• 제목/요약/키워드: Surface concentration

검색결과 6,123건 처리시간 0.039초

Characteristics of electrodeposited bismuth telluride thin films with different crystal growth by adjusting electrolyte temperature and concentration

  • Yamaguchi, Masaki;Yamamuro, Hiroki;Takashiri, Masayuki
    • Current Applied Physics
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    • 제18권12호
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    • pp.1513-1522
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    • 2018
  • Bismuth telluride ($Bi_2Te_3$) thin films were prepared with various electrolyte temperatures ($10^{\circ}C-70^{\circ}C$) and concentrations [$Bi(NO_3)_3$ and $TeO_2:1.25-5.0mM$] in this study. The surface morphologies differed significantly between the experiments in which these two electrodeposition conditions were separately adjusted even though the applied current density was in the same range in both cases. At higher electrolyte temperatures, a dendrite crystal structure appeared on the film surface. However, the surface morphology did not change significantly as the electrolyte concentration increased. The dendrite crystal structure formation in the former case may have been caused by the diffusion lengths of the ions increasing with increasing electrolyte temperature. In such a state, the reactive points primarily occur at the tops of spiked areas, leading to dendrite crystal structure formation. In addition, the in-plane thermoelectric properties of $Bi_2Te_3$ thin films were measured at approximately 300 K. The power factor decreased drastically as the electrolyte temperature increased because of the decrease in electrical conductivity due to the dendrite crystal structure. However, the power factor did not strongly depend on the electrolyte concentration. The highest power factor [$1.08{\mu}W/(cm{\cdot}K^2$)] was obtained at 3.75 mM. Therefore, to produce electrodeposited $Bi_2Te_3$ films with improved thermoelectric performances and relatively high deposition rates, the electrolyte temperature should be relatively low ($30^{\circ}C$) and the electrolyte concentration should be set at 3.75 mM.

PC1D 기반의 2스텝 도핑을 통한 실리콘 태양전지의 최적화

  • 김영필;정우원;이준신
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.256-256
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    • 2009
  • This paper presents a proper condition to achieve above 17 % conversion efficiency using PC1D simulator. Crystalline silicon wafer with thickness of $240{\mu}m$ was used as a starting material. Various efficiency influencing parameters such as rear surface recombination velocity and minority carrier diffusion length in the base region, front surface recombination velocity, junction depth and doping concentration in the Emitter layer. Among the investigated variables, we learn that 2nd doping concentration as a key factor to achieve conversion efficiency higher than 17 %.

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Photomask를 이용한 electroetching의 부식거동 (Etching behavior of electroetching by using photomask)

  • 김동규;이홍로
    • 한국표면공학회지
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    • 제28권2호
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    • pp.101-109
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    • 1995
  • Electroetching rates of $FeCl_3$ solution were increased according to increasing solution temperature. Activation energy of electroetching at Be'36 and 5A/$dm^2$ condition was 28.3Kcal and also, at Be'46 and 5A/dm$^2$ condition was 33.2Kcal. At Be'36 concentration of $FeCl_3$ solution, electroetching rate were more higher than at Be'46 concentration. Surfaces of etched grooves obtained at 8A/$dm^2$ or higher current density in 46 Be' concentration of $FeCl_3$ solution were observed to be flat and smooth owing to suppressing chemical etching reaction. Distinctly etched boundaries became to be appeared at 2A/$dm^2$ in Be'41 electroetching condition by differential effects. In case of applying 8A/$dm^2$ current density to Be'46 of $FeCl_3$ solution, etching depth were 4 times and side etching were 6 times more than chemical etching case respectively.

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페룰 가공용 무심연삭기의 가공변수에 관한 연구 (A Study on Machining Variable of centerless Grinding using for Ferrule Machining)

  • 박봉진;이은상;최헌종;이석우;조순주
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 춘계학술대회 논문집
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    • pp.28-31
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    • 2002
  • This paper compared the surface roughness with variables before development of centerless grinding using far ferrule machining. In this paper, theoretical surface roughness is obtained from variables such as mesh number, rate of concentration of grinding wheel, wheel rotation of work-piece etc., and optimum condition of machining is selected. For satisfaction the technical side and economical side, centerless grinding using fur ferrule machining should be designed more than #600, 18.8% rate of concentration of grinding wheel, 1440rpm wheel rotation outwork-piece.

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탈지분유 전처리에 의한 면직물의 물성 (The Physical Properties of Cotton Fabric Pretreated with Skim Milk Powder)

  • 이수민;송화순
    • 한국염색가공학회지
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    • 제17권1호
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    • pp.52-59
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    • 2005
  • The purpose of this study is to establish the scientific data of cotton fabric pretreated with skim milk powder and to improve the dyeability. The surface monophology, add on, whiteness, stiffness, air permeability, moisture regain and absorption of cotton fabrics were evaluated by varying concentration of SMP to get the optimal conditions in pretreatment. FT-IR of cotton fabrics pretreated with SMP were measured. Amino acid compositions, viscosity of SMP were evaluated. The K/S values by varying concentration of cinnamon cassia and subtract of dyed SMP-C were measured. I attempted to evalute the color fastness of untreated and AI. The results are as follow; The optimal concentration of SMP was 9%(w/v) to be pretreated with cotton fabrics. From FT-IR spectrum, formation of -NH$_2$ and -COOH was verified by SMP-C. Denaturalization of protein and condensation of carbohydrate, fat, etc. were found in a measurement of amino acid and viscocity. The K/S value of cotton fabrics pretreated with SMP was higher than that of untreated. Most of the color fastnesses were great.

