• 제목/요약/키워드: Surface concentration

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나노 이산화티탄 광촉매 코팅을 적용한 모르타르의 자기정화성능 평가 (Evaluation of Self-Cleaning Performance of Mortar Using Nano-Titanium Dioxide Photocatalytic Coating)

  • 양인환;전효진;이승진
    • 한국건설순환자원학회논문집
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    • 제10권1호
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    • pp.56-65
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    • 2022
  • 본 연구에서는 시설물의 자기정화성능을 확보하기 위하여 이산화티탄 광촉매 용액을 코팅한 모르타르의 자기정화성능을 분석하였다. 광촉매 코팅 용액의 농도(1.5 %와 3.0 %), 초친수강화 용액 적용 유무 및 프라이머 용액의 사용 유무를 실험변수로 고려하였다. 광촉매 농도가 증가할수록 메틸렌블루 수용액의 색상 변화율이 증가하였으며, 이는 광촉매 농도가 증가할수록 자기정화성능이 증가하는 것을 나타낸다. 초친수성 광촉매 용액의 적용은 일반 광촉매 용액에 비해 자기정화성능을 다소 감소시킬 가능성이 있음을 나타낸다. 또한, 프라이머를 사용한 모르타르의 자기정화성능은 프라이머를 사용하지 않은 모르타르의 자기정화성능과 뚜렷한 차이를 나타내지 않는다. 한편, 낮은 농도(1.5 %)로 코팅된 모르타르에 비해 높은 농도(3.0 %)로 코팅된 모르타르 시편 표면의 코팅 균열이 미세하여 상대적으로 큰 광촉매 반응면적을 확보하고 자기정화성능 증가에 유리한 영향을 미친 것으로 판단된다.

전기분해 염소소독공정의 반응표면분석법을 이용한 차아염소산나트륨 발생 최적화 (Application of Response Surface Methodology to Optimize the Performance of the Electro-Chlorination Process)

  • 주재현;박찬규
    • 한국환경보건학회지
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    • 제48권3호
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    • pp.167-175
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    • 2022
  • Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.

저탄소강의 질화침탄과 산화처리시 분위기 변화에 따른 조직 및 부식특성에 관한 연구 (A Study on the Corrosion Properties and Microstructure of the Nitrocarburized and Oxidized Low Carbon Steel according to the Treatment Atmospheres)

  • 신평우;이구현;남기석;박율민;조형준
    • 열처리공학회지
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    • 제17권2호
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    • pp.87-93
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    • 2004
  • Nitrocarburizing was carried out with various $CH_4$ gas composition with 4 torr gas pressure at $570^{\circ}C$ for 3 hours and post oxidation was carried out with 100% $O_2$ gas atmosphere with 4 torr at different temperatures for various time. In the case of plasma nitrocarburizing, It is that the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) and ${\gamma}^{\prime}-Fe_4$(C, N), which comprise the compound layer phase, depend on concentrations of $N_2$ gas and $CH_4$ such that when the concentration of $N_2$ and $CH_4$ increased, the ratio of ${\gamma}^{\prime}-Fe_4$(C, N) decreased, but the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) increased. The thickness of compound layer consistently increased as gas concentration increased regardless of $N_2$ and $CH_4$ expect when the concentration of $CH_4$ was 3.5 volume%, it decreased insignificantly. When oxidizing for 15min in the temperature range of $460{\sim}570{^\circ}C$, the study found small amount of $Fe_3O_4$ at the temperature of $460{^\circ}C$ and also found that amounts of $Fe_2O_3$. and $Fe_3O_4$ on the surface and amount of ${\gamma}^{\prime}-Fe_4$(C, N) in the compound layer increased as the increased over $460^{\circ}C$, but the thickness of the compound layer decreased. Corrosion resistance was influenced by oxidation times and temperature.

다결정 실리콘 태양전지 구조 최적화에 관한 연구 (A Study on the Optimization of Polysilicon Solar Cell Structure)

  • 이재형;정학기;정동수;이종인
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2011년도 춘계학술대회
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    • pp.702-705
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    • 2011
  • 고효율 다결정 태양전지 제작의 방향을 제시하기 위해 PC1D 프로그램을 이용하여 전, 후면 재결합 속도, 소수 캐리어 확산거리, 접합깊이, 에미터 층 면저항, 후면 전계층이 미치는 영향을 조사하였다. 최적화된 전지 파라미터는 후면 재결합 속도 1000 cm/sec, 베이스 층에서의 소수 캐리어 확산거리 50 [${\mu}m$], 전면 재결합 속도 100 [cm/sec], 에미터 층 면저항 $100{\Omega}/\Box$, 후면 전계층 두께 및 도핑 농도는 각각 0.5 [${\mu}m$]와 $5{\times}10^{19}\;cm^{-3}$로 조사되었다. 특히 19.8% 이상의 변환효율을 얻기 위해서는 베이스층의 확산거리가 가장 중요한 파라미터임을 알 수 있었다.

