• Title/Summary/Keyword: Surface diffusion

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Measurement of Particle Deposition Velocity toward a Horizontal Semiconductor Wafer Using a Wafer Surface Scanner (Wafer Surface Scanner를 이용한 반도체 웨이퍼상의 입자 침착속도의 측정)

  • Bae, G.N.;Park, S.O.;Lee, C.S.;Myong, H.K.;Shin, H.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.2
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    • pp.130-140
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    • 1993
  • Average particle deposition velocity toward a horizontal semiconductor wafer in vertical airflow is measured by a wafer surface scanner(PMS SAS-3600). Use of wafer surface scanner requires very short exposure time normally ranging from 10 to 30 minutes, and hence makes repetition of experiment much easier. Polystyrene latex (PSL) spheres of diameter between 0.2 and $1.0{\mu}m$ are used. The present range of particle sizes is very important in controlling particle deposition on a wafer surface in industrial applications. For the present experiment, convection, diffusion, and sedimentation comprise important agents for deposition mechanisms. To investigate confidence interval of experimental data, mean and standard deviation of average deposition velocities are obtained from more than ten data set for each PSL sphere size. It is found that the distribution of mean of average deposition velocities from the measurement agrees well with the predictions of Liu and Ahn(1987) and Emi et al.(1989).

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R&D Trend on Surface Treatment of Magnesium Alloys (마그네슘합금의 표면처리에 관한 연구개발 동향)

  • Shim, Jae-Dong;Byun, Ji-Young
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.72-80
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    • 2013
  • Recently, consumption of magnesium alloys has increased especially in the 3C (computer, communication, camera) and automobile industries. The structural application of magnesium alloys has many advantages due to their low densities, high specific strength, excellent damping and anti-eletromagnetic properties, and easy recycling. However, practical application of these alloys has been limited to narrow uses of mild condition, because they are inferior in corrosion resistance and wear resistance due to their high chemical reactivity and low hardness. Various wet and dry processes are being used or are under development to enhance alloy surface properties. Various conversion coating and anodizing methods have been developed in a view of eco-friendly concept. The conventional technologies, such as diffusion coating, sol-gel coating, hydrothermal treatment, and organic coating, are expected to be newly applicable to magnesium alloys. Surface treatments for metallic luster or coloring are suggested using the control of the micro roughness. This report reviews the recent R&D trends and achievements in surface treatment technologies for magnesium alloys.

The Temperature Dependence of the Diffusion Bonding Between Tungsten Carbides for Micro WC-PCD Tool Fabrication (초소형 초경 PCD Tool 제작을 위한 초경합금간 확산접합의 온도 의존성 연구)

  • Jeong, B.W.;Park, J.W.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.5
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    • pp.812-817
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    • 2013
  • This study demonstrates the diffusion bonding process between a tungsten carbide shank (K30) and tungsten carbide (DX5) for micro WC-PCD tool fabrication. A type of nickel alloy was used as the filler met alto improve the bond ability between K30 and DX5. The bonding pressure, time, and surrounding conditions were kept constant. In particular, the normal pressure was controlled precisely under buckling analysis. Diffusion bonding was performed at various operation temperatures (1170-1770 K) by using a specially designed jig. The microstructure on the localized bonded surface was analyzed using scanning electron microscopy and optical microscopy. In the case of diffusion bonding of WCat 1370-1770K, the filler metal melted completely and diffused between the two base metals, and they were bonded more tightly on both sides than at temperatures below 1370 K. Our results demonstrated the importance of sensitive temperature dependence of diffusion bonding.

Inward Diffusion of Tb Ions and the Magnetic Properties of the Nd-Fe-B Magnets (열처리 조건에 따른 Tb이온의 확산 및 Nd-Fe-B 자석의 자기적 특성)

  • Oh, Seong-Uk;Kim, Dong-Whan;Gong, Gun-Seung;Heo, Young-Woo;Kim, Jeong-Joo;Lee, Joon-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.27-31
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    • 2017
  • In this study, the effect of Tb inward diffusion on the magnetic properties of the Nd-Fe-B sintered magnets was studied. After sintering of the magnets, $TbF_3$ slurries were dip-coated on the surface of the samples, then heat-treatment was followed for $TbF_3$ diffusion. The element distribution in the magnets and the diffusion profiles of Tb ions were analyzed by an EPMA (electron probe micro-analyzer). Prolonged heat treatment resulted in a deeper diffusion length of Tb ions. Coercivity of the $1^{st}$ heat-treated sample showed 21.86 kOe, while that of the $1^{st}$, $2^{nd}$ heat-treated and annealed sample revealed 34 kOe.