Dissolution Characteristics of Liquid Carbon Dioxide Injected at the Intermediate Depth of the Ocean

  • Namjin Kim, Jaeyong-Lee;Byungki Hur;Taebeom Seo;Kim, Chongbo
    • Journal of Mechanical Science and Technology
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    • 제14권11호
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    • pp.1276-1285
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    • 2000
  • The solubility, the surface concentration and the dissolution behavior of carbon dioxide in deep sea were numerically investigated. Base on the calculations the relations between the surface concentration of liquid carbon dioxide droplet with the hydrate film and the solubility and those between the ambient carbon dioxide concentration in the plume and the dissolution rate were obtained. The result show that a carbon dioxide droplet is released both at 1000 m in depth with the initial droplet diameter of 0.011 m or less and at 1500 m in depth with a diameter of 0.015 m or less, and the droplet is completely dissolved below 500 m in depth. The hydrate film acts as a resistant layer for the dissolution of liquid carbon dioxide, and the effect of the hydrate film on the dissolution of liquid carbon dioxide depended upon the depth.

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제설제 살포에 따른 콘크리트 포장의 염화물 침투특성 (Characteristics of Chloride Penetration due to Sprinkle of the Deicing Salt on the Concrete Pavement)

  • 박진호;김명유;양은익;이성태;박해균
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.475-478
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    • 2005
  • Deicing salt has been generally used for traffic safety in winter, and the amount is increasing every year. However, deicing salt may induce the decrease of bond strength, surface scaling, and environmental pollution, etc. the purpose of this paper is to suggest the fundamental data on safety and durability for concrete structures through the estimation of chloride concentration profile and chloride diffusion coefficient. According to the test results, the critical chloride concentration($0.9\~1.2kg/m^3$)was measured at depth $23\~30mm$, and the limit chloride concentration($0.3kg/m^3$)was reached to depth 40mm. Also the surface chloride amount indicates 3.45kg per concrete unit weight, and the results showed the possibility of corrosion by deicing salt penetration.

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계면활성제를 첨가한 액적의 증발냉각 (Evaporation Cooling of a Droplet containing a Surfactant)

  • 유갑종;방창훈;김현우
    • 대한기계학회논문집B
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    • 제27권4호
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    • pp.424-431
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    • 2003
  • The evaporation cooling phenomenon of a droplet containing a surfactant on a heated surface has been studied experimentally. The two kinds of heater modules made of brass and Teflon$^{TM}$ were tested to investigate the cooling characteristics of droplet. Solutions of water containing Sodium Lauryl Sulfate(0 ppm, 100 ppm, 1000 ppm) were tested in the experiments. The results showed that the contact angle decrease as the concentration of surfactant increases. The tendency did not very with different heated solid materials. As initial temperature of the heated surface becomes high, time averaged heat flux increases and evaporation time decreases with the denser concentration of surfactant. Therefore, water with denser concentration of surfactant could be effective to cool flammable materials. However, the effect of surfactant becomes low as the material temperature is higher than the boiling temperature of water.

견의 탄닌처리에 관한 연구(III) - 축합형 탄닌과 가수분해형 탄닌의 비교 - (A Study on the Tannin Treatment of Silk Fabrics(III) - Comparion Condensed Tannin with Hydrlyzable Tannin -)

  • 설정화;최석철;조경래
    • 한국염색가공학회지
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    • 제7권3호
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    • pp.60-67
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    • 1995
  • This study was made to investigate the effect of silk fabrics treated with mimosa and tannic acid-weighting effect, surface color according to temprature, treatment time, concentration, pH. The results were as follows ; 1. The wavelength of maximum absorption of mimosa and tannic acid solution appeared at 278.5nm and 275.0nm, respectively. By the irradiation, spectra at wavelength of maximum absorption of mimosa solution disappeared, but those of tannic acid solution decreased after 48hr irradiation. 2. The tannin weighting increased with the increase of concentration, treatment temperature at 8$0^{\circ}C$, acidic condition. In case of tannic acid, it was higher than mimosa. 3. Surface color of silk fabric with mimosa changed from 2.8YR to 5.8YR acc-ording to the increase o( tannin concentration but in case of tannic acid itchanged from 4.2Y to 3.9Y. It was more changed acidic or alkaline conditionthan origine solution.

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전해 가공을 이용한 텅스텐 카바이드 미세축 제작 (Fabrication of Tungsten Carbide Microshaft Using Electrochemical Machining)

  • 강명주;오영탁;주종남
    • 한국정밀공학회지
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    • 제19권3호
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    • pp.80-87
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    • 2002
  • Tungsten carbide microshaft is used as micro-punch, electrode of MEDM (micro-electro-discharge machining), and micro-tool because it has high hardness and high rigidity. In this study, the tungsten carbide microshaft was fabricated using electrochemical machining. Concentration of material removal at the sharp edge and metal corrosion layer affect the shape of the microshaft. Control of microshaft shape was possib1e through conditioning the machining voltage and electrolyte concentration. By applying periodic voltage, material removal rate increased and surface roughness improved. The fabricated microshaft in $H_2 SO_4$ electrolyte maintained sharper end edge and better surface finish than those fabricated by other electrolytes.