• Title/Summary/Keyword: Surface modification

Search Result 1,917, Processing Time 0.029 seconds

Analysis of the Correlation Between Kidney Function Indicators and Kidney Size According Age Groups in Ultrasonography (신장 초음파 검사에서 연령대에 따른 신장 기능 지표와 신장 크기 간의 상관관계 분석)

  • Go, Ryo-won;Seoung, Youl-Hun
    • Journal of the Korean Society of Radiology
    • /
    • v.14 no.7
    • /
    • pp.871-879
    • /
    • 2020
  • The purpose of this study was to analysis the correlation between kidneys function indicators and these size in ultrasonography. A total of 170 (male:86, female:84) patients of sex and age groups were examined by abdominal ultrasonography. The patients classified as those in their 20's, 30's, 40's, and over 50's. We measured the length, width, and cross-sectional height of the kidneys twice. At this time, the length of these were measured from the maximum upper to the maximum lower pole and the widest width in the same ultrasonography was measured to obtain the cross-sectional area. Other relevant indicators included body surface area, serum creatinine, glomerular filtration rate (GFR), MDRD (Modification of diet in renal disease) and C-G (Cockcroft-Gault). Significant comparisons of differences between relevant factors by age groups and sex were conducted with a one-way distribution analysis. Correlation analysis was also performed between relevant factors by using Pearson and Spearman correlation coefficient. It was defined as meaningful when the p-value was less than 0.05. As a result, the length, the width, and the cross-sectional area of kidneys were correlated with GFR, C-G, MDRD. Therefore, it is expected that the accuracy of diagnosis of kidneys disease will be increased if the relevant indicators are evaluated together rather than measuring only length of these in ultrasonography.

Graphene Oxide Incorporated Antifouling Thin Film Composite Membrane for Application in Desalination and Clean Energy Harvesting Processes (해수담수화와 청정 에너지 하베스팅을 위한 산화 그래핀 결합 합성 폴리머 방오 멤브레인)

  • Lee, Daewon;Patel, Rajkumar
    • Membrane Journal
    • /
    • v.31 no.1
    • /
    • pp.16-34
    • /
    • 2021
  • Water supplies are decreasing in comparison to increasing clean water demands. Using nanofiltration is one of the most effective and economical methods to meet the need for clean water. Common methods for desalination are reverse osmosis and nanofiltration. However, pristine membranes lack the essential features which are, stability, economic efficiency, antibacterial and antifouling performances. To enhance the properties of the pristine membranes, graphene oxide (GO) is a promising and widely researched material for thin film composites (TFC) membrane due to their characteristics that help improve the hydrophilicity and anti-fouling properties. Modification of the membrane can be done on different layers. The thin film composite membranes are composed of three different layers, the top filtering active thin polyamide (PA) layer, supporting porous layer, and supporting fabric. Forward osmosis (FO) process is yet another energy efficient desalination process, but its efficiency is affected due to biofouling. Incorporation of GO enhance antibacterial properties leading to reduction of biofilm formation on the membrane surface. Pressure retarded osmosis (PRO) is an excellent process to generate clean energy from sea water and the biofouling of membrane is reduced by introduction of GO into the active layer of the TFC membrane. Different modifications on the membranes are being researched, each modification with its own advantages and disadvantages. In this review, modifications of nanofiltration membranes and their composites, characterization, and performances are discussed.

THE BOND CHARACTERISTICS OF PORCELAIN FUSED BY TITANIUM SURFACE MODIFICATION (타이타늄의 표면개질에 따른 도재 결합 특성)

