• Title/Summary/Keyword: Surface concentration

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Effect of Nitrogen Application Levels on Nitrate Concentration in Soil Solution under Plastic Film House

  • Lee, Chang Hoon;Kang, Seong Soo;Kim, Myung Sook;Kim, Yoo Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.30-35
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    • 2015
  • This study was conducted to investigate investigated the effect of nitrogen fertilizer on nitrate concentration in soil solution and to determine the relationship between yield and nitrate concentration in soil solution for cucumber cultivation under plastic film house. Nitrogen as urea was applied at rates of 0, 120, 240, 360, and $480kg\;N\;ha^{-1}$ as an additional fertilizer by trickle irrigation during cucumber cultivation. Monitoring of nitrate concentration in soil solution was investigated using porous cups at 25 cm depth under soil surface. Nitrate concentration in soil solution increased with increasing the rate of additional nitrogen. Correlation coefficient between EC value and nitrate concentration was positive in soil and soil solution (p<0.05). An additional nitrogen of about $300kg\;ha^{-1}$ was shown the highest yield of cucumber, and improved yield by 5% compared to N recommendation of $240kg\;N\;ha^{-1}$. The highest yield was determined at nitrate concentration of $82mg\;L^{-1}$ in soil solution by regression equation ($Y=74.2+0.73X+0.000504X^2$, $R^2=0.629^*$). These results means indicate that nitrate concentration in soil solution would be useful method to rapid determination for additional nitrogen during cucumber cultivation under plastic film house.

Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato;Tanaka, Keiji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.5-6
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    • 2006
  • Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

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Laser Surface Alloying of Alloy 600 to Improve Its Corrosion Resistance (Allow 600 합금의 내부식성 향상을 위한 레이저 표면 합금화)

  • 신진국;강석중;서정훈;국일현;김정수
    • Laser Solutions
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    • v.2 no.1
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    • pp.16-21
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    • 1999
  • The surface of Alloy 600 was alloyed using a continuous wave $CO_2$ laser beam in order to improve its corrosion resistance. Laser surface alloying (LSA) was done by melting the surface electroplated with Cr of the alloy. The Cr concentration of the alloyed surface was 28-30 at.%, which is similar to that of Alloy 690. Alloying elements in the alloyed layer was observed to be distributed very homogeneously all over the alloyed region. According to the electrochemical and modified Huey tests, the corrosion resistance, in particular the grain boundary corrosion resistance, of the LSA specimens was significantly improved, compared with that of the as-received(AR) specimen. This improved corrosion resistance of the alloyed specimen might be attributed to the high Cr content which could make possible formation of more stable and dense passive film onto its surface.

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Experimental and Theoretical Study on the Effect of Pressure on the Surface Reaction over Platinum Catalyst (백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구)

  • Kim, Hyung-Man
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.1-6
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    • 2000
  • Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

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Monitoring of Indicator Microorganism Concentrations of River Sediment and Surface Water in the Geum River Basin (금강 수계 내 하천퇴적물 및 지표수의 지표미생물 농도분포)

  • Kim, Geonha
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.125-132
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    • 2010
  • Characterization of sediment quality is important for the proper management of surface water quality, yet sediment has not been monitored sufficiently. In this study, fecal indicator microorganism concentrations of sediments in the Geum River Basin were monitored. Sampling was carried out at one paddy field, one lakeshore and five monitoring stations in the lower reach of the Geum River Basin. Surface waters and sediments were sampled four times during rainy season. Total coliform concentrations of sediments were 12 times higher in average to those of surface waters while E. coli concentrations of sediments were six times higher. No correlation found between indicator microorganism concentration between surface waters and sediments.

Surface-enhanced Raman Spectroscopy of Ethephone Adsorbed on Silver Surface

  • Lee, Chul-Jae;Kim, Hee-Jin;Karim, Mohammad Rezaul;Lee, Mu-Sang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.545-548
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    • 2006
  • We investigated the Surface-enhanced Raman Spectroscopy (SERS) spectrum of ethephone (2-chloroethylphosphonic acid). We observed significant signals in the ordinary Raman spectrum for solid-state ethephone as well as when it was adsorbed on a colloidal silver surface, strong vibrational signals were obtained at a very low concentration. The SERS spectra were obtained by silver colloids that were prepared by the $\gamma$-irradiation method. The influence of pH and the influence of anion $(Cl^-,\;Br^-,\;I^-)$ on the adsorption orientation were investigated. Two different adsorption mechanisms were deduced, depending on the experimental conditions. The chlorine atom or the chlorine and two oxygen atoms were adsorbed on the colloidal silver surface. Among halide ions, $Br^-$ and $I^-$ were more strongly adsorbed on the colloidal silver surfaces. As a result, the adsorption of ethephone was less effective due to their steric hinderance.

