• Title/Summary/Keyword: Surface conductivity

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Molecular Behavior and Electro-Chemical Properties of Dendrimer and Staff-type Polymer Monolayers in Crown Function Group (크라운 기능기를 포함한 덴드리머 및 Staff-type 고분자 단분자막의 분자거동 및 전기ㆍ화학적 특성)

  • 장정수
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.52 no.5
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    • pp.213-213
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    • 2003
  • We investigated the monolayer behavior at the air-water interface with metal solution, the surface morphologies and the electrical properties such as conductivity, The calculated conductivity values of pure water subphase and its complexes with L $i^{+}$ ions are 5.6$\times$10$^{-l6}$ and 1.9$\times$10$^{-14}$ [S/cm], respectively. And the calculated barrier height D values of pure water subphase and its complexes with Li. ions are 0.70 and 0.66 [eV], respectively. We also attempted to fabricate a crown dendrimer Langmuir-Blodgett (LB) films containing functional end group that could form a complex structure with metal ions. Also, we investigated the surface activity of dendrimer films at air-water interface. In AFM images. the larger domains irregularly shaped structures on the top while the smaller ones were free from such defects. In conclusion, it is demonstrated that the metal ion around dendrimer and polymer included crown function group can contribute to make formation of network structure among crown function group and result in change of electrical properties.s.s.

Molecular Behavior and Electro-Chemical Properties of Dendrimer and Staff-type Polymer Monolayers in Crown Function Group (크라운 기능기를 포함한 덴드리머 및 Staff-type 고분자 단분자막의 분자거동 및 전기ㆍ화학적 특성)

  • 장정수
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.5
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    • pp.213-218
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    • 2003
  • We investigated the monolayer behavior at the air-water interface with metal solution, the surface morphologies and the electrical properties such as conductivity, The calculated conductivity values of pure water subphase and its complexes with L $i^{+}$ ions are 5.6$\times$10$^{-l6}$ and 1.9$\times$10$^{-14}$ [S/cm], respectively. And the calculated barrier height D values of pure water subphase and its complexes with Li. ions are 0.70 and 0.66 [eV], respectively. We also attempted to fabricate a crown dendrimer Langmuir-Blodgett (LB) films containing functional end group that could form a complex structure with metal ions. Also, we investigated the surface activity of dendrimer films at air-water interface. In AFM images. the larger domains irregularly shaped structures on the top while the smaller ones were free from such defects. In conclusion, it is demonstrated that the metal ion around dendrimer and polymer included crown function group can contribute to make formation of network structure among crown function group and result in change of electrical properties.s.s.

A Study on the Initial Maximum Value of Heat Flux, $q_{max}$ of Wool Fabrics (Part I) - The correlation between $q_{max}$ and thermal conductivity, thermal transmittance, surface air cavity of wool fabrics - (양모 복지의 초기열류속최대치($q_{max}$)에 관한 연구( I ) -열전도도, 열통과성, 표면기공도와의 상관성을 중심으로-)

  • Choi Suk Chul;Jung Jin Soun;Chun Tae il
    • Journal of the Korean Society of Clothing and Textiles
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    • v.15 no.4 s.40
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    • pp.367-372
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    • 1991
  • In this study, we discussed about the factors effected upon the initial maximum value of heat flux ($q_{max}$). Thermal conductivity, thermal transmittance and surface air cavity of wool fabrics were examind and their correlation to the $q_{max}$ was studied. The factors were examined which had an effect upon the $q_{max}$ of an objective measure of warm/cool feeling. It was simulated by Thermo-Labo apparatures. We selected twenty sorts of pure wool woven fabrics for men's fall -winter cloth (all Wool). The conclusions are as follows; 1. There was not a certain correlation between the $q_{max}$ and the thermal conductivity of wool fabric. 2. When the fabrics touched on the copper plates, the thickness of wool fabric had a negative correlation to the $q_{max}$. The thermal transmittance had a positive correlation. Both of them had a good correlation to the $q_{max}$. 3. As a major factor, the thickness of fabric effected on the $q_{max}$.