  • Choi, Taek-Huw;Park, Sang-Won;Vang, Mong-Sook;Yang, Hong-So;Park, Ha-Ok;Lim, Hyun-Pil;Oh, Gye-Jeong;Kim, Hyun-Seung;Lee, Kwang-Min;Lee, Kyung-Ku
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.45 no.2
    • /
    • pp.169-181
    • /
    • 2007
  • Statement of problem: Titanium is well known as a proper metal for the dental restorations, because it has an excellent biocompatibility, resistance to corrosion, and mechanical property. However, adhesion between titanium and dental porcelains is related to the diffusion of oxygen to the reaction layers formed on cast-titanium surfaces during porcelain firing and those oxidized layers make the adhesion difficult to be formed. Many studies using mechanical, chemical and physical methods to enhance the titanium-ceramic adhesion have been actively performed. Purpose: This study meant to comparatively analyse the adhesion characteristics depending on different titanium surface coatings after coating the casts and wrought titanium surfaces with Au and TiN. Material and method: In this study, the titanium specimens (CP-Ti, Grade 2, Kobe still Co. Japan) were categorized into cast and wrought titanium. The wrought titanium was cast by using the MgO-based investment(Selevest CB, Selec). The cast and wrought titanium were treated with Au coating($ParaOne^{(R)}$., Gold Ion Sputter, Model PS-1200) and TiN coating(ATEC system, Korea) and the ultra low fusing dental porcelain was fused and fired onto the samples. Biaxial flection test was done on the fired samples and the porcelain was separated. The adhesion characteristics of porcelain and titanium after firing and the specimen surfaces before and after the porcelain fracture test were observed with SEM. The atomic percent of Si on all sample surfaces was comparatively analysed by EDS. In addition, the constituents of specimen surface layers after the porcelain fracture and the formed compound were evaluated by X-ray diffraction diagnosis. Result: The results of this study were obtained as follows : 1. The surface characteristics of cast and wrought titanium after surface treatment(Au, TiN, $Al_2O_3$ sandblasting) were similar and each cast and wrought titanium showed similar bonding characteristics. 2. Before and after the biaxial flection test, the highest atomic weight change of Si component was found in $Al_2O_3$ sandblasted wrought titanium(28.6at.% $\rightarrow$ 8.3at.%). On the other hand, the least change was seen in Au-Pd-In alloy(24.5at.% $\rightarrow$ 9.1at.%). 3. Much amount of Si components was uniformly distributed in Au and TiN coated titanium, but less amount of Si's was unevenly dispersed on Al2O3 sandblasting surfaces. 4. In X-ray diffraction diagnosis after porcelain debonding, we could see $Au_2Ti$ compound and TiN coating layers on Au and TiN coated surfaces and $TiO_2$, typical oxide of titanium, on all titanium surfaces. 5. Debonding of porcelain on cast and wrought titanium surface after the biaxial flection is considered as a result of adhesion deterioration between coating layers and titanium surfaces. We found that there are both adhesive failure and cohesive failure at the same time. Conclusion: These results showed that the titanium-ceramic adhesion could be improved by coating cast and wrought titanium surfaces with Au and TiN when making porcelain fused to metal crowns. In order to use porcelain fused to titanium clinically, it is considered that coating technique to enhance the bonding strength between coating kKlayers and titanium surfaces should be developed first.

Interface Functional Materials for Improving the Performance and Stability of Organic Solar Cell (유기태양전지의 효율 및 수명 향상을 위한 기능성 계면 소재 연구)

  • Hong, Kihyon;Park, Sun-Young;Lim, Dong Chan
    • Applied Chemistry for Engineering
    • /
    • v.25 no.5
    • /
    • pp.447-454
    • /
    • 2014
  • Organic solar cells (OSCs) have intensively studied in recent years due to their advantages such as cost effectiveness and possibility of applications in flexible devices. In spite of the high power conversion efficiency (PCE) of 10 %, the OSCs still have a draw back of their low environmental stability due to the oxidization of aluminum cathode and etching of transparent conducting oxide as electrode. To solve these problems, the inverted structured OSCs (I-OSCs) having greatest potential for achieving an improvement of device performances are suggested. Therefore, there are a lot of studies to develope of interface layer based on organic/inorganic materials for the electron transport layer (ETL) and passivation layer, significant advancements in I-OSCs have driven the development of interface functional materials including electron transport layer. Recent efforts to employing 2D/3D zinc oxide (ZnO) based ETL into I-OSCs have produced OSCs with a power conversion efficiency level that matches the efficiency of ~9 %. In this review, the technical issues and recent progress of ZnO based ETL in I-OSCs to enhancement of device efficiency and stability in terms of materials, process and characterization have summarized.

