• Title/Summary/Keyword: Synergetic effect

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Fabrication of a Hybrid Superhydrophobic/superhydrophilic Surface for Water Collection: Gravure Offset Printing & Colloidal Lithography (수분수집을 위한 초발수/초친수 복합 표면 제작: 그라비아 옵셋 프린팅과 콜로이달 리소그래피 공정)

  • Ji, Seung-Muk;Kim, In-Young;Kim, Eun-Hee;Jung, Jie-Un;Kim, Wan-Doo;Lim, Hyun-Eui
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.1
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    • pp.19-24
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    • 2012
  • We demonstrate the desert beetle back mimicking hybrid superhydrophilic/superhydrophobic patterned surface by using the combination method of colloidal lithography and gravure offset printing for nano and micro patterning, respectively. The two methods are cost-effective and industrially available techniques compared to the other nano/micro patterning methods. To verify the water collecting function of the hybrid surface, the water condensation behavior is investigated on the chilled surface in ambient temperature and high humidity. Due to the synergetic effect of drop and film wise condensation, the hybrid superhydrophobic/superhydrophilic surface shows the higher efficiency than one of single wettability surfaces. The work is underway to get the good patterns of hybrid surfaces for water collecting from the dew or fog.

Photocatalytic Activity of Hierarchical N doped TiO2 Nanostructures

  • Naik, Brundabana;Kim, Sun Mi;Jung, Chan Ho;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.669-669
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    • 2013
  • Hierarchical N doped TiO2 nanostructured catalyst with micro, meso and macro porosity have been synthesized by a facile self-formation route using ammonia and titanium isopropoxide precursor. The samples were calcined in different calcination temperature ranging from $300^{\circ}C$ to $800^{\circ}C$ at slow heating rate ($5^{\circ}C$/min) and designated as NHPT-300 to NHPT-800. $TiO_2$ nanostructured catalyst have been characterized by physico-chemical and spectroscopy methods to explore the structural, electronic and optical properties. UV-Vis diffuse reflectance spectra confirmed the red shift and band gap narrowing due to the doping of N species in TiO2 nanoporous catalyst. Hierarchical macro porosity with fibrous channel patterning was observed (confirmed from FESEM) and well preserved even after calcination at $800^{\circ}C$, indicating the thermal stability. BET results showed that micro and mesoporosity was lost after $500^{\circ}C$ calcination. The photocatalytic activity has been evaluated for methanol oxidation to formaldehyde in visible light. The enhanced photocatalytic activity is attributed to combined synergetic effect of N doping for visible light absorption, micro and mesoporosity for increase of effective surface area and light harvestation, and hierarchical macroporous fibrous structure for multiple reflection and effective charge transfer.

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Antimicrobial Activities of Extracts from Several Native and Exotic Plants in Korea (수 종의 한국자생식물과 귀화식물 추출액이 토양미생물에 미치는 항균활성)

  • Kim, Yong-Ok;Lee, Eun-Ju;Lee, Ho-Joon
    • The Korean Journal of Ecology
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    • v.23 no.5
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    • pp.353-357
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    • 2000
  • The soil pH favored by several native plants in Korea ranges 5.33∼7.20, while a more acidic range of pH 3.95∼6.10 is acceptable to exotic plants. Ethanol extracts of native and exotic plants in Korea were investigated for antimicrobial activity against Bacillus sphiaericus 2362, Bacillus thuringiensis var. subtilis and Bacillus thuringiensis var. cereus and Actinomycetes. Higher antimicrobial activity was observed from the extract of exotic plants than those of native plants. The ethanol extract of Ambrosia artemisiifolia var. elatior was observed to have the highest antimicrobial activity against 4 species of soil microbes. Especially, antimicrobial activity of Ambrosia artemisiifolia var. elatior showed the largest clear zone of 48mm in Actinomycetes. Larger clear zone was formed in the order of caffeic acid, benzoic acid and ρ -coumaric acid among the nine chemical compounds. Accordingly, the antimicrobial activity of Ambrosia artemisiifolia var elatior against Actinomycetes was found to be due to the synergetic effect of chemical compounds.