Extraction of Exact Layer Thickness of Ultra-thin Gate Dielectrics in Nanoscaled CMOS under Strong Inversion

  • Dey, Munmun;Chattopadhyay, Sanatan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.10 no.2
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    • pp.100-106
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    • 2010
  • The impact of surface quantization on device parameters of a Si metal oxide semiconductor (MOS) capacitor has been analyzed in the present work. Variation of conduction band bending, position of discrete energy states, variation of surface potential, and the variation of inversion carrier concentration at charge centroid have been analyzed for different gate voltages, substrate doping concentrations and oxide thicknesses. Oxide thickness calculated from the experimental C-V data of a MOS capacitor is different from the actual oxide thickness, since such data include the effect of surface quantization. A correction factor has been developed considering the effect of charge centroid in presence of surface quantization at strong inversion and it has been observed that the correction due to surface quantization is crucial for highly doped substrate with thinner gate oxide.

Surface Characterization of Al Coated Steel Treated with Cerium Nitrate (Ce화합물로 표면처리한 Al도금강판의 표면 분석 연구)

  • Lee, Do-Hyung
    • Analytical Science and Technology
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    • v.14 no.6
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    • pp.494-498
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    • 2001
  • In this study, cerium nitrate was used as an alternative to chromate for the surface-treatment of Al coated steel to improve the corrosion resistance. The surface of Al coated steel was characterized by means of a X-ray photoelectron spectroscopy(XPS). It was found that cerium on the surface of Al coated steel had a mixture of oxidation states such as Ce(+4) and Ce(+3), and the relative concentration of each state was 57 % and 43 %, respectively. The surface film consisting of these cerium compounds played an important role for achieving the corrosion resistance of Al coated steel.

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Surface Modification of Polyurethane Film Using Atmospheric Pressure Plasma (대기압 플라스마에 의한 폴리우레탄 필름의 표면 개질)

  • Yang In-Young;Myung Sung-Woon;Choi Ho-Suk;Kim In-Ho
    • Polymer(Korea)
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    • v.29 no.6
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    • pp.581-587
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    • 2005
  • Commercial polyurethane film (PU) was modified with Ar plasma ionized in dielectric barrier discharge (DBD) plate-type reactor under atmospheric pressure. We measured the change of the contact angle and the surface fee energy with respect to the plasma treatment conditions such as treatment time, RF-power, and Ar gas flow rate. We also optimized the plasma treatment conditions to maximize the surface peroxide concentration. At the plasma treatment time of 70 sec, the power of 120 W and the Ar gas flow rate of 5 liter per minute (LPM), the best wettability and the highest surface fee energy were obtained. The 1,1 diphenyl-2-picrylhydrazyl (DPPH) method confirmed that the surface peroxide concentration was about 2.1 nmol/$\cm^{2}$ at 80 W, 30 sec, 6 LPM.

Electrostatic Interaction between Mercaptoundecanoic-acid Layers on Gold and ZrO2 Surfaces (금 표면 위의 메르캡토언데카노익산층 표면과 이산화지르코늄 표면 사이의 정전기적 상호작용)

  • Park, Jin-Won
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.607-612
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    • 2014
  • The physical properties of mercaptoundecanoic-acid layer formed on gold surfaces, which may affect the distribution of either gold particles adsorbed to the zirconium dioxide surface or vice versa, were investigated. To conduct this investigation, the surface forces were measured between the surfaces with respect to the salt concentration and pH value using atomic force microscope (AFM). The forces were quantitatively converted by the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to the surface potential and charge density of surfaces. The converted-value dependence on the salt concentration and pH was described with the law of mass action, and the dependence was consistent with the theoretical prediction. It was found that the mercaptoundecanoic-acid layer had higher values for the surface charge densities and potentials than the $ZrO_2$ surfaces, which may be attributed to the ionized-functional-groups of the mercaptoundecanoic-acid layer.