Effect of Fluorination of Carbon Nanotubes on Physico-chemical and EMI Shielding Properties of Polymer Composites (고분자 복합재의 물리화학적 및 전자파차폐 특성에 미치는 탄소나노튜브의 불소화 영향)

  • Lee, Si-Eun;Kim, Doyoung;Lee, Man Young;Lee, Min-Kyung;Jeong, Euigyung;Lee, Young-Seak
    • Polymer(Korea)
    • /
    • v.39 no.1
    • /
    • pp.114-121
    • /
    • 2015
  • Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.

Sintering of Surface-Modified PMN-PT-BT Powder with MgO Sol and Its Dielectric Properties (MgO 졸로 표면개질된 PMN-PT-BT 분말의 소결 및 유전특성)

  • Han, Kyoung-Ran;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.12 s.271
    • /
    • pp.929-932
    • /
    • 2004
  • It is known that small amount of MgO in excess is often added to develop pure perovskite single phase of PMN-based composite, however, extra MgO precipitates in grains and inhibits densification of PMN. In this study PMN-PT-BT (PBT) powder was prepared by a conventional mixed oxide method using $(MgCO_3)_4{\cdot}Mg(OH)_2{\cdot}5H_{2}O$ instead of MgO. The precursor was heated at $500^{\circ}C/1h$ and its surface was modified with MgO sol. This effect was investigated in the aspects of sintering and dielectric properties. Small amount of added MgO sol ($0.5{\sim}1.0wt\%$) enhanced sintering substantially below $1000^{\circ}C$. The PBT with $0.5wt\%$ MgO sol sintered at $900^{\circ}C/2h$ had density of $7.62\;g/cm^3$, room temperature dielectric constant of 14800, loss of dielectric constant of $1.1\%$, which were comparable to those of the PBT sintered at $1000^{\circ}C/2h$. It was noticeable that the extra MgO precipitated mostly on triple points and grain boundaries and resulted in inhibition of grain growth.

Effects of Al2O3 Coating on BiVO4 and Mo-doped BiVO4 Film for Solar Water Oxidation

  • Arunachalam, Maheswari;Yun, Gun;Lee, Hyo Seok;Ahn, Kwang-Soon;Heo, Jaeyeong;Kang, Soon Hyung
    • Journal of Electrochemical Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.424-432
    • /
    • 2019
  • Planar BiVO4 and 3 wt% Mo-doped BiVO4 (abbreviated as Mo:BiVO4) film were prepared by the facile spin-coating method on fluorine doped SnO2(FTO) substrate in the same precursor solution including the Mo precursor in Mo:BiVO4 film. After annealing at a high temperature of 450℃ for 30 min to improve crystallinity, the films exhibited the monoclinic crystalline phase and nanoporous architecture. Both films showed no remarkably discrepancy in crystalline or morphological properties. To investigate the effect of surface passivation exploring the Al2O3 layer, the ultra-thin Al2O3 layer with a thickness of approximately 2 nm was deposited on BiVO4 film using the atomic layer deposition (ALD) method. No distinct morphological modification was observed for all prepared BiVO4 and Mo:BiVO4 films. Only slightly reduced nanopores were observed. Although both samples showed some reduction of light absorption in the visible wavelength after coating of Al2O3 layer, the Al2O3 coated BiVO4 (Al2O3/BiVO4) film exhibited enhanced photoelectrochemical performance in 0.5 M Na2SO4 solution (pH 6.5), having higher photocurrent density (0.91 mA/㎠ at 1.23 V vs. reversible hydrogen electrode (RHE), briefly abbreviated as VRHE) than BiVO4 film (0.12 mA/㎠ at 1.23 VRHE). Moreover, Al2O3 coating on the Mo:BiVO4 film exhibited more enhanced photocurrent density (1.5 mA/㎠ at 1.23 VRHE) than the Mo:BiVO4 film (0.86 mA/㎠ at 1.23 VRHE). To examine the reasons, capacitance measurement and Mott-Schottky analysis were conducted, revealing that the significant degradation of capacitance value was observed in both BiVO4 film and Al2O3/Mo:BiVO4 film, probably due to degraded capacitance by surface passivation. Furthermore, the flat-band potential (VFB) was negatively shifted to about 200 mV while the electronic conductivities were enhanced by Al2O3 coating in both samples, contributing to the advancement of PEC performance by ultra-thin Al2O3 layer.

