• Title/Summary/Keyword: Surface concentration

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Evaluation of Self-Cleaning Performance of Mortar Using Nano-Titanium Dioxide Photocatalytic Coating (나노 이산화티탄 광촉매 코팅을 적용한 모르타르의 자기정화성능 평가)

  • Yang, In-Hwan;Jeon, Hyo-Jin;Lee, Seung-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.56-65
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    • 2022
  • This paper aims at estimating self-cleaning performance of mortar coated with photocatalytic suspension under various conditions. Experimental variables included the concentration (1.5 % and 3.0 %) of photocatalytic suspension for coating mortar specimen, the presence of hydrophilic agent in photocatalytic suspension, and applying the primer on the surface of mortar. The color change of methylene blue solution increased and accordingly self-cleaning performance increased as photocatalytic concentration increased. The presence of hydrophilic agent in photocatalytic suspension slightly decreased the self-cleaning performance compared to the conventional photocatalytic suspension. Test results also showed that mortar specimen including primer and specimen not including primer did not show significantly different self-cleaning performance. In addition, cracks on the surface of mortar specimens decreased as the photocatalytic concentration increased. Therefore, increase in cracks on the surface of mortar at different photocatalytic concentration might adversely affect the self-cleaning performance of mortar specimens.

Application of Response Surface Methodology to Optimize the Performance of the Electro-Chlorination Process (전기분해 염소소독공정의 반응표면분석법을 이용한 차아염소산나트륨 발생 최적화)

  • Ju, Jaehyun;Park, Chan-gyu
    • Journal of Environmental Health Sciences
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    • v.48 no.3
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    • pp.167-175
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    • 2022
  • Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.

A Study on the Corrosion Properties and Microstructure of the Nitrocarburized and Oxidized Low Carbon Steel according to the Treatment Atmospheres (저탄소강의 질화침탄과 산화처리시 분위기 변화에 따른 조직 및 부식특성에 관한 연구)

  • Shin, P.W.;Lee, K.H.;Nam, K.S.;Park, Y.M.;Jo, H.J.
    • Journal of the Korean Society for Heat Treatment
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    • v.17 no.2
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    • pp.87-93
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    • 2004
  • Nitrocarburizing was carried out with various $CH_4$ gas composition with 4 torr gas pressure at $570^{\circ}C$ for 3 hours and post oxidation was carried out with 100% $O_2$ gas atmosphere with 4 torr at different temperatures for various time. In the case of plasma nitrocarburizing, It is that the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) and ${\gamma}^{\prime}-Fe_4$(C, N), which comprise the compound layer phase, depend on concentrations of $N_2$ gas and $CH_4$ such that when the concentration of $N_2$ and $CH_4$ increased, the ratio of ${\gamma}^{\prime}-Fe_4$(C, N) decreased, but the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) increased. The thickness of compound layer consistently increased as gas concentration increased regardless of $N_2$ and $CH_4$ expect when the concentration of $CH_4$ was 3.5 volume%, it decreased insignificantly. When oxidizing for 15min in the temperature range of $460{\sim}570{^\circ}C$, the study found small amount of $Fe_3O_4$ at the temperature of $460{^\circ}C$ and also found that amounts of $Fe_2O_3$. and $Fe_3O_4$ on the surface and amount of ${\gamma}^{\prime}-Fe_4$(C, N) in the compound layer increased as the increased over $460^{\circ}C$, but the thickness of the compound layer decreased. Corrosion resistance was influenced by oxidation times and temperature.

A Study on the Optimization of Polysilicon Solar Cell Structure (다결정 실리콘 태양전지 구조 최적화에 관한 연구)

  • Lee, Jae-Hyeong;Jung, Hak-Ki;Jung, Dong-Su;Lee, Jong-In
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.702-705
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    • 2011
  • Poly-Si wafers with resistivity of 1 [${\Omega}$-cm[ and thickness of 50 [${\mu}m$] were used as a starting material. Various efficiency influencing parameters such as rear surface recombination velocity and minority carrier diffusion length in the base region, front surface recombination velocity, junction depth and doping concentration in the Emitter layer, BSF thickness and doping concentration were investigated. Optimized cell parameters were given as rear surface recombination of 1000 [cm/sec], minority carrier diffusion length in the base region 50 [${\mu}m$], front surface recombination velocity 100 [cm/sec], sheet resistivity of emitter layer 100 [${\Omega}/{\Box}$], BSF thickness 0.5 [${\mu}m$], doping concentration $5{\times}10^{19}\;cm^{-3}$. Among the investigated variables, we learn that a diffusion length of base layer acts as a key factor to achieve conversion efficiency higher than 19.8 %. Further details of simulation parameters and their effects to cell characteristics are discussed in this paper.