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Improved Thermal Conductivities of Epoxy Resins Containing Surface Functionalized BN Nanosheets

  • Weng, Ling;Wang, HeBing;Zhang, Xiaorui;Liu, Lizhu;Zhang, Hexin
    • Nano
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    • v.13 no.11
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    • pp.1850133.1-1850133.9
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    • 2018
  • The hexagonal boron nitride nanosheets (BN) were firstly treated by silane coupling agents 3-aminopropyltriethoxysilane (KH550) and 3-glycidoxypropyl-trimethoxysilane (KH560) to introduce some amino and epoxy (EP) groups on the BN surface. These modified BN nanosheets were incorporated into an EP matrix to prepare BN@KH560/EP composites with excellent thermal conductivity and electrical insulation properties. Results showed that the thermal conductivity of BN@KH560/EP composite with 20 vol% BN dosage was found to be 0.442 W/($m{\cdot}K$), which was 81% higher than that of pure EP resin. Both BN/EP composites treated by KH550 and KH560 showed rather good electrical insulation properties, although the dielectric constant of BN@KH550/EP composites were slightly higher than BN@KH560/EP composites. Moreover, BN@KH560/EP composites also showed better thermal and mechanical properties than that of BN@KH550/EP composites.

Study on Improvement of Heat Dissipation Characteristics of TIM Material Using Radiant Energy (복사에너지를 이용한 TIM소재의 방열 특성 향상을 위한 연구)

  • Hwang, Myungwon;Kim, Dohyung;Jung, Uoo-Chang;Chung, Wonsub
    • Journal of Surface Science and Engineering
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    • v.52 no.2
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    • pp.58-61
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    • 2019
  • The aim of this study is to quantitatively demonstrate the possibility of heat transfer by thermal radiation by comparing heat transfer by conventional heat transfer and radiation by radiation. 1) The heat transfer was measured by using filler of TIM material with low thermal conductivity (CuS). As a result, heat transfer was easier than ceramic with high thermal conductivity ($Al_2O_3$ and $Si_3N_4$). 2) The reason for this is thought to be that the infrared wave due to radiation of the air diaphragm has moved easily. 3) From the above results, the heat dissipation of the TIM material indicates the possibility of heat transfer by thermal radiation.

A new thermal conductivity estimation model for weathered granite soils in Korea

  • Go, Gyu-Hyun;Lee, Seung-Rae;Kim, Young-Sang;Park, Hyun-Ku;Yoon, Seok
    • Geomechanics and Engineering
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    • v.6 no.4
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    • pp.359-376
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    • 2014
  • Thermal conductivity of ground has a great influence on the performance of Ground Heat Exchangers (GHEs). In general, the ground thermal conductivity significantly depends on the density (or porosity) and the moisture content since they are decisive factors that determine the interface area between soil particles which is available for heat transfer. In this study, a large number of thermal conductivity experiments were conducted for soils of varying porosity and moisture content, and a database of thermal properties for the weathered granite soils was set up. Based on the database, a 3D Curved Surface Model and an Artificial Neural Network Model (ANNM) were proposed for estimating the thermal conductivity. The new models were validated by comparing predictions by the models with new thermal conductivity data, which had not been used in developing the models. As for the 3D CSM, the normalized average values of training and test data were 1.079 and 1.061 with variations of 0.158 and 0.148, respectively. The predictions became somewhat unreliable in a low range of thermal conductivity values in considering the distribution pattern. As for the ANNM, the 'Logsig-Tansig' transfer function combination with nine neurons gave the most accurate estimates. The normalized average values of training data and test data were 1.006 and 0.954 with variations of 0.026 and 0.098, respectively. It can be concluded that the ANNM gives much better results than the 3D CSM.