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EPMA를 이용한 침탄강의 정확하고 신뢰성 있는 탄소농도 측정을 위한 분석조건 최적화 (Optimization of Analytical Condition for Reliable and Accurate Measurement of Carbon Concentration in Carburized Steel by EPMA)

  • 권기훈;박현준;최병호;이영국;문경일
    • 한국재료학회지
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    • 제33권3호
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    • pp.106-114
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    • 2023
  • The carbon concentration in the carburized steels was measured by electron probe microanalysis (EPMA) for a range of soluted carbon content in austenite from 0.1 to 1.2 wt%. This study demonstrates the problems in carbon quantitative analysis using the existing calibration curve derived from pure iron (0.008 wt%C) and graphite (99.98 wt%C) as standard specimens. In order to derive an improved calibration curve, carbon homogenization treatment was performed to produce a uniform Kα intensity in selected standard samples (AISI 8620, AISI 4140, AISI 1065, AISI 52100 steel). The trend of detection intensity was identified according to the analysis condition, such as accelerating voltage (10, 15, 30 keV), and beam current (20, 50 nA). The appropriate analysis conditions (15 keV, 20 nA) were derived. When the carbon concentration depth profile of the carburized specimen was measured for a short carburizing time using the improved calibration curve, it proved to be a more reliable and accurate analysis method compared to the conventional analysis method.

표면전하밀도(表面電荷密度)를 이용(利用)한 동(銅)·크롬·비소계(砒素系) 방부방충제의 정착(定着)에 관(關)한 연구(硏究) (Evaluation of Copper-Chromium-Arsenic Preservatives Fixation on Wood by Measuring the Density of Surface Electric Charge)

  • 김영숙
    • Journal of the Korean Wood Science and Technology
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    • 제18권1호
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    • pp.24-30
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    • 1990
  • This study was attempted to propose a method evaluating fixation of active ingredients in Copper-Chromium-Arsenic preservatives treatment. Fixated amount of active ingredients on wood was obtained by measuring the density of surface electric charge based on $\varsigma$ potential. Data accumulated from density of surface electric charge showed that the fixated amount of preservatives on wood increased linearly as concentration of treating solution increaced, which indicatied quantitative reactions in fixation of preservatives.

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합금화 용융아연 도금강판의 합금화 거동에 미치는 실리콘의 영향 (Effect of silicon on alloying behavior of hot-dip galvannealed steel sheets)

  • 이호종;김종상
    • 한국표면공학회지
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    • 제32권2호
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    • pp.134-143
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    • 1999
  • The effects of silicon on galvannealing behavior of interstitial-free (IF) steels were studied. The growth rate of the Fe-Zn alloy layer was retarded as silicon in the steel added. Titanium in steel strongly favors Fe-Zn reaction, in particular outburst structures, whereas silicon inhibit them. Cross-sectional and planar views of galvannealed coatings were investigated to characterize alloy phase development. A possible mechanism to explain the retardation effect of silicon is discussed in terms of concentration on surface and inhibition layer.

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납-주석합금 도금층의 조성 및 조직특성 (Composition and microstructure of Lead-Tin alloy electrodeposits)

  • 예길촌;지창훈
    • 한국표면공학회지
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    • 제34권2호
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    • pp.151-160
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    • 2001
  • The composition and the microstructure of the lead-tin alloy electrodeposited in a gluconate bath were invesitigated according to electrolysis conditions. The tin content of the lead-tin alloy electrodeposits increased with increasing current density and EDTA addition, while it decreased with increasing temperature and sodium gluconate concentration. The preferred orientation of the alloy deposits changed from the (220) plane through (200) to (200) + (111) planes with increasing cathode overpotential. The surface morphology of the films was closely related to both the preferred orientation and the alloy composition.

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THE EFFECTS OF ADDITIVES IN NICKEL AND COPPER ELECTROPLATING FOR MICROSTRUCTURE FABRICATION

  • Kim, Go-Eun;Lee, Jae-Ho
    • 한국표면공학회지
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    • 제32권3호
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    • pp.214-218
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    • 1999
  • The effect of additives in nickel and copper electroplating were investigated for MEMS applications. Saccharin and gelatin were used as additives in nickel and copper electroplating bath respectively. The morphology and surface hardness of electroplated coating were investigated with additive concentration. Microstructures were fabricated with optimum conditions.

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실란 커플링제 프로필트리메톡시실란에 의해 표면 개질된 CaCO3 나노입자가 에멀젼과 기포 안정성에 미치는 영향에 관한 연구 (Effect of Surface Modification of CaCO3 Nanoparticles by a Silane Coupling Agent Propyltrimethoxysilane on the Stability of Emulsion and Foam)

  • 이예진;박기호;임종주
    • 공업화학
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    • 제31권1호
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    • pp.49-56
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    • 2020
  • 본 연구에서는 실란 커플링제 프로필트리메톡시실란(propyltrimethoxysilane, PTMS)을 사용하여 CaCO3 나노입자의 표면을 개질하였으며, 개질된 CaCO3 나노입자를 에멀젼 유화제 및 기포 안정화제로의 적용 가능성을 시험하고자 나노입자 표면의 소수성 변화가 기포와 에멀젼의 안정성에 미치는 영향에 관하여 살펴보았다. PTMS에 의한 CaCO3 나노입자의 표면 개질은 FT-IR, TGA, DSC 분석을 통하여 확인하였으며, XRD 및 XPS 분석을 통하여 나노입자 표면의 원소 분석을 실행하였다. 또한 부상 시험과 접촉각 측정을 통하여 PTMS 농도가 CaCO3 나노입자의 표면 개질에 미치는 영향에 관하여 살펴보았다.