• 제목/요약/키워드: Surface dipoles

검색결과 37건 처리시간 0.029초

Mechanism of workfunction modification on HAT-CN/Cu(111) interface: ab initio study

  • Kim, Ji-Hoon;Park, Yong-Sup;Kwon, Young-Kyun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.357-357
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    • 2010
  • Using ab initio density functional theory, we study the structural and electronic properties of interface between Cu surface and highly electron withdrawing hexaazatriphenylene-hexanitrile (HAT-CN) known as an efficient hole injection layer for organic light emitting diodes (OLEDs). We calculate the equilibrium geometries of the interface with different HAT-CN coverages. Usually, some of C-N bonds located at the edge of the HAT-CN molecule are deformed toward Cu atoms resulting in the reconstruction of Cu surface. By analyzing the electron charge and the potential distributions over the interface, we observe the formation of surface dipoles, which modify the work function at the interface. Such dipole formation is attributed to two origins, one of which is a geometrical nature and the other is a bond dipole. The former is related to structural deformation mentioned above, whereas the latter is due to charge transfer between organic and metal surface.

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고도가 변화하는 헬리콥터 탐사에서 얻어지는 자력이상의 변환 (Reduction of magnetic anomaly observations from helicopter surveys at varying elevations)

  • 중총 정;대웅무웅
    • 지구물리와물리탐사
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    • 제9권1호
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    • pp.121-128
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    • 2006
  • 헬리콥터를 이용한 항공자력탐사는 정해진 고도를 따라 지표면에 평행하게 이루어지지만, 고해상도 탐사에서는 특히 측정이 이루어지는 고도가 너무 변화하여 평탄면으로 간주할 수 없는 경우가 있다. 이 연구에서는 모서리 효과를 조절할 수 있도록 주변 자력원이 포함되는 등가원 방법을 이용하여 이러한 자료를 변환하는 방법을 개발하였고, 3차원적으로 무작위하게 분포하는 점의 자료를 직접적으로 모델화하였다. 이 문제는 일반적으로 under-determined 이지만 CG 법은 최소 norm 해를 찾을 수 있으며, 자력이상을 자력원과 연관시키는 조화함수를 선택할 자유가 있는데, 상향연속 함수 연산자가 선택되면 등가원 자체가 자력이상이 된다. 기본자기장의 방향으로의 자기 쌍극자분포를 자력원으로 선택하면, 자기 쌍극자의 방향을 수직으로 돌려줌으로써 쉽게 자극화 변환 이상을 유도할 수 있다.

양력판(揚力板) 이론(理論)에 의(依)한 2차원(次元) 수중익(水中翼)의 초월(超越) 공동(空洞) 문제(問題) 해석(解析) (A Potential-Based Panel Method for the Analysis of A Two-Dimensional Super-Cavitating Hydrofoil)

  • 김영기;이창섭;이진태
    • 대한조선학회논문집
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    • 제28권2호
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    • pp.159-173
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    • 1991
  • 본 논문에서는 양력판 이론을 사용하여 2차원 수중익에 발생한 비 대칭 초월 공동 문제를 포텐셜을 기저로하여 수치 해석하였다. 수중익과 공동 표면에 법선 다이폴을 분포하고 공동 표면에는 공동 형상을 찾기위하여 쏘오스를 분포하였다. 수중익 표면에서의 운동학적 경계조건은 수중익 내부에서의 전체 포텐셜이 0이라는 조건으로 대치하였고 공동 표면에서의 역학적 경계조건은 공동 표면에서의 접선 방향 속도가 일정하다는 조건으로 표현되었다. 표면에 특이 함수를 분포하여 포텐셜을 기저로하여 공동 문제를 해석하였기 때문에 압력 분포에 대하여, 특히 수중익의 앞날 근처에서는 양력면 이론에 의한 결과보다 더욱 향상된 정도의 결과를 얻었다. 본 이론은 먼저 주어진 공동 길이에 대하여 그에 상응하는 공동 형상 및 공동수를 구하였다. 좀더 좋은 결과를 얻기 위하여 새로이 계산된 공동 표면과 수중익 표면에 또 다시 특이 함수를 분포하여 그곳에서 경계 조건을 만족시킴으로써 새로운 공동 형상 및 공동수를 구하는 반복 계산을 수행하였다. 본 이론에 의한 계산 결과의 검증을 위하여 폭 넓은 수렴성 시험을 수행하였으며 특히, Geurst의 선형 이론에 의한 해석해 및 Wu의 비 선형 이론에 의한 해석해, 그리고 Acosta, Parkin, Meijer, Silberman, Waid의 실험 결과와 비교한 결과, 본 이론의 효용성을 입증하였다.