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Optimization of Analytical Condition for Reliable and Accurate Measurement of Carbon Concentration in Carburized Steel by EPMA (EPMA를 이용한 침탄강의 정확하고 신뢰성 있는 탄소농도 측정을 위한 분석조건 최적화)

  • Gi-Hoon Kwon;Hyunjun Park;Byoungho Choi;Young-Kook Lee;Kyoungil Moon
    • Korean Journal of Materials Research
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    • v.33 no.3
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    • pp.106-114
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    • 2023
  • The carbon concentration in the carburized steels was measured by electron probe microanalysis (EPMA) for a range of soluted carbon content in austenite from 0.1 to 1.2 wt%. This study demonstrates the problems in carbon quantitative analysis using the existing calibration curve derived from pure iron (0.008 wt%C) and graphite (99.98 wt%C) as standard specimens. In order to derive an improved calibration curve, carbon homogenization treatment was performed to produce a uniform Kα intensity in selected standard samples (AISI 8620, AISI 4140, AISI 1065, AISI 52100 steel). The trend of detection intensity was identified according to the analysis condition, such as accelerating voltage (10, 15, 30 keV), and beam current (20, 50 nA). The appropriate analysis conditions (15 keV, 20 nA) were derived. When the carbon concentration depth profile of the carburized specimen was measured for a short carburizing time using the improved calibration curve, it proved to be a more reliable and accurate analysis method compared to the conventional analysis method.

Evaluation of Copper-Chromium-Arsenic Preservatives Fixation on Wood by Measuring the Density of Surface Electric Charge (표면전하밀도(表面電荷密度)를 이용(利用)한 동(銅)·크롬·비소계(砒素系) 방부방충제의 정착(定着)에 관(關)한 연구(硏究))

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.1
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    • pp.24-30
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    • 1990
  • This study was attempted to propose a method evaluating fixation of active ingredients in Copper-Chromium-Arsenic preservatives treatment. Fixated amount of active ingredients on wood was obtained by measuring the density of surface electric charge based on $\varsigma$ potential. Data accumulated from density of surface electric charge showed that the fixated amount of preservatives on wood increased linearly as concentration of treating solution increaced, which indicatied quantitative reactions in fixation of preservatives.

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Effect of silicon on alloying behavior of hot-dip galvannealed steel sheets (합금화 용융아연 도금강판의 합금화 거동에 미치는 실리콘의 영향)

  • 이호종;김종상
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.134-143
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    • 1999
  • The effects of silicon on galvannealing behavior of interstitial-free (IF) steels were studied. The growth rate of the Fe-Zn alloy layer was retarded as silicon in the steel added. Titanium in steel strongly favors Fe-Zn reaction, in particular outburst structures, whereas silicon inhibit them. Cross-sectional and planar views of galvannealed coatings were investigated to characterize alloy phase development. A possible mechanism to explain the retardation effect of silicon is discussed in terms of concentration on surface and inhibition layer.

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Composition and microstructure of Lead-Tin alloy electrodeposits (납-주석합금 도금층의 조성 및 조직특성)

  • 예길촌;지창훈
    • Journal of the Korean institute of surface engineering
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    • v.34 no.2
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    • pp.151-160
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    • 2001
  • The composition and the microstructure of the lead-tin alloy electrodeposited in a gluconate bath were invesitigated according to electrolysis conditions. The tin content of the lead-tin alloy electrodeposits increased with increasing current density and EDTA addition, while it decreased with increasing temperature and sodium gluconate concentration. The preferred orientation of the alloy deposits changed from the (220) plane through (200) to (200) + (111) planes with increasing cathode overpotential. The surface morphology of the films was closely related to both the preferred orientation and the alloy composition.

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THE EFFECTS OF ADDITIVES IN NICKEL AND COPPER ELECTROPLATING FOR MICROSTRUCTURE FABRICATION

  • Kim, Go-Eun;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.214-218
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    • 1999
  • The effect of additives in nickel and copper electroplating were investigated for MEMS applications. Saccharin and gelatin were used as additives in nickel and copper electroplating bath respectively. The morphology and surface hardness of electroplated coating were investigated with additive concentration. Microstructures were fabricated with optimum conditions.

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Effect of Surface Modification of CaCO3 Nanoparticles by a Silane Coupling Agent Propyltrimethoxysilane on the Stability of Emulsion and Foam (실란 커플링제 프로필트리메톡시실란에 의해 표면 개질된 CaCO3 나노입자가 에멀젼과 기포 안정성에 미치는 영향에 관한 연구)

  • Lee, YeJin;Park, KiHo;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.31 no.1
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    • pp.49-56
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    • 2020
  • In this study, surface modification of CaCO3 nanoparticles by a silane coupling agent propyltrimethoxysilane (PTMS) was conducted and the effect of surface hydrophobicity on the stability of foam and emulsion was studied in order to test the potential applicability as a foam stabilizer or an emulsifier. The surface modification of CaCO3 nanoparticles by PTMS was confirmed by FT-IR, DSC and TGA analysis. The atomic concentration of CaCO3 particle surface treated by PTMS has been also identified by using XRD and XPS analyses. Both floating tests and contact angle measurements were also performed to examine the effect of PTMS concentration on the surface modification of CaCO3 nanoparticles.