• 제목/요약/키워드: Surface plasmon

검색결과 439건 처리시간 0.026초

실리카 코어 금 위성입자의 합성 및 표면 증강 라만 산란을 기반으로 한 센서로의 응용 (Synthesis of Silica-Core Gold-Satellite Nanoparticles and Their Surface-enhanced Raman Scattering Based Sensing Application)

  • 최현지;김영국;윤석영;백연경
    • 한국분말재료학회지
    • /
    • 제21권6호
    • /
    • pp.441-446
    • /
    • 2014
  • In this study, we synthesize silica-core gold-satellite nanoparticles (SGNPs) for the surface-enhanced Raman scattering (SERS) based sensing applications. They consist of gold satellite nanoparticles (AuNPs) fixed on the silica core nanoparticles, which sizes of AuNPs can be tunned by varying the amount of reactants (growth solution and reducing agent). Their surface plasmon resonance (SPR) properties were characterized by using UV-vis spectroscopy, showing that the growth of AuNPs on silica cores leads to the light absorption in the longer wavelength region. Furthermore, the size increase of AuNPs exhibited the dramatic change in SERS activity due to the formation of hot spots. The optimized SGNPs showing enhancement factor ${\sim}3.8{\times}10^6$ exhibited a detection limit of rhodamine 6G (R6G) as low as $10^{-8}M$. These findings suggest the importance of size control of SGNPs and their SPR properties to develop highly efficient SERS sensors.

장거리 표면 프라즈몬을 이용한 은-피리딘계에서의 표면증강 라만산란 (Surface Enhanced Raman Scattering at Ag-Pyridine Interface by Use of Long Range Surface Plasmon)

  • 백문구;고의관;고도경;이해형;장준성
    • 한국광학회지
    • /
    • 제1권2호
    • /
    • pp.142-148
    • /
    • 1990
  • Sarid형의 감쇠 전반사 구조를 통하여 장거리 표면 프라즈몬을 여기시켜 은-피리딘 경계면에서 표면증강 라만산란 실험을 수행하였다. 장거리 표면 플라즈몬의 여기를 확인하기 위해 은을 $100\AA$으로 증착하여 실험한 결과, 그 진행을 눈으로 볼 수 있었다. 이것을 이용해서 은 표면에 흡착된 피리딘의 라만신호를 관측하여 체적 상태 및 화학적 흡착이 있는 경우의 피리딘의 라만신호와 비교, 분석하였는데 장거리 표면 프라즈몬을 이용한 표면증강 라만산란 실험을 아직까지 보고된 바 없다.

  • PDF

Direct Triazine Herbicide Detection Using a Self-Assembled Photosynthetic Reaction Center from Purple Bacterium

  • Nakamura, Chikashi;Hasegawa, Miki;Shimada, Kazumi;Shirai, Makoto;Miyake, Jun
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제5권6호
    • /
    • pp.413-417
    • /
    • 2000
  • In this study, a direct detection system for triazine derivative herbicides was developed using the photosynthetic reaction center (RC) from the purple bacterium, Rhodobacter sphaeroides, and surface plasmon resonance (SPR) apparatus. The histidine-tagged RCs were immobilized on an SPR gold chip using nickel-nitrilotriacetic acid groups as a binder for one of the triazine herbicide, atrazine. The SPR responses were proportional to the sample concentrations of atrazine in the range 0.1-1 $\mu\textrm{g}$/mL. The sensitivity of the direct detection of atrazine using the RC-assembled sensor chip was higher than that using the antibody-immobilized chip. The other types of herbicides, DCMU or MCPP, were not detected with such high sensitivity. The results indicated the high binding selectivity of the RC complex.

  • PDF

High System Performance with Plasmonic Waveguides and Functional Devices

  • Kwong, Wing-Ying
    • ETRI Journal
    • /
    • 제32권2호
    • /
    • pp.319-326
    • /
    • 2010
  • Photonics offers a solution to data communication between logic devices in computing systems; however, the integration of photonic components into electronic chips is rather limited due to their size incompatibility. Dimensions of photonic components are therefore being forced to be scaled down dramatically to achieve a much higher system performance. To integrate these nano-photonic components, surface plasmon-polaritons and/or energy transfer mechanisms are used to form plasmonic chips. In this paper, the operating principle of plasmonic waveguide devices is reviewed within the mid-infrared spectral region at the 2 ${\mu}m$ to 5 ${\mu}m$ range, including lossless signal propagation by introducing gain. Experimental results demonstrate that these plasmonic devices, of sizes approximately half of the operating free-space wavelengths, require less gain to achieve lossless propagation. Through optimization of device performance by means of methods such as the use of new plasmonic waveguide materials that exhibit a much lower minimal loss value, these plasmonic devices can significantly impact electronic systems used in data communications, signal processing, and sensors industries.