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A Potential-Based Panel Method for the Analysis of a Two-Dimensional Partially-Cavitating Hydrofoil

  • Lee, Chang-Sup
    • Selected Papers of The Society of Naval Architects of Korea
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    • 제1권1호
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    • pp.15-25
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    • 1993
  • A potential-based panel method is presented for the analysis of a partially-cavltatlng two-dimensional hydrofoil. The method employs normal dipoles and sources distributed on the foil and cavity surfaces. It is shown that the source plays an Important role in positioning the cavity surface through an iterative process. The cavity closure consition is found very effective in generating the cavity shape. Upon convergence, the method predicts the cavitation nurser, together with the lift, the drag and the surface pressure distribution, for a given cavity length. Systematic convergence tests shows that the present numerical method is fast and stable. The present computations show a good agreement with the previously computed and measured results.

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Analysis of the Wettability of Partially Fluorinated Polymers Reveals the Surprisingly Strong Acid-Base Character of Poly(vinylidene Fluoride)

  • Lee, Sang-Wha;Park, Joon-Seo;Lee, T. Randall
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.41-48
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    • 2011
  • The wettabilities of the partially fluorinated polymers (ethylene-tetrafluoroethylene copolymer (ETFE), ethylenechlorotrifluoroethylene copolymer (ECTFE), and poly(vinylidene fluoride) (PVDF)) were investigated by contact angle measurements. Zisman plots for ETFE and ECTFE exhibited linear relationships, while the Zisman plot for PVDF showed a slight curvature, which was interpreted to indicate strong non-dispersive interactions between the surface and the contacting liquids. The Lifshitz-van der Waals forces of the fluoropolymers were estimated to increase in the order of ETFE < PVDF $\ll$ ECTFE. An evaluation of the polar or "acid-base" interaction energies showed that PVDF, which possesses the most acidic hydrogens among the examined fluoropolymers, has the strongest acid-base interactions.

Analysis of mechanical properties of microtubules under combined effects of surface and body forces for free and embedded microtubules in viscoelastic medium

  • Farid, Khurram;Taj, Muhammad
    • Advances in concrete construction
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    • 제13권3호
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    • pp.255-264
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    • 2022
  • Vibration is expected to occur in microtubules as tubular heterodimers. They oscillate like electric dipoles. Several research studies have estimated a frequency of vibration using the orthotropic model, a beam or rod like models and shell models, considering the surface forces. The effects of body forces on the dynamics of the microtubules were not yet taken into account. This study seeks to capture the body force effects on the vibration modes generated and on the corresponding frequency for microtubules. An orthotropic elastic shell model for the structural details of microtubules is used for the analysis. The tests are conducted out for microtubules, exposed to electro-magnetic and gravitational forces, the transverse vibration, radial mode vibration, and axial mode of vibration have accomplished. We therefore, evaluate and compare microtubules' frequencies with prior results of vibration frequency without the effects of body force.

