• Title/Summary/Keyword: Surface conductivity

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스퍼터링 법으로 증착한 CdS 박막의 광전도도 특성 평가

  • Heo, Seong-Gi;Jang, Dong-Mi;Choe, Myeong-Sin;An, Jun-Gu;Seong, Nak-Jin;Yun, Sun-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.81-81
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    • 2008
  • Applications of CdS films in this study are to exhibit a high conductivity when they are exposed at light with visible wavelength and sequentially to show a low conductivity in dark state. For this purpose, CdS films should have a high photosensitivity, still maintaining a high conductivity at a visible light. In this study, CdS films were prepared at room temperature on glass substrates by rf magnetron sputtering. In order to increase the photo-conductivity in visible light, various defect levels should be located within the CdS band gap. In order to nucleate the defect sites within the CdS band gap, CdS films were deposited on glass substrates at room temperature using various $H_2$/(Ar+$H_2$) flow ratios by an rf magnetron sputtering. Through the investigation of the structural and photoconductive properties of CdS films by an addition of hydrogen, the relationship between photo- and dark-resistance in CdS films was investigated in detail. 200-nm-thick CdS films for photoconductive sensor applications were prepared at various $H_2$/(Ar+$H_2$) flow ratios on glass substrates at room temperature by rf magnetron sputtering. Sulfur concentration in CdS films crystallized at room temperature with (002) preferred orientation depends directly on the hydrogen atmosphere and the surface roughness of the films gradually increases with increasing hydrogen atmosphere. Films deposited at 8% of $H_2$/(Ar+$H_2$) exhibit an abrupt decrease of dark- and photo-resistance, showing a low photo-sensitivity ($R_{dark}/R_{photo}$). Onthe other hand, films deposited at a hydrogen atmosphere of 42% exhibit a photo-sensitivity of $5\times10^3$, maintaining a photo-resistance of an approximately $2\times10^4\Omega$/square. The dark- and photo-resistance values of CdS films were related with a composition, surface roughness, and defect sites within the band gap.

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Improvement of Electrical Conductivity of Carbon-Fiber Reinforced Plastics by Nano-particles Coating (나노입자 코팅 탄소섬유 강화 복합재료의 전기전도도 향상)

  • Seo, Seong-Wook;Ha, Min-Seok;Kwon, Oh-Yang;Cho, Heung-Soap
    • Composites Research
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    • v.23 no.6
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    • pp.1-6
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    • 2010
  • The electrical conductivity of carbon-fiber reinforced plastics (CFRP's) has been improved by indium-tin oxide (ITO) nano-particle coating on carbon fibers for the purpose of lightning strike protection of composite fuselage skins. ITO nano-particles were coated on the surface of carbon fibers by spraying the colloidal suspension with 10~40% ITO content. The electrical conductivity of the CFRP has been increased more than three times after ITO coating, comparable to or higher than that of B-787 composite fuselage skins with metal wire-meshes on the outer surface, without sacrificing the tensile property due to the existence of nano-particles at fiber-matrix interface. The damage area by the simulated lightning strike was also verified for different materials and conditions by using ultrasonic C-scan image. As the electrical conductivity of 40% nano-ITO coated sample surpass that of the B-787 sample, the damage area by lightning strike also appeared comparable to that of the materials currently employed for composite fuselage construction.

Correlation Between Bulk and Surface Resistivity of Concrete

  • Ghosh, Pratanu;Tran, Quang
    • International Journal of Concrete Structures and Materials
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    • v.9 no.1
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    • pp.119-132
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    • 2015
  • Electrical resistivity is an important physical property of portland cement concrete which is directly related to chloride induced corrosion process. This study examined the electrical surface resistivity (SR) and bulk electrical resistivity (BR) of concrete cylinders for various binary and ternary based high-performance concrete (HPC) mixtures from 7 to 161 days. Two different types of instruments were utilized for this investigation and they were 4 point Wenner probe meter for SR and Merlin conductivity tester for bulk resistivity measurements. Chronological development of electrical resistivity as well as correlation between two types of resistivity on several days was established for all concrete mixtures. The ratio of experimental surface resistance to bulk resistance and corresponding resistivity was computed and compared with theoretical values. Results depicted that bulk and SR are well correlated for different groups of HPC mixtures and these mixtures have attained higher range of electrical resistivity for both types of measurements. In addition, this study presents distribution of surface and bulk resistivity in different permeability classes as proposed by Florida Department of Transportation (FDOT) specification from 7 to 161 days. Furthermore, electrical resistivity data for several HPC mixtures and testing procedure provide multiple promising options for long lasting bridge decks against chloride induced corrosion due to its ease of implementation, repeatability, non-destructive nature, and low cost.

