• Title/Summary/Keyword: Surface discoloration

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THE CHANGE IN SURFACE CONVERSION AND DISCOLORATION IN DENTAL RESTORATIVE COMPOSITE RESIN UNDER DIFFERENT POLISHING METHODS; THE CORRELATION BETWEEN SURFACE CONVERSION AND SURFACE DISCOLORATION (수복용복합레진의 표면처리방법에 따른 표면중합률 및 변색정도의 변화와 그 상관관계에 대한 연구)

  • Park, Sung-Ho;Noh, Byung-Duk;Kim, Mo-Ran;Ahn, Hyun-Jung
    • Restorative Dentistry and Endodontics
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    • v.25 no.3
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    • pp.482-486
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    • 2000
  • The purpose of the present study was first, to evaluate the relationship between composite surface conversion and surface discoloration, second, to know if there was difference in surface discoloration between celluloid-strip-finished composite surface and polished surface. In addition, the discoloration of composite surface was also evaluated with visual inspection or digital camera with high resolution monitor, Z100, Tetric Ceram, Spectrum, and Aelitfil were used. The composite surfaces were celluloid-strip finished (group 1), polished (group 2), celluloid-strip finished under nitrogen gas purging (group 3) or only light cured without finishing or polishing under nitrogen gas purging (group 4). The microhardness of each samples were also measured in each group. The samples of each group were also divided into 4 subgroup whether they were immediately placed in disclosing solution (0.2% Elythrosin, pH 7.0) (subgroup1), 1 day after light curing(subgroup 2), 3day after light curing(subgroup 3) or 7 day after light curing(subgroup 4). The computer controlled spectrophotometer was used to determine CIELAB coordinates ($L^*$, $a^*$, $b^*$). The amounts of color difference were compared. The results were as follows; 1. There was no difference in discoloration between celluloid strip finished composite surface and polished surface. 2. The samples discolored more when they were placed in disclosing solution immediately after polymerization than other groups. 3. When the samples were light cured under nitrogen gas purging and without polishing process, they discolored more than other groups even though they showed higher micro hardness. 4. With visual inspection or digital camera, only a limited information was available in detecting composite surface discoloration.

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Analysis on the Cooling Effect of Applying Temperature Discoloration Paint to a Roof Surface (온도 변색 도료의 지붕 적용 및 냉방효과 분석)

  • Baek, Sanghoon
    • Land and Housing Review
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    • v.13 no.4
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    • pp.115-123
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    • 2022
  • This study aims to introduce a temperature discoloration roof system and its cooling effect in the summer. Temperature discoloration paints can reverse their colors based on temperature changes. If these paints on the roof surface could color-shift between white in the summer and black in the winter, the indoor cooling and heating loads can be affected by the changes in reflection and absorption of solar radiation. Focusing on the summer period, the study analyzed the cooling effect of applying temperature discoloration paint that color-shifts from white to black on the roof surface of a small experimental building module and compared it to commonly used gray and green roof colors. Results of the experiment showed that the surface temperature of the roof with temperature discoloration paint was lower than the gray and green color roofs by a maximum of 10℃. Furthermore, the indoor temperature of the experimental module with the temperature discoloration roof was lower than the gray and green roofs by approximately 3℃. Findings of the study indicate that the application of temperature discoloration paint to the roof can reduce indoor cooling loads.

DISCOLORATION AND CORROSION RESISTANCE OF TiN-COATED ORTHODONTIC APPLIANCES PRODUCED BY ION-PLATING METHOD (Ion-plating법에 의하여 TiN 피막처리된 교정용 장치물의 변색성 및 내식성)

  • Kim, Jin-Hee;Kwon, Oh-Won;Choi, Young-Yun
    • The korean journal of orthodontics
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    • v.23 no.3 s.42
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    • pp.327-340
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    • 1993
  • The purpose of this study was to estimate the possibility of practical application of TiN ion-plating method on orthodontic appliances. TiN was coated on the surface of orthodontic stainless steel roll band by means of ion-plating method, and colorimetric properties of its obtained TiN film were investigated by using color analyzer. Also its corrosion and discoloration properties were compared with those of non ion-plated stainless steel roll band by using immersion test, which was done in 1N HCl solution for 10 days. Both weight changes and surface corrosion appearances of specimens for each day were respectively investigated by using electronic weighing machine and SEM(Scanning Electron Microscope). The discoloration degress of TiN-coated specimens immersed in 1N HCl solution were investigated by using color analyzer and then judged by N.B.S.(National Bureau of Standard) Unit. The results of this study were summarized as follows. o TiN ion-plated films showed the hue of 5Y, the value of 7, and the chroma of 3 by Munsell notations. o The weight losses and surface changes of TiN ion-plated specimens immersed in 1N HCl solution were less than those of non ion-plated specimens. It was shown, therefore, that the corrosion resistance was significantly improved by TiN ion-plating. o The discoloration degrees of non ion-plated specimens were too significant to be examined by color analyzer, while those of TiN ion-plated specimens were slight when judged by N.B.S. Unit. It was also apparent, therefore, that the anti-discoloration property was significantly improved by TiN ion-plating.

