• Journal of Theoretical and Applied Mechanics
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• 제1권1호
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• pp.1-27
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• 1995

In this paper a finite element method for free-surface problems is described. the method is based on two different forms of Hamilton's principle. To test the present computational method two specific wave problems are investigated; the dispersion relations and the nonlinear effect for the well-known solitary waves are treated. The convergence test shows that the present scheme is more efficient than other existing methods, e.g. perturbation scheme.

• 한국해양공학회지
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• 제10권3호
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• pp.96-104
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• 1996

Hamilton's principle is used to derive Euler-Lagrange equations for free surface flow problems of incompressible ideal fluid. The velocity field is chosen to satisfy the continuity equation a priori. This approach results in a hierarchial set of governing equations consist of two evolution equations with respect to two canonical variables and corresponding boundary value problems. The free surface elevation and the Lagrange's multiplier are the canonical variables in Hamilton's sense. This Lagrange's multiplier is a velocity potential defined on the free surface. Energy is conserved as a consequence of the Hamiltonian structure. These equations can be applied to waves in water of finite depth including generalization of Hamilton's equations given by Miles and Salmon.

• Structural Engineering and Mechanics
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• 제74권2호
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• pp.175-187
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• 2020

The theories having been developed thus far account for higher-order variation of transverse shear strain through the depth of the beam and satisfy the stress-free boundary conditions on the top and bottom surfaces of the beam. A shear correction factor, therefore, is not required. In this paper, the effect of surface on the axial buckling and free vibration of nanobeams is studied using various refined higher-order shear deformation beam theories. Furthermore, these theories have strong similarities with Euler-Bernoulli beam theory in aspects such as equations of motion, boundary conditions, and expressions of the resultant stress. The equations of motion and boundary conditions were derived from Hamilton's principle. The resultant system of ordinary differential equations was solved analytically. The effects of the nanobeam length-to-thickness ratio, thickness, and modes on the buckling and free vibration of the nanobeams were also investigated. Finally, it was found that the buckling and free vibration behavior of a nanobeam is size-dependent and that surface effects and surface energy produce significant effects by increasing the ratio of surface area to bulk at nano-scale. The results indicated that surface effects influence the buckling and free vibration performance of nanobeams and that increasing the length-to-thickness increases the buckling and free vibration in various higher-order shear deformation beam theories. This study can assist in measuring the mechanical properties of nanobeams accurately and designing nanobeam-based devices and systems.

• 대한기계학회논문집B
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• 제35권5호
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• pp.445-450
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• 2011

본 연구에서는 상압 플라즈마를 발생시켜 고분자 재료의 표면 자유에너지와 접착력의 변화를 조사하였다. 고분자 재질은 PC, PET, EVA 를 사용하였으며 표면자유에너지 변화를 관찰하기 위해 Di water 와 diiodomethane을 사용하여 접촉각을 측정하였다. 플라즈마 처리에 따른 접착력의 변화를 관찰하기 위해 PET 필름에 고분자 필름을 부착시켜 $180^{\circ}$ peel test 를 수행하였다. 그 결과 PET 필름의 표면자유에너지 및 접착력이 가장 큰 것을 확인할 수 있었으며, 상압 플라즈마 표면처리 공정은 필름 계면의 접착력을 크게 증가시켜 주는 것을 확인하였다.

• Elastomers and Composites
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• 제51권4호
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• pp.350-354
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• 2016

The surface properties of poly(methyl methacrylate) (PMMA) were investigated after accelerated weathering. Glossinesses, contact angles, surface free energies, thermal stability, and mechanical properties were investigated. The glossiness of the weathered PMMA was decreased with increasing exposure time. Contact angles and surface free energies were not overtly changed because the amount of oxygen on the surface was remained. PMMA was compounded with anti-block and antistatic agents using a co-rotating twin screw extruder to improve the durability. The PMMA composites showed better glossinesses after accelerated weathering while maintaining the contact angles, surface energy, thermal stability, and mechanical properties without significant changes.