Effect of Hydrogen Partial Pressure Ratio on Electrical and Structural Properties of ZnO Thin Film (ZnO 박막의 전기적 구조적 특성에 미치는 수소 분압비의 영향)

  • Lee, Sung-Hun;Shin, Min-Geun;Byon, Eung-Sun;Kim, Do-Geun;Jeon, Sang-Jo;Koo, Bon-Heun
    • Journal of Surface Science and Engineering
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    • v.39 no.6
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    • pp.250-254
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    • 2006
  • Effect of hydrogen partial pressure ratio on the structural and electrical properties of highly c-axis oriented ZnO films deposited by oxygen ion-assisted pulsed filtered vacuum arc at a room temperature was investigated. The hydrogen partial pressure ratio were $1.4%\sim9.8%$ at 40% oxygen pressure ratio. The conductivity of ZnO:H films was increased from 1.4% up to 4.2% due to relatively high carrier mobility caused by improvement of crystallinity While the conductivity of ZnO:H films were decreased over than 4.2% and (0002) orientation was also deteriorated. The lowest resistivity of ZnO:H films was $2.5{\times}10^{-3}\;{\Omega}{\cdot}cm$ at 4.2% of hydrogen pressure ratio. Transmittance of ZnO:H films in visible range was 85% which is lower than that of undoped ZnO films because of declined preferred orientation.

The Characteristics of Al Thin Films on Ar Plasma Surface Treatment (Al 박막의 Ar 플라즈마 표면처리에 따른 특성)

  • Park, Sung-Hyun;Ji, Seung-Han;Jeon, Seok-Hwan;Chu, Soon-Nam;Lee, Sang-Hoon;Lee, Neung-Hun
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1333-1334
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    • 2007
  • Al thin film was the most popular electrode in semiconductor and flat panel display world, because of its electrical conductivity, selectivity and easy to apply to thin film. However, Al thin films were not good to use on the bottom electrode about the crystalline growth of inorganic compound materials such as ZnO, AlN and GaN, because of its surface roughness and melting points. In this paper, we investigated Ar plasma surface treatment of Al thin film to enhance the surface roughness and electrical conductivity using the reactive ion etching system. Several process conditions such as RF power, working pressure and process time were controlled. In results, the surface roughness showed $15.53\;{\AA}$ when RF power was 100 W, working pressure was 50 mTorr and process time was 10 min. Also, we tried to deposit ZnO thin films on the each Al thin films, the upper conditions showed the best crystalline characteristics by x-ray diffraction.

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Hydraulic Conductivity Changes Due to Subsidence Using Rock Mass Classification Parameters (암반분류변수를 이용한 침하에 따른 수리전도도 변화 해석)

  • 윤용균;김장순;김종우
    • Tunnel and Underground Space
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    • v.13 no.4
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    • pp.321-329
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    • 2003
  • The change of strain-dependent hydraulic conductivity around mined panels due to subsidence is examined where normal and shear strains, modulus reduction ratio and joint spacing are major factors controlling the changes of hydraulic conductivity. Modulus reduction ratio and joint spacing are defined through RMR and RQD, respectively. Utilizing these two empirical parameters, changes of hydraulic conductivity values of a full gamut of rock mass conditions are determined. The change of hydraulic conductivity is not apparent in the near surface area and more significant change takes place in the area around mined panels. A zone of strong influence from the subsidence extends to a height of approximately 20m above mined panels. The shear strain does also play the role of increasing a hydraulic conductivity around mined panels. As RMR of rock mass decreases, a hydraulic conductivity is found to be increased and this means that subsidence in a poor rock with low RMR has a great effect on a hydraulic conductivity field.