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CNT and CNF reinforced carbon fiber hybrid composites by electrophoresis deposition (전기영동법에 의한 탄소나노튜브 및 탄소나노섬유 강화 탄소섬유 하이브리드 복합재료)

  • Choi, O-Young;Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Kim, Jin-Bong;Choe, Hyeon-Seong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.7-12
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    • 2010
  • In order to increase the electrical conductivity and the mechanical properties of carbon fabric composites, multi-walled carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) were deposited on carbon fabrics by anodic and cathodic electrophoretic deposition (EPD) processes. In the cathodic EPD, carbon nano-particles and nano-sized Cu particles were simultaneously deposited on the carbon fabric, which gave a synergetic effect on the enhancement of properties as well as the degree of deposition. The hybridization of carbon nano-particles and micron-sized carbon fiber significantly improved the through-the-thickness electrical conductivity. In addition, both MWCNTs and CNFs were deposited onto the carbon fabric for multi-scale hybrid composites. Multi-scale deposition improved the through-the-thickness electrical conductivity, compared to the deposition of either MWCNTs or CNFs.

Ni Nanoparticles-Graphitic Carbon Nanofiber Composites for Pt-Free Counter Electrode in Dye-Sensitized Solar Cells (염료감응 태양전지의 비백금 상대전극을 위한 니켈 나노입자-흑연질 탄소나노섬유 복합체)

  • Oh, Dong-Hyeun;Koo, Bon-Ryul;Lee, Yu-Jin;An, HyeLan;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.649-655
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    • 2016
  • Ni nanoparticles (NPs)-graphitic carbon nanofiber (GCNF) composites were fabricated using an electrospinning method. The amounts of Ni precursor used as catalyst for the catalytic graphitization were controlled at 0, 2, 5, and 8 wt% to improve the photovoltaic performances of the nanoparticles and make them suitable for use as counter electrodes for dye-sensitized solar cells (DSSCs). As a result, Ni NPs-GCNF composites that were fabricated with 8 wt% Ni precursors showed a high circuit voltage (0.73 V), high photocurrent density ($14.26mA/cm^2$), and superb power-conversion efficiency (6.72%) when compared to those characteristics of other samples. These performance improvements can be attributed to the reduced charge transport resistance that results from the synergetic effect of the superior catalytic activity of Ni NPs and the efficient charge transfer due to the formation of GCNF with high electrical conductivity. Thus, Ni NPs-GCNF composites may be used as promising counter electrodes in DSSCs.

Synthesis of Fe3O4/porous Carbon Composite for Efficient Cu2+ Ions Removal (효과적인 Cu2+ 이온 제거를 위한 산화철(Fe3O4)/다공성 탄소 복합체 합성)

  • Seok, Dohyeong;Kim, Younghun;Sohn, Hiesang
    • Membrane Journal
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    • v.29 no.6
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    • pp.308-313
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    • 2019
  • In this study, the Fe3O4/porous carbon composite was synthesized by hydrothermal method for removal of Cu2+ ions and the characteristic of Cu2+ ions removal was performed. The Fe3O4/porous carbon composite was investigated via using SEM, XRD for its morphology and structure. BET analysis was conducted to conform a specific area and pore size distribution of the composite. For the investigation of the performance for removal of Cu2+ ions in the solution, UV-vis spectrometer was used. It suggests that a synergetic effect between magnetic Fe3O4 and porous carbon shows an improvement for removal of Cu2+ ions.

Analysis of sugars and total amino acids-content of young spring and fall-radish cotyledons and hypocotyls by cold and polyamine-treatments (저온과 Polyamine 처리에 의한 봄무우와 가을무우 자엽과 상배축에서 당류와 총 아미노산 분석에 관한 연구)

  • Cho, Bong-Heuy;Park, Sun Young
    • Analytical Science and Technology
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    • v.9 no.4
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    • pp.325-330
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    • 1996
  • The content of reducing sugars and sucroses was increased by cold- and PA-treatment in cotyledons of spring radish. But in cotyledons of fall radish, the content of reducing sugars, and sucroses was increased by cold treatment but was not increased by cold- and PA-treatment. Total free amino acids in cotyledons of spring radish were increased by cold treatment, but were not increased in cotyledons of fall radish. The results show that cold sensitive spring radishes were adapted by regulating of cellular osmosis and show that the physiological and biochemical metabolism of spring radish was much different from the fall radish. We report first that polyamine has synergetic effect with cold stress on cotyledons of spring radish, but not on cotyledons of fall radish.