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Fabrication Process and CTQ Analysis of Organic Solderability Preservatives(OSP) Finish on Cu Pad for SMT (SMT(Surface Mounting Technology)용 Cu 패드의 유기솔더보전제 처리공정 및 CTQ(Critical-to-Quality)분석)

  • Lee, Hyo-Soo;Yi, Min-Su
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.1
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    • pp.1-9
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    • 2007
  • OSP(organic solderability preservatives) finish has been considered as a very effective process for substituting the metal surface treatment of Ni/Au finish because of lower cost, interface property and environmental issue of OSP finish. However, the discoloration of OSP layer is formed during assembly process consisting of various steps of temperature. The causes of discoloration and the characterization of solder joint were investigated with a degree of discoloration and the assembly process of OSP finished products, which was also compared statistically with that of conventional Ni/Au finished products. As the results, the solution of process trouble for OSP finished products is able to be offered.

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Weathering Characteristics according to Seawater Immersion of the Magai Wareiishi Jizo (Buddhist Statue Carved on Rock Surface) in Hiroshima, Japan (일본 히로시마현 마애화령석지장(磨崖和靈石地藏)의 해수 침수에 의한 풍화특성)

  • Lee, Sun Myung;Lee, Myeong Seong;Chun, Yu Gun;Lee, Jae Man;Morii, Masayuki
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.329-341
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    • 2012
  • Magai Wareiishi Jizo (Buddhist statue carved on rock surface) is close to shoreline and a part of rock block is periodically immersed by seawater. Rock material of the Wareiishi-jizo statue is composed mainly of medium or coarse-grained biotite granite and very durable. However, physical properties of the rock have been changed according to the complex interactions of the salt solution and surrounding environment. Exfoliation of the rock surface is a serious condition by salt crystallization. Exfoliation (14.6%) is concentrated on the upper part of the rock block with mainly boundary of seawater as the center. On the other hand, lower part of the rock block show black layers by contaminants deposition. In addition, brown discoloration and biological contaminants is overlapped. Rock surface show high discoloration rate of 50.5% (black discoloration, 29.2% > yellow discoloration, 14.1% > brown discoloration, 4.4% > green discoloration, 2.9%). Upper part of the rock block had a lot of change in the physical properties than lower part that is immersed by seawater. In particular, surface properties of the rock block was very weak state at the boundary surface of seawater permeation.

Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface (은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향)

  • Shin, Byung-Hyun;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.54 no.1
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

Interpretation of Surface Contamination and Genesis on the Stupa of the State Preceptor Jigwang from the Beopcheonsaji Temple Site in Wonju, Korea (원주 법천사지 지광국사탑의 표면오염 및 성인 해석)

  • Kang, San Ha;Lee, Ju Mok;Lee, Gyu Hye;Kim, Sa Duk;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.211-225
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    • 2018
  • The Stupa of the State Preceptor Jigwang from the Beopcheonsaji temple site in Wonju (National Treasure No. 101) was built in the Goryeo Period (around the 11th century), with very excellent style and techniques. It was returned to the Korea after being taken to Osaka of Japan without notice in 1912, and was severely damaged during the Korean War. Subsequently, the Stupa was restored using restoration materials like mortar, and relocated to the National Palace Museum of Korea. Surface contaminants in the Stupa primarily existed around the restoration materials. Black discoloration, which indicates a high discoloration grade, signified a high possession rate in the north and inner regions of the Stupa, which may be related to the relative moisture maintenance time. Most surface contaminants were calcite and gypsum; the black discoloration area underwent secondary discoloration due to air pollution. Moreover, the stone properties exhibited a relatively low discoloration grade, exhibiting crystallized contaminants that partly covered the rock-forming minerals. Overall, the Stupa deteriorated due to discoloration and being covered by lime materials, which were dissolved as the mortar degraded. Hence, it required contaminants removal, surface cleaning and desalination during conservation treatment, in order to control the rate of physicochemical deterioration by contaminants.

THE EFFECT OF FERMENTED FOODS ON THE COLOR AND HARDNESS CHANGE OF DENTURE BASE ACRYLIC RESINS (발효음식이 의치상레진의 색상 및 표면경도 변화에 미치는 영향)