평판에 충돌하는 원형분류의 공력소음에 관한 실험적 연구 (Au Experimental Study on the Aerodynamic Noise by a Circular Jet Impinging on a Plate)

  • 이동훈;권영필;한희갑
    • 소음진동
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    • 제7권1호
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    • pp.71-79
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    • 1997
  • The objective of this study is to investigate experimentally the effect of surface conditions of the plate on the impinging jet noise. The experimental results about the spectrum, the sound pressure level and the directivity are pressented and discussed in relation with the surface conditions. Regardless of the surface conditions, the pure tones of high level are generated at the same frequency band and the overall sound power level of impinging jets is much higher than that of the free jet. However, the velocity dependence of the sound pressure level and the directivity are different between smooth surfaces and rough surfaces. The dependence of sound pressure level on the jet velocity shows that the smooth surface generates quadrupole-type sound like free jets. However, the perforated or the rough surface radiates sound power exactly proportional to the sixth power of the jet velocity, indicating that the source is fixed dipole type. The directivities of 1/3 octave band sound pressure level for both the free and impinging jet show the peak directivity at 115$^\circ$ upstream, probably due to the refraction associated with velocity gradient.

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유한수심(有限水深)의 해상(海上)에서 규칙파(規則波)에 놓인 구(球)의 운동특성(運動特性) (On the Motion Characteristics of a Freely-Floating Sphere in a Water of Finite Depth)

  • 최항순;이성균
    • 대한조선학회지
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    • 제19권1호
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    • pp.23-32
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    • 1982
  • Herein the motion of a freely-floating sphere in a water of finite depth is analysed within the framework of a linear potential theory. A velocity potential describing fluid motion is generated by distributing pulsating sources and dipoles on the immersed surface of the sphere, without introducing an inner flow model. The potential becomes the solution of an integral equation of Fredholm's second type. In the light of the vertical axisymmetry of the flow, surface integrals reduce to line integrals, which are approximated by summation of the products of the integrand and the length of segments along the contour. Following this computational scheme the diffraction potential and the radiation potential are determined from the same algorithm of solving a set of simultaneous linear equations. Upon knowing values of the potentials hydrodynamic forces such as added mass, hydrodynamic damping and wave exciting forces are evaluated by the integrating pressure over the immersed surface of the sphere. It is found in the case of finite water depth that the hydrodynamic forces are much different from the corresponding ones in deep water. Accordingly motion response of the sphere in a water of finite depth displays a particular behavior both in a amplitude and phase.

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Study on the Aerodynamic Characteristics of Wings Flying Over the Nonplanar Ground Surface

  • Han, Cheol-Heui;Lee, Kye-Beom;Cho, Jin-Soo
    • International Journal of Aeronautical and Space Sciences
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    • 제3권2호
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    • pp.82-87
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    • 2002
  • Aerodynamic analysis of NACA wings moving with a constant speed over guideways are performed using an indirect boundary element method (potential-based panel method). An integral equation is obtained by applying Green's theorem on all surfaces of the fluid domain. The surfaces over the wing and the guideways are discretized as rectangular panel elements. Constant strength singularities are distributed over the panel elements. The viscous shear layer behind the wing is represented by constant strength dipoles. The unknown strengths of potentials are determined by inverting the aerodynamic influence coefficient matrices constructed by using the no penetration conditions on the surfaces and the Kutta condition at the trailing edge of the wing. The aerodynamic characteristics for the wings flying over nonplanar ground surfaces are investigated for several ground heights.

THE BOUNDARIES OF DIPOLE GRAPHS AND THE COMPLETE BIPARTITE GRAPHS K2,n

  • Kim, Dongseok
    • 호남수학학술지
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    • 제36권2호
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    • pp.399-415
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    • 2014
  • We study the Seifert surfaces of a link by relating the embeddings of graphs with induced graphs. As applications, we prove that every link L is the boundary of an oriented surface which is obtained from a graph embedding of a complete bipartite graph $K_{2,n}$, where all voltage assignments on the edges of $K_{2,n}$ are 0. We also provide an algorithm to construct such a graph diagram of a given link and demonstrate the algorithm by dealing with the links $4^2_1$ and $5_2$.