• Title/Summary/Keyword: Surfactant solution

Search Result 560, Processing Time 0.032 seconds

Characteristics of Water Solutions Containing Nonionic Surfactants and Their Fire Fighting Performance (비이온성 계면활성제가 함유된 수용액의 특성과 소화성능)

  • 이윤우;이윤용;박양원
    • Fire Science and Engineering
    • /
    • v.16 no.3
    • /
    • pp.61-70
    • /
    • 2002
  • A fire extinguishing agent containing non-ionic surfactant which is environmentally friendly and low cost was prepared and tested its characteristics and fire fighting performance. Ethoxylated sorbitol septaoleate, containing 40 moles of ethylene oxide as the primary surfactant, linear ethoxylated secondary alcohol, containing 7-11 moles ethylene oxide as the secondary surfactant, and ethoxylated sorbitol trioleate, containing 40-50 moles of ethylene oxide were used in the agent. It is demonstrated that the water solution containing 6 wt% agent is capable to extinguish gasoline fire when it is put into the fire four times as much as gasoline. According to the field test of class B fire with a unit 1, it is found that the fire fighting performance is directly proportional to the concentration of surfactant in the agent.

Enhancement of Heat and Mass Transfer by Insert Spring in a Vertical Absorber with Surfactant

  • Yoon, Jung-In;Choi, Kwang-Hwan;Moon, Choon-Geun;Sarker M.M.A;Kwon, Oh-Kyung
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.28 no.8
    • /
    • pp.1239-1250
    • /
    • 2004
  • This research was concerned with the enhancement of heat transfer by surfactant added to the aqueous solution of LiBr. Different vertical tubes were tested with and without an additive of normal octyl alcohol. The test tubes are a bare inner surface. a groove inner surface, a corrugated inner surface and a spring inserted inner surface tubes. The additive concentration was about 0.08 mass%. The heat transfer coefficient was measured as a function of the film Reynolds number in the range of 20~200. Experiments were carried out at higher cooling water temperature of $35^{\circ}C$ to simulate an air cooling condition for several kinds of absorber testing tubes. The experimental results were compared with and without surfactant. The enhancement of heat transfer by Marangoni convection effect which was generated by addition of the surfactant is observed in each test tube. Especially, it is clarified that the tube with an inserted spring has the highest enhancement effect.

Drag Reduction Phenomena of Surfactant Turbulent Pipe Flows (계면활성제에 의한 난류 관내 유동의 마찰감소 현상)

  • Yoon, Hyung-Kee;Shin, Kwang-Ho;Chang, Ki-Chang;Ra, Ho-Sang;Yoo, Seong-Yeon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.18 no.12
    • /
    • pp.1025-1032
    • /
    • 2006
  • This is to characterize the fluid mechanics of surfactant water solutions, which exhibit drag reduction in the turbulent flow as compared to pure water. The emphasis is placed on those fluid characteristic aspects of drag reducing solutions which are relevant for application in closed circulation loops for the purpose of pumping power savings, like hydronic cooling and heating systems in buildings. The experiments are carried out with the solutions of the surfactant Beraid DR-IW 616 in concentration of $100{\sim}3,000ppm$. The following key parameters are focused in this study: surfactant concentration, solution temperature and pipe diameter.

Heat Transfer Performance of Various Tubes for an Air-cooled Absorber with Surfactant

  • Yoon, Jung-In;Kim, Eun-Pil;Moon, Choon-Geun;Kwon, Oh-Kyong
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • v.8 no.2
    • /
    • pp.1-10
    • /
    • 2000
  • This research is concerned with the enhancement of heat transfer by surfactant added to the aqueous solution of LiBr. Different vertical tubes were tested with and without an additive of normal octyl alcohol. The test tubes are a bare tube, a groove tube, a corrugated tube and a spring-inserted tube. The additive concentration is about 0.08 mass%. The heat transfer coefficient is measured as a function of the film Reynolds number in the range of 20~200. Experiments are carried out at higher cooling water temperature of $35^{\circ}C$to simulate an air cooling condition for several kinds of absorber testing tubes. The experimental results with and without surfactant are compared. The enhancement of heat transfer by Marangoni convection effect which is generated by addition of the surfactant is observed in each test tube. Especially, it is clarified that the tube with an spring-inserted has the enhancement effect.

