• Title/Summary/Keyword: Surface contaminants

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Analysis of the Organic Acid Contaminants on the surface of TEN-STORIED STONE PAGODA ON THE SITE OF WON-GAKSA (원각사지 십층석탑 오염물의 유기산 분석)

  • Lee, Kyu-Shik;Han, Sung-Hee
    • 보존과학연구
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    • s.16
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    • pp.112-122
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    • 1995
  • TEN-STORIED STONE PAGODA ON THE SITE OFWON-GAKSA(Temple) which is one of three marble pagodas in South Korea, were dated from the thirteenth year of the reign of King Sejo(1467). On the roof and surface of each the stories, there were large amount of the contaminants such as pigeon′s excretions, dust and environmental elements for a long time. The pH of contaminants is not acid, but is 7.2, neutral. To find the species of organic acidscontained in the contaminants and the degree of damaging for a marble pagoda, we analyzed the contaminants using GC-MSD method by the following procedures. Organic acids were extracted by saponifying whole contaminants. After Saponification, the organic acids were mathylated to increase their volatility upon subsequent GC-MSD analysis. The mathyl esters of the organic acids are extracted from the acidified aqueous solution. And the organic extracts were washed with adilute base solution. The washed extract were analyzed by GC(Hewlett Packard 5890)with a nonpolar capillary column(Crosslinked 5% Ph Me Silicone, $50×0.2㎜×0.33\mum$film thickness, USA) and Mass Spectrometric Detector(Hewlett Packard 5970B).As the result, it was found that 12 organic acids were the main compound in pagoda′contaminants, and the amount of organic acid were negligible.

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Forming Process of Surface Contaminants on Ten-story Stone Pagoda of Wongaksa Temple, Seoul (서울 원각사지 십층석탑의 표면오염물 형성과정)

  • Chun, Yu Gun;Lee, Myeong Seong;Kim, Yuri;Lee, Sun Myung;Lim, Bo A
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.365-375
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    • 2016
  • This study was interpreted the forming process of surface contaminants on ten-story stone pagoda of Wongaksa temple, Seoul. Results of research, we estimated that black contaminants were formed by graphite stuck carbon in air pollution substance after that gypsum was generated by chemical weathering on stone pagoda. White contaminants were built by recrystallization of calcite that were made by decomposition of finishing materials and structure on the stone surface. To preserve a long-term of stone pagoda in Wongaksa temple, there were required that continuous monitoring, anticorrosion treatment and contaminants cleaning of protective facilities.

Effect of Dissolved and Colloidal Contaminants of Newsprint Machine White Water on Water Surface Tension and Paper Physical Properties

  • Consultant, Seika-Tay
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.61-69
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    • 1999
  • Contaminants such as fatty acids, triglycerides, resin acids and foam collected from a high yield sulfite weak liquor storage tank lowered the water surface tension and reduced inter-fibre bonding but also tended to benefit sheet opacity. Some common wet end additives such as defoamers and dispersants gave similar results. Lignosulfonate and naphthalene sulfonate showed little if any negative effect on both surface tension and sheet strength properties. Among the natural wood extractives. fatty acids were identified to be most detrimental followed by triglycerides and then resin acids. In order to alleviate the detrimental impact of these contaminants, membrane separation, air floatation and ozone treatment were carried out on paper machine white water samples. The effect of these treatments on removal of fatty and resin acids was quantified by a GC-Mass analysis. Reverse osmosis with a 1000 molecular weight cut off membrane failed to totally reject fatty and resin acids, but markedly reduced losses of sheet properties due to contaminants. Ozone treatment resulted in a significant increase of the surface tension and air floatation was considered to be a practical and useful method for removing fatty and resin acids from the machine white water.