Development of SPR Gas Sensor for Small Molecules Using Molecularly Imprinted Polymer Thin Films

  • 장성우;진성일;박찬량
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 춘계학술발표대회
    • /
    • pp.242.2-242.2
    • /
    • 2011
  • Molecularly imprinted polymer thin films were applied to develop a gas sensor based on the surface plasmon resonance phenomenon for small gaseous molecules such as toluene and xylene. The imprinted polymer films were synthesized via photo-polymerization method using various combination of templates, functional monomers and cross-linkers. The temperature of pre-polymerization solutions and the power of UV light were controlled for optimized performance of gas sensing. The morphology and porosity of the polymer films were controlled by varying the mixing ratios of the pre-polymerization solutions and confirmed by atomic force microscopy. By fitting the adsorption/desorption sensorgrams to conventional kinetic models, the effects of different templates and cross-linkers were interpreted in term of the structural differences of the polymer networks formed on the gold film. The sensitivity and selectivity of sensors were estimated for toluene and xylene, and also for humidity and other gaseous molecules such as formaldehyde and ammonia.

  • PDF

광섬유 표면 플라즈몬 공명 센서를 이용한 스트레인 및 온도 측정 (Measurement of temperature and strain using fiber-optic surface plasmon resonance sensor)

  • 정재훈;김민욱
    • 전기전자학회논문지
    • /
    • 제11권2호
    • /
    • pp.77-82
    • /
    • 2007
  • 본 논문에서는 광섬유 표면 플라즈몬 공명 센서를 이용하여 스트레인 및 온도 변화에 따른 센서를 제시하였다. 광섬유 센서의 구조는 광섬유의 클래딩 일부를 제거하여 크롬, 은, 금을 증착한 다층 박막 구조를 모델로 하였고, dip 파장의 변화가 선형성을 보임으로써 효율적인 센서로의 활용 가능성을 보이고자 한다.

  • PDF

Highly flexible, transparent and low resistance IZO-Ag-IZO multilayer electrode for flexible OLEDs

  • Cho, Sung-Woo;Choi, Kwang-Hyuk;Jeong, Jin-A;Lee, Se-Hyung;Kim, Jang-Joo;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.609-612
    • /
    • 2008
  • Characteristics of indium-zinc-oxide (IZO)-Ag-IZO multilayer grown on a PET substrate were investigated for flexible organic emitting diodes. By inserting very thin Ag layer between amorphous IZO, IZO-Ag-IZO (IAI) multilayer anode exhibited remarkably reduced sheet resistance and high transmittance due to the surface plasmon resonance effect and Ag layer.

  • PDF

금 나노 입자의 표면 플라즈몬 공명 현상을 이용한 상변화 층에서의 전자기파 증폭 해석 (Analysis of electromagnetic field enhancement in the phase change material based on surface plasmon resonance induced by gold nanoparticles)

  • 강성묵;박노철;박영필;김수경;이학철;오명렬;나광훈;박강호;이성규;이형근;조용훈;김려화
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2009년도 춘계학술대회 논문집
    • /
    • pp.863-864
    • /
    • 2009
  • PDF

표면 플라즈몬 광섬유 편광기의 제작 및 특성 조사 (Fabrication and Characterization of Surface Plasmon Fiber-Optic Polarizers)

  • 김진하;김병윤
    • 한국광학회지
    • /
    • 제5권2호
    • /
    • pp.311-318
    • /
    • 1994
  • 광섬유의 클래딩을 갈아내고 코어 가까이에 알루미늄 박막을 증착하여 표면 플라즈몬으로의 편광 선택적인 모드 결합 원리를 이용하는 광섬유 편광기를 제작하였다. 633nm, 830nm, $1.3\mu\textrm{m}$의 단일 모드 광섬유를 사용하여 알루미늄 박막의 두께를 달리하며 소광률과 삽입손실을 측정한 결과 대부분의 샘플에서 30dB 이상의 소광률을 얻을 수 있었으며 삽입손실은 0.2dB 에서 1.5dB 사이였다.

  • PDF

Protein G와 NHS를 이용하여 고정한 anti-IgG의 검출 성능 비교 (A comparison of detection capabilities of anti-IgG immobilizedby protein G and NHS)

  • 신은정;손영호;손영수
    • 센서학회지
    • /
    • 제19권2호
    • /
    • pp.142-148
    • /
    • 2010
  • We have compared and investigated the detection capabilities of antibody of immunoglobulin G(anti-IgG) immobilized by protein G and N-hydroxysuccinimide(NHS) at the end of the self-assembled monolayer(SAM). Surface plasmon resonance(SPR) sensor has been utilized to measure the interaction between biomolecules. After formation of the protein G and SAM, anti-IgG, bovine serum albumin(BSA) and IgG has been sequently injected. Through the reponse of the SPR, we can conclude that the protein G immobilized anti-IgG better than the SAM. In addition, IgG detection capability of the anti-IgG immobilized by the protein G showed better performance compared with that immobilized by the SAM.