  • PDF

Surface-Active Properties of Sodium bis-Alkyl Sulfonatosuccinate (술폰화된 호박산 알킬에스테르류의 계면성)

  • Kim, Myeong-Soo;Jeong, Hwan-Kyeong;Yoon, In-Young;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
    • /
    • v.18 no.2
    • /
    • pp.95-102
    • /
    • 2001
  • Recently, there has been considerably interested in the development to new functional gemini type anionic surfactant, sodium bis-n-alkyl sulfonatosuccinate, had been synthesized through the addition reaction of sodium bisulfite to bis-n-alkyl maleate, in which water was azeotropically distilled by adding benzene to the reaction system, gave a good yield. All the surface activities including krafft point, surface tension, emulsion power and foaming were measure and cmc was evaluated in dilute solution. This results showed a lower ability in $27{\sim}30dyne/cm$ than single-chain surfactant with $32{\sim}35dyne/cm$ to surface tension. Also its cmc value much smaller in $(6.5{\sim}10){\times}10^{-4}mca{\ell}/{\ell}$ than single-chain surfactant with $(40{\sim}45){\times}10^{-4}mca{\ell}/{\ell}$ concentration. In foaming ability and foam stability of gemini surfactant had especially a good ability in approximately $100{\sim}150ml$, and in emulsing power they exhibited a good emulsing phase and stability, and Krafft points were $0{\sim}10^{\circ}C$.

Suspension Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(part 3);Synthesis of Anionic Oligo Surfactant having Fluorescent Intensity and Their Properties (올리고머형 음이온성계면활성제 수용액에서 안료의 분산안정성(제 3보);형광성이 큰 올리고머 계면활성제의 합성 및 그의 계면성)

  • Lee, H.W.;Lee, J.H.;Ju, M.J.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
    • /
    • v.14 no.1
    • /
    • pp.109-115
    • /
    • 1997
  • Fluorescent anionic oligo surfactants were synthesized by the condensing products of long chain alkylvinylether-maleic anhydride cooligomers and resorcinol including dye structures. Their various surface activities and dispersing action were studied on the aqueous solution. These oligo surfactants exhibited a remarkable surface tension lowering property, lower foaming and a large dispersing action for the particles of ${\alpha}-copper$ phthalocyanine blue. Further it was ascertained that the binding of oligo surfactant onto the pigment surface caused the deviation towards lower wavelengths at the maximum fluorescent intensity as compared with aqueous oligo surfactant solutions, These surface active properties of the oligo surfactants may be attributed to rigid and hydrophobic structure of dye groups, besides surface-active groups of alkylether groups and carboxylic group of the anionic oligo surfactants.

Ultrasonic Synthesis of Silica Powder Using Emulsion Method (에멀젼법을 이용한 실리카 분말의 초음파 합성)

  • Lee, S.G.;Kim, H.S.;Kang, B.S.;Seo, G.S.;Park, S.S.;Park, H.C.
    • Korean Journal of Materials Research
    • /
    • v.16 no.6
    • /
    • pp.355-359
    • /
    • 2006
  • Fine silica powders were synthesized via w/o emulsion method using sodium silicate, ammonium sulfate, Triton N-57, and cyclohexane as silica source, precipitating agent, surfactant, and oil phase, respectively. The powders were prepared under a conventional process and an ultrasonic process using the same reactants at room temperature for 1 hr varying the concentration of $Na_2SiO_3$ solution and the mol ratio of $H_2O$/surfactant, respectively. The particle size of the silica powder was reduced with decreasing the concentration of sodium silicate solution and with increasing the mol ratio of $H_2O$/surfactant under with and without ultrasounds. The size of powder with ultrasounds was smaller than that without ultrasounds, which indicates that the application of ultrasound in the synthesis of silica powder is an efficient way to reduce particle size.