Slip Resistance of Contaminants on the Floor for Variation of Viscosity (점도변화에 따른 바닥 오염물질의 미끄러짐 저항 특성)

  • Park, Jae-Suk;Oh, Whan-Sup
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.185-189
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    • 2012
  • While there is no standards on slip risk for contaminants on surface, glycerol is described in standard contaminant for measuring coefficient of friction(COF) and slip resistance such as ISO 13287. But that is just used to measure the slip resistance of surface materials and shoes not to evaluate the contaminant materials. Therefore the objective of this study was to find out the relationship between standard contaminant and the contaminants used usually at the workplaces. For this, some measurement criteria were acquired from the analysis based on biomechanics and kinetics of human gait during slips. The slip resistance according to viscosity of the contaminants was measured applying the criteria and slip probability was determined by the gait analysis. Some factors which should be considered when measuring the slip resistance were identified. The velocity, acceleration, contact time and contact pressure should be 1 m/sec, 10 $m/sec^2$, 350 kPa and less than 0.5sec respectively. The variation of viscosity according to temperature for working oils was different from that of standard contaminant. The static coefficient of friction (SCOF) of working oils was almost 0.5 times as large as the SCOF of standard contaminant. So it was assumed to be difficult to compare the contaminants at the workplaces with the glycerol as a standard contaminant for estimating the slip risk.

Effect of Surface Contaminants Remained on the Blasted Surface on Epoxy Coating Performance and Corrosion Resistance

  • Baek, Kwang Ki;Park, Chung Seo;Kim, Ki Hong;Chung, Mong Kyu;Park, Jin Hwan
    • Corrosion Science and Technology
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    • v.5 no.1
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    • pp.27-32
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    • 2006
  • One of the critical issues in the coating specification is the allowable limit of surface contaminant(s) - such as soluble salt(s), grit dust, and rust - after grit blasting. Yet, there is no universally accepted data supporting the relationship between the long-term coating performance and the amount of various surface contaminants allowed after grit blasting. In this study, it was attempted to prepare epoxy coatings applied on grit-blasted steel substrate dosed with controlled amount of surface contaminants - such as soluble salt(s), grit dust, and rust. Then, coating samples were subjected to 4,200 hours of cyclic test(NORSOK M-501), which were then evaluated in terms of resistance to rust creepage, blistering, chalking, rusting, cracking and adhesion strength. Additional investigations on the possible damage at the paint/steel interface were carried out using an Electrochemical Impedance Spectroscopy(EIS) and observations of under-film-corrosion. Test results suggested that the current industrial specifications were well matched with the allowable degree of rust, whereas the allowable amount of soluble salt and grit dust after grit blasting showed a certain deviation from the specifications currently employed for fabrication of marine vessels and offshore facilities.

Laser decontamination for radioactive contaminated metal surface: A review

  • Qian Wang;Feisen Wang;Chuang Cai;Hui Chen;Fei Ji;Chen Yong;Dasong Liao
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.12-24
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    • 2023
  • With the improvement of laser technology, the strategic needs of efficient and precise decontamination of various components in nuclear application units can be fulfilled by laser decontamination. The surface contaminants of nuclear facilities mainly exist both as loose contaminated layer and fixed oxide layer. The types of radionuclides and contamination layer thickness are closely related to the operation status of nuclear facilities, which have an important influence on the laser decontamination process. This study reviewed the mechanism of laser surface treatment and the influence of laser process parameters on the decontamination thickness, decontamination factor, decontamination efficiency and the distribution of aerosol particle. Although multiple studies have been performed on the mechanism of laser processing and laser decontamination process, there are few studies on the microscopic process mechanism of laser decontamination and the influence of laser decontamination on surface properties. In particular, the interaction between laser and radioactive contaminants needs more research in the future.

Use of Anionic Surfactants To Modify Soil Surface to Retard Migration of Hydrophobic Organic Compounds (음이온 계면활성제를 이용한 유기오염물질 고정화 방안에 관한 연구)

  • 박인선;조윤경;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.129-132
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    • 2000
  • In this research, we proposed the immobilization zone where the organic contaminant would be fixed, so that ground water could be prevented from the organic contaminants. The surfactant was adsorbed on the soil particles and the organic contaminants were partitioned into the hydrophobic tails of the surfactant in the immobilization zone. Surfactants with different molecular structures-SDDBS (sodium dodecylbenzenesulfonic acid), MADS (monoalkylated disulfonated diphenyl oxide), DADS (dialkylated disulfonated diphenyl oxide) - were used in this study. Up to the present, the research on the immolization simulated the saturated condition. But many site contaminated with organic contaminants and the zones where immobilization would be applied are unsaturated. In this research, in order to investigate the behaviors of surfactants and organic contaminants in unsaturated condition, the unsaturated columns were experimented, and their results were compared with the saturated case.