Infiltration characteristics and hydraulic conductivity of weathered unsaturated soils

  • Song, Young-Suk;Hong, Seongwon
    • Geomechanics and Engineering
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    • v.22 no.2
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    • pp.153-163
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    • 2020
  • Laboratory experiments were conducted with two different soil conditions to investigate rainfall infiltration characteristics. The soil layer materials that were tested were weathered granite soil and weathered gneiss soil. Artificial rainfall of 80 mm/hr was reproduced through the use of a rainfall device, and the volumetric water content and matric suction were measured. In the case of the granite soil, the saturation velocity and the moving direction of the wetting front were fast and upward, respectively, whereas in the case of the weathered gneiss soil, the velocity and direction were slow and downward, respectively. Rainfall penetrated and saturated from the bottom to the top as the hydraulic conductivity of the granite soil was higher than the infiltration capacity of the artificial rainfall. In contrast, as the hydraulic conductivity of the gneiss soil was lower than the infiltration capacity of the rainfall, ponding occurred on the surface: part of the rainfall first infiltrated, with the remaining rainfall subsequently flowing out. The unsaturated hydraulic conductivity function of weathered soils was determined and analyzed with matric suction and the effective degree of saturation.

Effect of initial ground temperature measurement on the design of borehole heat exchanger (초기 지중온도 측정이 지중 열교환기 설계에 미치는 영향)

  • Song, Yoon-ho;Kim, Seong-Kyun;Lee, Kang-Kun;Lee, Tae-Jong
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.600-603
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    • 2009
  • We compared relative importance of thermal conductivity and initial ground temperature in designing borehole heat exchanger network and also we test accuracy of ground temperature estimation in thermal response test using a proven 3-D T-H modeler. The effect of error in estimating ground temperature on calculated total length of borehole heat exchanger was more than 3 times larger than the case of thermal conductivity in maximum 20% error range. Considering 10% of error in estimating thermal conductivity is generally acceptable, we have to define the initial ground temperature within 5% confidence level. Utilizing the mean annual ground surface temperature and the geothermal gradient map compiled so far can be a economic way of estimating ground temperature with some caution. When performing thermal response test for estimating ground temperature as well as measuring thermal conductivity, minimum 100 minutes of ambient circulation is required, which should be even more in case of very cold and hot seasons.

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Effect of Sn Addition on the SCC Properties of Al-Cu-Mn Cast Alloy (Al-Cu-Mn 주조합금의 SCC 특성에 미치는 Sn 첨가의 영향)

  • Kim, Kwang-Nyeon;Kim, Kyung-Hyun;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.436-441
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    • 2002
  • Effect of Sn addition on the stress corrosion cracking(SCC) resistance of the Al-Cu-Mn cast alley was investigated by C-ring teat and electrical conductivity measurement, The electrical conductivity and SCC resistance increased by Sn addition. The alley containing 0,10%Sn showed maximum electrical conductivity and the best SCC resistance. At the same composition, the electrical conductivity and SCC resistance increased from peak aged condition to ever aged condition. The PFZ and coarse precipitates along the grain boundary were observed from TEM micrographs. The fracture mode of the alloy was confirmed as intergranular type and showed brittle fracture surface. The SCC mechanism of the alloy was concluded as the anodic dissolution model, The maximum hardness was increased from 130Hv in the Sn-free alloy to 156Hv in the 0.10%Sn added alloy.

Characterization of Thermal Contact Resistance Doped with Thermal Interface Material (접촉열전도재를 도포한 접촉열저항 특성연구)

  • Bajracharya, Iswor;Ito, Yoshimi;Nakayama, Wataru;Moon, Byeong-Jun;Lee, Sun-Kyu
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.9
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    • pp.943-950
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    • 2013
  • This paper describes the thermal contact resistance and its effect on the performance of thermal interface material. An ASTM D 5470 based apparatus is used to measure the thermal interface resistance. Bulk thermal conductivity of different interface material is measured and compared with manufacturers' data. Also, the effect of grease void in the contact surface is investigated using the same apparatus. The flat type thermal interface tester is proposed and compared with conventional one to consider the effect of lateral heat flow. The results show that bulk thermal conductivity alone is not the basis to select the interface material because high bulk thermal conductivity interface material can have high thermal contact resistance, and that the center voiding affects the thermal interface resistance seriously. On the aspect of heat flow direction, thermal impedance of the lateral heat flow shows higher than that of the longitudinal heat flow by sixteen percent.