Preparation of Cationic Liposomes Modified by Polyethylenimine and Their Application as Gene Carrier (폴리에틸렌이민으로 수식된 양이온 리포좀의 제조 및 유전자 전달체로서의 응용)

  • Seo, Dong-Hoan;Shin, Byung-Cheol;Kim, Moon-Suk
    • Polymer(Korea)
    • /
    • v.29 no.3
    • /
    • pp.277-281
    • /
    • 2005
  • Recently, various curriers prepared by the modification both cationic polymers and liposomes have been examined. In this work, we prepared the lipid with polyethylenimine (PEI) to investigate the possibility as effective DNA carrier. Cationic lipid (PEI-DSPE) was synthesized by the reaction of PEI and 1,2-diacyl-sn-glycero-3-phosphoetha-nolamine (DSPE). The liposomes were prepared by the concenoation changes of PEI-DSPE for a mixture of 1,2-disteanyl-sn-glycero-3-phosphocholine (DSPC), L-$\alpha$-phosphatidylcholine, hydrogenated (HSPC) and cholesterol (CHOL). Particle size decreased as PEI-DSPE concentration increased. In addition, the charge of liposome surface increased to positive value according to increasing the relative of PEI-DSPE concentration. The complexation of DNA was confirmed by gel retardation assay and fluorescence measurement. The surface charge of liposome/DNA complexes increased as the liposome concentration or surface charge of liposome increased. In conclusion, we confirmed that the prepared liposomes have the possibility as a DNA carrier.

The Analysis of Effect of Surface Shape and Pattern of Noise Barrier Panel on the Noise Reduction (방음벽 전면형상에 따른 소음 효과 분석에 관한 연구)

  • Kim, IlHo;Ahn, Hosang;Park, Jong-Bin;Kim, Gwang Soo;Lee, Ju Haeng;Ko, Junhee
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.34 no.12
    • /
    • pp.835-839
    • /
    • 2012
  • In recent decades, a lot of noise barriers have been installed along paved road in order to reduce the road induced noise, which increases as traffic volume grows. For better range of sight, transparent noise barriers are widely installed despite of reflecting noise. In this study, the effect of surface shape and pattern of noise barriers on the reduction of reflecting noise was analyzed to maximize the noise reduction. According to the number of shape and pattern, it was observed that there were noise reduction effect as of 0.9~1.5 dB(A). It was found that the spatial field where the noise concentrates or disperses changes according to the width of blocks on the barriers as well. It suggests that there might be possibility of surface shape modification to optimize the noise reduction technology.

The effects of non-condensable gas on condensation heat transfer on a super-hydrophobic surface tube (초소수성 코팅 튜브에서의 비응축가스 영향에 대한 응축 열전달 연구)

  • Ji, Dae-Yun;Kim, Daeho;Lee, Kwon-Yeong
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.4
    • /
    • pp.517-524
    • /
    • 2018
  • This purpose of this research is to observe the influence of non-condensable gas (NCG) on a horizontal super-hydrophobic aluminum tube and compare it with a bare aluminum tube. To achieve super-hydrophobic characteristics, an aluminum tube was coated with a Self-Assembled Monolayer (SAM). The overall heat transfer coefficient U was used to represent the condensation performance. The NCG mass fraction was the main variable, and its range was 0.08 to 0.45. The condensation performance of the SAM tube and bare tube increased with decreasing mass fraction of NCG. The SAM tube showed 1.9 to 2.5 times larger dropwise condensation performance than the bare tube. When the mass fraction of NCG decreased in the SAM tube, the rate of increase of the SAM tube was lower because flooded condensation occurred. In addition, filmwise condensation occurred in the SAM tube when more active condensation was generated, and its performance was lower than that of the bare aluminum tube. The flooded and filmwise condensation in the SAM tube is explained by the pinning effect. In conclusion, controlling the condition of the condenser is necessary to improve the condensation performance by surface modification a SAM.