear hinge joints or sliding lines. The component mode synthesis method is extended to couple substructures and the nonlinear models. In order to verify the improved coupling method, a numerical plate model consisting of two substructures and torsional springs, is synthesized by using the proposed method and its modal parameters are compare with analysis data. Then the coupling method is applied to a three-substructure-model with the nonlinearity of sliding lines between the substructures. The coupled structural model is verified from its dynamic analysis. The analysis results show that the improved coupling method is adequate for the structural nonlinear analyses with the nonlinear hinge and sliding mode condition.

• Bulletin of the Korean Chemical Society
• /
• 제24권4호
• /
• pp.460-466
• /
• 2003

For the drug master file (DMF) of ketoconazole, four impurities (1-4) contained in ketoconazole were synthesized. During the synthesis of 2, a new synthetic method of 1,4-dihydropyrazine was established. To oxidize the aminoalcohol (2j) to the aminal (2j-1), the standard Swern oxidation condition was modified to mask the nucleophilicity of the amino group temporarily using one equivalent of acetic acid. Derivative 3 was synthesized via regioselective bromination at the 2 position of the 4-aminophenol derivative (3a) using $Br_2$ in the presence of p-TsOH. The etherification of aryl bromide with the phenol derivative (1f) was accomplished by a modification of the general Cu-mediated reaction condition using excess 1f itself as a solvent at elevated temperature (190 ℃).

• 대한화학회지
• /
• 제55권3호
• /
• pp.486-489
• /
• 2011

Potassium dihydrogen phosphate는 마이크로파 조사조건에서 용매 없이 페놀과 아세토아세트산 에틸의 Pechmann 축합반응에 의하여 쿠마린을 합성하는 효과적인 촉매로 밝혀졌다. 이 방법은 쿠마린 합성에 있어서 소량의 촉매를 필요로 하며 수율이 높고, 반응이 깨끗할 뿐만 아니라 반응 시간이 짧은 장점들을 가지고 있다.

• Advances in materials Research
• /
• 제3권2호
• /
• pp.117-128
• /
• 2014

Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.