• Bulletin of the Korean Chemical Society
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• 제24권12호
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• pp.1742-1750
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• 2003

In order to characterize the hydrophobic parameters of N-acetyl amino acid amides in 1-octanol/water, a theoretical calculation was carried out using a solvation free energy density model. The hydrophobicity parameters of the molecules are obtained with the consideration of the solvation free energy over the solvent volume surrounding the solute, using a grid model. Our method can account for the solvent accessible surface area of the molecules according to conformational variations. Through a comparison of the hydrophobicity of our calculation and that of other experimental/theoretical works, the solvation free energy density model is proven to be a useful tool for the evaluation of the hydrophobicity of amino acids and peptides. In order to evaluate the solvation free energy density model as a method of calculating the activity of drugs using the hydrophobicity of its building blocks, the contracture of Bradykinin potentiating pentapeptide was also predicted from the hydrophobicity of each residue. The solvation free energy density model can be used to employ descriptors for the prediction of peptide activities in drug discovery, as well as to calculate the hydrophobicity of amino acids.

• Journal of Pharmaceutical Investigation
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• 제15권2호
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• pp.45-52
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• 1985

For the model tablets using mannitol and Avicel PH 101 as excipients, the patterns of disintegration and dissolution from the differences of physical properties were investigated. It was found that the patterns in the dissolution and binding forces in the interaction of materials by estimates of solid-solid or liquid surface free energy due to cohesive or adhesive properties of materials, and solid surface free energy in binding forces of tablet should be considered as an important factor in dissolution processes.

• 한국도로학회논문집
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• 제8권2호
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• pp.13-22
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• 2006

Surface fog coating methods to porous pavements with a polymer, that contains MMA as a main ingredient, are being widely used in Japan and called 'Top-Coat Processes'. They have lots of effects such as to prevention of the pavement void choking, improvement of the water permeability of the pavements and so on. The purpose of this research is to show the characterization of the polymer to optimize the functions of the polymer fog-coat methods. This study focused on the difference of 'wetting' by water among polymers used for the fog coatings, and calculation the surface free energy from the water contact angle on each material. At the end, the water permeability test were conducted using porous asphalt mixtures that were coated with several kinds of polymers. The permeability was also measured on the specimens that were forcibly choked by muddy water and the resistance to choking was compared. It is concluded that the reduction of the surface free energy between water and a polymer improves the life of the permeability functions of porous pavements. Improvement of water permeation capacity and void-blocking controlling effects can be quantitatively evaluated using the interfacial tension ($\gamma$sl) with water for the coating material (high-viscosity asphalt and hardening resin binder). Consequently, the smaller the $\gamma$sl of the coating material the higher the water permeation capacity and void-blocking controlling effects of the porous asphalt pavements.

• Geomechanics and Engineering
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• 제21권3호
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• pp.237-245
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• 2020

The process of evaporation from free water surface was simulated in a large scale environmental chamber under various controlled atmospheric conditions and also was modelled by a new mass transfer model. Six evaporation tests were conducted with increasing wind speed and air temperature in the environmental chamber, and hence the effect of atmosphere parameters on the evaporation process and the corresponding response of water were investigated. Furthermore, based on the experiment results, seven general types of mass transfer models were evaluated firstly, and then a new model consisted of wind speed function and air relative humidity function was proposed and validated. The results show that the free water evaporation is mainly affected by the atmospheric parameters and the evaporation rate increases with the increasing air temperature and wind speed. Both the air and soil temperatures are affected by the energy transformation during water evaporation. The new model can satisfactorily describe the evaporation process from free water surface under different atmospheric conditions.

• 한국군사과학기술학회지
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• 제4권1호
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• pp.207-215
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• 2001

Plastic bonded explosive(PBX) is mainly composed of the nitramine-ploymer compositions. PBX is characterized by high velocity and pressure of detonation, low vulnerability and good thermal stability. Many important applications of PBX require the good adhesion between nitramine crystals and the binder. For PBXs as well as propellants, where good mechanical properties are of great importance, dewetting therefore must be prevented by strong adhesion between filler-binder. Adhesion depends on surface characteristics of filler and binder. In order to design for better adhesion, an understanding of the surface properties of explosive and binder is required. The surface free energies are calculated from contact angle values by the method of Kaelble. Critical surface tension of solids are calculated by Zisman plot. Critical surface tension is a useful parameter for characterizing the wettability of solid surface. In this study, HMX and 3 kinds of copolymers are selected, since they are widely used in many plastic bonded explosives. The technical objective of this investigation is to predict the interaction between filler and binder from their surface free energies.