Classification of Nanoparticles by Inertial/Diffusion Filter (관성/확산필터를 이용한 나노입자의 분류기술 연구)

  • Kim, Yonggu;Lee, Sangyul;Kim, Hannah;Noh, Hakjae;Bong, Choonkeun;Kim, Daesung
    • Particle and aerosol research
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    • v.11 no.2
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    • pp.29-36
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    • 2015
  • The purpose of this research is to find out the collection property of nanoparticle in diffusion filter to know particle size dispersion of nanomaterial using inertial force and principle of Brownian diffusion motion. We used inertial filters which are two different type and diffusion filters made by various kinds of Wiremesh and the different pieces of filter to compare with particle size distribution using NaCl particles. Finally, We made a conclusion as follows : (1) the bigger available charging volume is and the larger specific surface area of inertial filter is, the better collection efficiency is. (2) The higher wire-mesh number of filter is, the more collection efficiency of small particle is increasing because the wire of the higher Wiremesh number filter is thinner and denser. (3) The more pieces of wire-mesh filter, the more collection efficiency is increasing because it makes the residence time longer.

A Model for Diffusion and Dissolution Controlled Drug Release from Dispersed Polymeric Matrix (고분자 분산 매트릭스로부터의 약물방출에 관한 확산 및 용출 제어 모델)

  • Byun, Young-Rho;Choi, Young-Kweon;Jeong, Seo-Young;Kim, Young-Ha
    • Journal of Pharmaceutical Investigation
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    • v.20 no.2
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    • pp.79-88
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    • 1990
  • A numerical model for diffusion and dissolution controlled transport from dispersed matrix is presented. The rate controlling process for transport is considered to be diffusion of drug through a concentration gradient coupled with time-dependent surface change and/or disappearance of the dispersed drug in response to the dissolution. The transport behavior of drug was explained in terms of ${\nu}$ parameter: ${\nu}$ value means a ratio of diffusion time constant and dissolution time constant. This general model has wide range of application from where release is controlled by the diffusion rate to where release is governed by the dissolution rate. Based on this model, theoretical drug concentration, particle size distributions in the polymer matrix system and the resulting release rate were also investigated.

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Estimation of Probability Valuable for Diffusion Coefficient of Chloride Ion (염소이온 확산계수의 확률변수 평가)

  • Bae Su Ho;Lee Kwang Myong;Kim Jee Sang;Jung Sang Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.515-518
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    • 2005
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures exposed to chloride environments. In particular, the development of new procedures for probability-based durability analysis and design has been proved to be very valuable. To carry out the procedures described above, the statistical properties of design valuables such as diffusion coefficient of chloride ion, surface chloride concentration, and chloride threshold value etc. should be known. For this purpose, this paper presents the statistical properties of the diffusion coefficient of chloride ion such as mean value and standard deviation with water-cement(w/c) ratio and curing conditions, respectively. It was observed from the test that the standard deviation for the diffusion coefficient of chloride ion was found to be small with decrease in the w/c ratio irrespective of curing conditions and that of standard curing was found to be smaller than that of field curing.

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Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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Formation and Growth of Hydride Blisters in Zr-2.5Nb Pressure Tubes

  • Cheong, Yong-Moo;Gong, Un-Sik;Choo, Ki-Nam;Kim, Sung-Soo;Kim, Young-Suk
    • Nuclear Engineering and Technology
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    • v.33 no.2
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    • pp.192-200
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    • 2001
  • Hydride blisters were formed on the outer surface of Zr-2.5Nb pressure tube by a non- uniform steady thermal diffusion process. A thermal gradient was applied to the pressure tube with a heat bath kept at a temperature of 415$^{\circ}C$ and an aluminum cold finger cooled with flowing water of 15$^{\circ}C$. Optical microscopy and tree-dimensional laser profilometry were used to characterize the hydride blisters with different hydrogen concentrations and thermal diffusion time. Hydride blisters were expected to start at a hydrogen concentration of 30 - 70 ppm and a thermal diffusion time of 4 - 6$\times$10$^{5}$ sec. The hydride blister size increases with higher hydrogen concentrations and longer thermal diffusion time . Some of the samples revealed cracks on the hydride blisters. The ratio of hydride blister depth to height was estimated as approximately 8: 1.

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Adsorption Characteristics of Nickel, Zinc and Cadmium Ions using Alginate Bead (Alginate Bead를 이용한 니켈, 아연, 카드뮴의 흡착특성에 관한 연구)

  • Jung, Heung-Joe
    • Journal of Integrative Natural Science
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    • v.4 no.2
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    • pp.130-136
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    • 2011
  • This study investigated the adsorption characteristics of nickel, zinc and cadmium ions from the aqueous solution onto the alginate bead. Adsorption equilibrium capacities of the heavy metal ions increased with increasing initial pH of the solution. The adsorption equilibrium isotherm of the heavy metal ions was well represented by Langmuir equation. The magnitude of adsorption capacity of the heavy metal ions onto alginate bead was the order of cadmium > zinc > nickel. Kinetic parameters were measured in a batch adsorber to analyze the adsorption rates of the heavy metal ions. The internal diffusion coefficient of the heavy metal ions in the intraparticle were determined by comparing the experimental concentration curves with those predicted from the surface diffusion model (SDM) and pore diffusion model (PDM). The internal diffusion of the heavy metal ions in the intraparticles was explained by PDM.