Comparative Quantitative Study of Surfactant Protein C mRNA by Filter Hybridization and Solution Hybridization in Rats (Filter Hybridization과 Solution Hybridization 방법에 의한 백서 Surfactant Protein C mRNA 정량측정의 비교)

  • Kim, Jin-Ho;Sohn, Jang-Won;Yang, Seok-Chul;Yoon, Ho-Joo;Shin, Dong-Ho;Park, Sung-Soo
    • Tuberculosis and Respiratory Diseases
    • /
    • v.51 no.6
    • /
    • pp.517-529
    • /
    • 2001
  • Background : Surfactant protein C(SP-C) is a hydrophobic 5,000 dalton molecule. SP-C has the primary roles in accelerating surface spreading of a surfactant phospholipid. The filter hybridization and solution hybridization assays are both rapid and sensitive and can be used to measure the RNAs complementary to any cloned DNA sequence. Methods : The authors measured the SP-C mRNA levels quantitatively using solution hybridization and filter hybridization assays to obtain a standard curve equation to quantify the mRNA of unknown samples comparatively. Results : 1. The minimum level of the specimens by solution hybridization was 3 pg for SP-C mRNA. 2. The standard curve equation of the solution hybridization assay between the counts per minute(Y) and the SP-C mRNA transcript input(X) was Y=6.46 X+244. The correlation coefficient was 0.99. 3. The minimum detection level of specimens by filter hybridization was 0.1 ng for SP-C mRNA. 4. The standard curve equation of the filter hybridization assay between the counts per minute(Y) and SP-C mRNA transcript input(X) is Y=2541.6 X+252.7. The correlation coefficient was 0.99. Conclusions : A comparison of CPM/filter in the linear range allowed an accurate and reproducible estimation of the SP-C mRNA copy number. Filter hybridization and solution hybridization assays are both rapid and sensitive and can be used to measure the RNAs complementary to any cloned DNA sequence. It is ideally suited to situations where accurate quantitation of multiple samples is required.

  • PDF

Preparation of Nano-sized Pt Powders by Solution-phase Reduction (액상환원법(液相還元法)에 의한 백금(白金) 나노분말(粉末) 제조(製造))

  • Kim, Chul-Joo;Yoon, Ho-Sung;Cho, Sung-Wook;Sohn, Jung-Soo
    • Resources Recycling
    • /
    • v.16 no.5
    • /
    • pp.36-40
    • /
    • 2007
  • Platinum plays an important role in many applications because of its extraordinary physical and chemical properties. All these applications require the use of platinum in the finely divided state. Therefore the preparation of platinum nanoparticles by reducing platinum-surfactant salt with reducing agent in the solution was investigated in this study. The net interaction between C14TABr and $H_2[PtCl_6]$ in aqueous solution results in the formation of $[C14TA]_2[PtCl_6]$. The concentration of C14TABr and the concentration of $H_2[PtCl_6]$ has to be above cmc and 0.32 mM, respectively in order to obtain complex-micelle aggregation for mono dispersed Pt particles. Pt particle size increases with increasing $H_2[PtCl_6]$ and C14TABr concentration. And the shape of Pt particles was well controlled with increasing surfactant concentration.

Transport of Phenol in Waste Water Through Liquid Surfactant Membrane (폐수중 액체막에 의한 페놀의 이동)

  • 우인성;김병석;김윤선
    • Journal of the Korean Society of Safety
    • /
    • v.5 no.3
    • /
    • pp.39-43
    • /
    • 1990
  • The transport of phenol from waste water through the liquid surfactant membrane containing Aliquat 336 as a carrier was analyzed by a theoretical model. Extraction experiments was carried out to investigate the effect of process parameters, such as mixing intensity, concentration of sodium hydroxide in internal aqueous solution, and counter anions, and initial phenol concentration in waste water at $25^{\circ}C$. It was found that transport rate of phenol increased with increasing pH differents. The transport rate of phenol in waste water was influenced by counter anions.

  • PDF