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Mechanical Properties and Morphology of Polyamide 6/Maleated Polypropylene Blends (폴리아미드6/반응성 폴리프로필렌(PA6/PP-g-MA) 블렌드의 기계적 특성과 모폴로지)

  • Koh, Jae Song;Jang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1136-1140
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    • 1999
  • Melt blends of polymide 6(PA6) and polypropylene grafted maleic anhydride(PP-g-MA) were prepared to study the influence of chemical reaction between the two polymer components. The tensile, flexural, izod impact, dynamic mechanical properties and phase structure were investigated for this blend system. Tensile strength and modulus of the blends showed synergetic effect upon blending of two polymer components. Flexural properties maintained the value of numerical mean calculated from the weight ratio of two components. Also, notched izod impact strengths showed maximum in th PA6/PP-g-MA 50/50 wt % blend. From the change of tan ${\delta}$ observed, we confirmed the increase of miscibility in this blend system by chemical reaction between PA6 and PP-g-MA. Blends of good impact resistance could be obtained when the PP-g-MA particles of $2{\mu}m$ was dispersed in the PA6 matrix.

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The comparison of pathogenicity in the SPF chickens challenged with avian reovirus and/or fowl adenovirus (SPF 닭에서 레오바이러스와 아데노바이러스의 단일 혹은 혼합감염에 따른 병원성 비교)

  • Min, Kyeong-Cheol;Choi, Dong-Myong;Kim, Ji-Yea;Jeon, Eun-Ok;Byun, Sung-Hwan;Mo, In-Pil
    • Korean Journal of Veterinary Service
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    • v.34 no.2
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    • pp.139-148
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    • 2011
  • Avian reovirus (ARV) and fowl adenovirus (FAdV) were evaluated for pathogenicity in specific pathogen free (SPF) chickens. ARV was isolated from the broilers with history of malabsorption syndrome (MAS). FAdV was isolated from the layer breeders with inclusion body hepatitis and hydropericardium syndrome. Total 6 inoculated groups including 1 un-inoculated group were organized and inoculated with the ARV and/or FAdV by oral route. The minimal pathological lesions and lower viral gene detection rates were present in the ARV inoculated groups compared to those of FAdV or ARV/FAdV inoculated groups. Common gross lesions in the ARV inoculated group were distended intestine with foamy contents and in the FAdV group there were foamy cecal contents and hydropericardium among the evaluation methods such as gross and histological lesion, viral gene detection, body weight and serum chemistry, histopathological lesion score was reliable especially in the liver lesions such as hepatic necrosis and lymphocytic infiltration. However, we did not success to evaluate the synergetic effect of mixed infection of ARV and FAdV in this study. Therefore, we need further study to reproduce malabsorption syndrome of ARV infection using different viral agent such as rotavirus and using different dose of virus.

Hydrogel Dressing with a Nano-Formula against Methicillin-Resistant Staphylococcus aureus and Pseudomonas aeruginosa Diabetic Foot Bacteria

  • El-Naggar, Moustafa Y.;Gohar, Yousry M.;Sorour, Magdy A.;Waheeb, Marian G.
    • Journal of Microbiology and Biotechnology
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    • v.26 no.2
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    • pp.408-420
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    • 2016
  • This study proposes an alternative approach for the use of chitosan silver-based dressing for the control of foot infection with multidrug-resistant bacteria. Sixty-five bacterial isolates were isolated from 40 diabetic patients. Staphylococcus aureus (37%) and Pseudomonas aeruginosa (18.5%) were the predominant isolates in the ulcer samples. Ten antibiotics were in vitro tested against diabetic foot clinical bacterial isolates. The most resistant S. aureus and P. aeruginosa isolates were then selected for further study. Three chitosan sources were tested individually for chelating silver nanoparticles. Squilla chitosan silver nanoparticles (Sq. Cs-Ag0) showed the maximum activity against the resistant bacteria when mixed with amikacin that showed the maximum synergetic index. This, in turn, resulted in the reduction of the amikacin MIC value by 95%. For evaluation of the effectiveness of the prepared dressing using Artemia salina as the toxicity biomarker, the LC50 was found to be 549.5, 18,000, and 10,000 μg/ml for amikacin, Sq. Cs-Ag0, and dressing matrix, respectively. Loading the formula onto chitosan hydrogel dressing showed promising antibacterial activities, with responsive healing properties for the wounds in normal rats of those diabetic rats (polymicrobial infection). It is quite interesting to note that no emergence of any side effect on either kidney or liver biomedical functions was noticed.