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A Study of Cognitive Slips According to Contaminants on the Floor

  • Kim, Jong-Il;Park, Min Soo;Kim, Tae-Gu
    • Safety and Health at Work
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    • v.9 no.2
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    • pp.180-183
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    • 2018
  • Background: This research investigates the degrees of slipperiness felt by the participants who walk on contaminants applied to a floor surface to decide degrees of slipperiness for various contaminants. Methods: For the experiment, 30 participants walked on a floor to which six contaminants were applied. All participants took the analytic hierarchy process (AHP)-based slipperiness questionnaire survey for the six kinds of contaminants, and the results were compared with the coefficient of friction. Results: The results of slip risk from the AHP indicate that grease is the most slippery of the six contaminants, followed by diesel engine oil, hydraulic oil, cooking oil, water-soluble cutting oil, and water in a decreasing order of slipperiness. When the results of slip risk from the AHP are compared with the static coefficient of friction for each contaminant, the order of slip risk follows the same trend. Although the results of slip risk from the AHP coincide with the static coefficient of friction, further study would be needed to investigate this relationship. Conclusion: This study will contribute as reference material for future research on preventing industrial accidents that result in falls from high places due to slipping.

Surface Cleaning of a Wafer Contaminated by Fingerprint Using a Laser Cleaning Technology (레이저 세정기술을 이용한 웨이퍼의 표면세정)

  • Lee, Myong-Hwa;Baek, Ji-Young;Song, Jae-Dong;Kim, Sang-Bum;Kim, Gyung-Soo
    • Journal of ILASS-Korea
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    • v.12 no.4
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    • pp.185-190
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    • 2007
  • There is a growing interest to develop a new cleaning technology to overcome the disadvantages of wet cleaning technologies such as environmental pollution and the cleaning difficulty of contaminants on integrated circuits. Laser cleaning is a potential technology to remove various pollutants on a wafer surface. However, there is no fundamental data about cleaning efficiencies and cleaning mechanisms of contaminants on a wafer surface using a laser cleaning technology. Therefore, the cleaning characteristics of a wafer surface using an excimer laser were investigated in this study. Fingerprint consisting of inorganic and organic materials was chosen as a representative of pollutants and the effectiveness of a laser irradiation on a wafer cleaning has been investigated qualitatively and quantitatively. The results have shown that cleaning degree is proportional to the laser irradiation time and repetition rate, and quantitative analysis conducted by an image processing method also have shown the same trend. Furthermore, the cleaning efficiency of a wafer contaminated by fingerprint strongly depended on a photothermal cleaning mechanism and the species were removed in order of hydrophilic and hydrophobic contaminants by laser irradiation.

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Interpretation of Surface Contamination and Genesis on the Stupa of the State Preceptor Jigwang from the Beopcheonsaji Temple Site in Wonju, Korea (원주 법천사지 지광국사탑의 표면오염 및 성인 해석)

  • Kang, San Ha;Lee, Ju Mok;Lee, Gyu Hye;Kim, Sa Duk;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.211-225
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    • 2018
  • The Stupa of the State Preceptor Jigwang from the Beopcheonsaji temple site in Wonju (National Treasure No. 101) was built in the Goryeo Period (around the 11th century), with very excellent style and techniques. It was returned to the Korea after being taken to Osaka of Japan without notice in 1912, and was severely damaged during the Korean War. Subsequently, the Stupa was restored using restoration materials like mortar, and relocated to the National Palace Museum of Korea. Surface contaminants in the Stupa primarily existed around the restoration materials. Black discoloration, which indicates a high discoloration grade, signified a high possession rate in the north and inner regions of the Stupa, which may be related to the relative moisture maintenance time. Most surface contaminants were calcite and gypsum; the black discoloration area underwent secondary discoloration due to air pollution. Moreover, the stone properties exhibited a relatively low discoloration grade, exhibiting crystallized contaminants that partly covered the rock-forming minerals. Overall, the Stupa deteriorated due to discoloration and being covered by lime materials, which were dissolved as the mortar degraded. Hence, it required contaminants removal, surface cleaning and desalination during conservation treatment, in order to control the rate of physicochemical deterioration by contaminants.