  • Jeon, Yeol-Mae;Lim, Heon-Song;Shin, Soo-Yeon
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.4
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    • pp.344-355
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    • 2004
  • Statement of problem: For a long time, many of denture base acrylic resins have been used for edentulous and partial edentulous patients because of easy manipulation and good mechanical properties, but its esthetic aspect has not been commented enough. Denture base acrylic resins also has caused esthetic problems due to discoloration or staining as in esthetic restoration. Many researches and reports have treated the problems and accomplished esthetic improvement. But these researches and reports dealt with general food colors or beverages, not with fermented foods. Purpose: This study is designed to assess what fermented foods, such as soy sauce, gochujang, and toenjang that many of Koreans have taken in, influence on the color and hardness variation of denture base acrylic resins. Materials and methods: For the procedure, twelve disks per 4 denture base acrylic resins were fabricated with a thickness of 2mm and 16mm in diameter. Each seven specimen were measured for discoloration with spectrophotometer, while the others, five specimen, for surface hardness change with Barcol hardness tester, over time. Each 12 specimen were immersed into the 4 beakers of fermented foods(soy sauces, gochujangs, toenjangs, deionized water), and $L^{*},a^{*}$, and $b^*$ values were measured for the color difference$({\Delta}E^*)$, on the 1st, 7th, and 28th day with spectrophotometer, with the measurement of surface hardness change. Each data observed was processed statistically. Results: The findings are as follows; Discoloration 1. All of denture base resins was not influenced by the kind of fermented foods, except for $QC20^{(R)}$ 2. Soy sauce and red pepper paste caused more change for denture base resins than deionized water and soy bean paste, except for Perform$^{(R)}$ 3. Most significant change was shown in Lucitone 199$^{(R)}$, whereas Perform$^{(R)}$ results in the least change for all immersed solution, with no statistical significance. Hardness change 1. Barcol hardness values in deposited specimens have been changed low degree, but with significant statistical change according to the kind of food and duration. 2. Lucitone$^{(R)}$ 199 as significantly lower Barcol hardness value than others do. Conclusion: Based on the above results, it suggests that the habitual intake of fermented foods is not helpful for the color stability of denture base acrylic resins because Soy sauce and red pepper paste mainly caused discoloration and surface hardness change. Particularly $Lucitone199^{(R)}$ shows specific discoloration and low surface hardness values. Therefore, it is recommended giving caution patients with denture of $Lucitone199^{(R)}$ especially against the habitual intake of fermented foods like soy sauce and red pepper paste.

Surface Discoloration of Ultraviolet (UV)-Irradiated Phyllostachys bambusoides Bamboo

  • Hyoung-Woo LEE;Eun-Ju LEE;Yoon-Jung SHIN;Ha-Yeong JO;Dae-Yeon SONG
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.3
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    • pp.173-182
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    • 2023
  • Color is an attribute of visual perception and can be an important factor that affects the preference of customers toward bamboo and wood products. Solar radiation can discolor bamboo surfaces and initiate cracking. The purpose of this study is to investigate the effects of an ultraviolet (UV)-protective coating on the photodiscoloration of untreated and heat-treated Phyllostachys bambusoides bamboo surfaces. Artificial UVA radiators are set at a UVA irradiance of 2,000 W/m2 to accelerate the aging of the outer surfaces of hot-air-dried and heat-treated bamboo samples. Half of the samples are coated with transparent UV-protective paint. As the UVA radiation progresses, the discoloration prevention efficiency (DPE) of the UV-protective coating on all samples decreases gradually. The DPEs of the hot-air-dried samples are estimated to be 31.4% and 18.8% after 21 and 72 hours of artificial UVA radiation, respectively. The heat-treated samples exhibit similar trends (29.0% after 21 hours and 10.3% after 72 hours). Recoating the UV-protective paint periodically every six months is expected to minimize the discoloration of the bamboo's outer surface.

Peracetic Acid Treatment as an Effective Method to Protect Wood Discoloration by UV Light

  • PARK, Kyoung-Chan;KIM, Byeongho;PARK, Hanna;PARK, Se-Yeong
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.4
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    • pp.283-298
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    • 2022
  • Wood has always been used for various day-to-day applications such as interior or exterior construction materials, and household products. However, it can undergo photodegradation and discoloration by environmental factors including ultraviolet (UV) light, and thus has shortened its service life. Bleaching or delignification of wood surfaces is a suitable solution to stabilize wood against weathering by UV because these techniques can alter or remove the chromophores in lignin, which is a main factor of wood discoloration. To improve the color stability of wood surface according to the lifespan, surface delignification was conducted using peracetic acid (PAA) and hydrogen peroxide (HP) on the woods of Larix kaempferi and Quercus mongolica. After the PAA treatment, L* increased considerably from 60-70 to 90-95. Furthermore, wood surface color did not change significantly after UV exposure. The color differences (𝜟E*) between before and after PPA treatment of wood showed the 4.8-12.2 of L. kaempferi, and 1.7-3.7 of Q. mongolica, respectively. The lignin-related peaks in Fourier transform infrared spectroscopy (FT-IR) spectra disappeared with increased duration of PAA treatment. These results confirmed that the lignin component was partially or completely removed after the PAA treatment; the color differences (𝜟E*) clearly showed that there was a reduction in redness (a*) and yellowness (b*), and an increase in lightness (L*) owing to the removal of lignin. Based on these results, this study demonstrated that the partial removal of lignin from wood surfaces is a fundamental method for resolving photo-degradation.