Observation of Thermal Conductivity of Pressureless Sintered AlN Ceramics under Control of Y2O3 Content and Sintering Condition (Y2O3 함량과 소결조건에 따른 상압소결 AlN 세라믹스의 열전도도 고찰)

  • Na, Sang-Moon;Go, Shin-Il;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.368-372
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    • 2011
  • Aluminum nitride (AlN) has excellent thermal conductivity, whereas it has some disadvantage such as low sinterability. In this study, the effects of sintering additive content and sintering condition on thermal conductivity of pressureless sintered AlN ceramics were examined on the variables of 1~3 wt% sintering additive ($Y_2O_3$) content at $1900^{\circ}C$ in $N_2$ atmosphere with holding time of 2~10 h. All AlN specimens showed higher thermal conductivity as the $Y_2O_3$ content and holding time increase. The formation of secondary phases (yttrium aluminates) by reaction of $Y_2O_3$ and $Al_2O_3$ from AlN surface promoted the thermal conductivity of AlN specimens, because the secondary phases could reduce the oxygen contents in AlN lattice. Also, thermal conductivity was increased by long sintering time because of the uniform distribution and the elimination of the secondary phases at the grain boundary by the evaporation effect during long holding time. A carbothermal reduction reaction was also affected on the thermal conductivity. The thermal conductivity of AlN specimens sintered at $1900^{\circ}C$ for 10 h showed 130~200W/mK according to the content of sintering additive.

Ground Surface Temperature Distribution of Korea (우리나라 지표면 온도 분포)

  • Koo, Min-Ho;Song, Yoon-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.431-433
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    • 2006
  • Accurate information on the ground surface temperature is essential for design of a borehole heat exchanger and thus ensuring the performance of a ground source heat pump system along with knowledge on thermal diffusivity and conductivity of ground. In this study we analyzed the shallow subsurface temperature monitoring data of 58 Korea Meteorological Administration synoptic stations. As a result, we compiled mean annual ground surface temperature distribution map using multiple regression analysis of the monitoring data.

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Evaluation of Mechanical and Electrical Properties of Bipolar Plate Made of Fiber-reinforced Composites for PEM Fuel Cell (섬유강화 복합재를 사용한 PEM 연료전지 분리판의 전기적.기계적 특성 평가)

  • Lee, Hee-Sub;Ahn, Sung-Hoon;Jeon, Ui-Sik;Ahn, Sang-Yeoul;Ahn, Byung-Ki
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.39-46
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    • 2006
  • The fuel cell is one of promising environment-friendly energy sources for the next generation. The bipolar plate is a major component of the PEM fuel cell stack, which takes a large portion of stack cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity To achieve desired electrical properties, specimens made with different mixing ratio, processing pressure and temperature were tested. To increase mechanical strength, one or two layers of woven carbon fabric were added to the graphite and resin composite. Thus, the composite material was consisted of three phases: graphite particles, carbon fabric, and epoxy resin. By increasing mixing ratio of graphite, fabricated pressure and process temperature, the electric conductivity of the composite was improved. The results of tensile test showed that the tensile strength of the two-phase graphite composite was about 4MPa, and that of three-phase composite was increased to 57MPa. As surface properties, contact an91e and surface roughness were tested. Graphite composites showed contact angles higher than $90^{\circ}$, which mean low surface energy. The average surface roughness of the composite specimens was $0.96{\mu}m$.

Incorporation of Graphitic Porous Carbon for Synthesis of Composite Carbon Aerogel with Enhanced Electrochemical Performance

  • Singh, Ashish;Kohli, D.K.;Singh, Rashmi;Bhartiya, Sushmita;Singh, M.K.;Karnal, A.K.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.204-211
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    • 2021
  • We report, synthesis of high surface area composite carbon aerogel using additive based polymerization technique by incorporating graphitic porous carbon as additive. This additive was separately prepared using sol-gel polymerization of resorcinol-furfuraldehyde in iso-propyl alcohol medium at much above the routine gelation temperature to yield porous carbon (CA-IPA) having graphitic layered morphology. CA-IPA exhibited a unique combination of meso-pore dominated surface area (~ 700 m2/g) and good conductivity of ~ 300 S/m. The composite carbon aerogel (CCA) was synthesized by traditional aqueous medium based resorcinol-formaldehyde gelation with CA-IPA as additive. The presence of CA-IPA favored enhanced meso-porosity as well as contributed to improvement in bulk conductivity. Based on the surface area characteristics, CCA-8 composition having 8% additive was found to be optimum. It showed specific surface area of ~ 2056 m2/g, mesopore area of 827 m2/g and electrical conductivity of 180 S/m. The electrode formed with CCA-8 showed improved electrochemical behavior, with specific capacitance of 148 F/g & ESR < 1 Ω, making it a better choice as super capacitor for energy storage applications.