• Title/Summary/Keyword: Surface concentration

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Removal Characterics of $SO_x$ by CuO Impregnated ${\gamma}-Alumina$ (${\gamma}-Alumina$에 담지된 산화구리에 의한 $SO_x$가스의 제거 특성)

  • 이창선;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.11 no.3
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    • pp.29-35
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    • 1996
  • Numerical solutions were obtained to the model equations for various parameters characterizing the pore structure, effective internal diffusion and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly depend on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. And the conversion were affected by gas flow rate and pore size distribution of the reacting solid.

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Effect of Solution Compositions on Properties of Ni-Fe Nano Thin Film and Wire Made by Electrodeposition Method (Electrodeposition법으로 제조한 Ni-Fe 나노박막 및 나노선의 특성에 미치는 용액 조성의 영향)

  • Koo, Bon-Keup
    • Journal of the Korean institute of surface engineering
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    • v.43 no.5
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    • pp.243-247
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    • 2010
  • The micro Vickers hardness and internal stress of Ni-Fe metal thin film synthesized by electrodeposition method at $25^{\circ}C$ were studied as a function of bath composition, and surface microstructure and atomic compositions of thin films were investigated by SEM and EDS. And the shape change of $200\;{\AA}$ Ni-Fe nanowires made using anodic aluminum oxide(AAO) templates by electrodeposition method were observed by SEM as a function of ultrasonic treatment time and bath composition. The Fe deposition contents on the substrate non-linearly increased with Fe ion concentration over total metal ion concentration. In case of low Fe contents film, the grain size is smaller and denser than high Fe contents deposited films, and the micro Vickers hardness increased with Fe contents of electrodeposited films. These results affected the shape change of nanowire after ultrasonic treatments.

The Estimation of Outdoor Insulation According to the Concentration of Surface Discharge (표면방전의 집중에 따른 옥외용 설비의 성능평가)

  • Lim, Jang-Seob;Jeong, Seung-Chun;Lee, Jin;No, Jin-Yang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.212-216
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    • 2001
  • The conventional tracking testing as IEC-60587 is widely used in surface aging measurement of outdoor insulator because those testing can carry out very short time in Lab-testing. Also IEC-60587 testing is able to offer the standard judgement of relative degradation level of outdoor HV machine/system. Therefore it is very useful method compare to previous conventional tracking testing method and effective Lab-testing method. But surface discharges(SD) have very complex characteristics of discharge pattern so it is required estimation research to development of precise analysis method. In recent, the study of IRR-camera is carrying out discover of temperature of power equipment through condition diagnosis and system development of degradation diagnosis. In this study, SD occurred from procelain insulator, used 22.9[KV] distribution, is measured with partial temperature distribution in real time, the degradation grade of SD is analyzed through produced patterns in SD concentration according to applied time.

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INVESTIGATION ON MATERIAL DEGRADATION OF ALLOY 617 IN HIGH TEMPERATURE IMPURE HELIUM COOLANT

  • Kim, Dong-Jin;Lee, Gyeong-Geun;Jeong, Su-Jin;Kim, Woo-Gon;Park, Ji-Yeon
    • Nuclear Engineering and Technology
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    • v.43 no.5
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    • pp.429-436
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    • 2011
  • The corrosion of materials exposed to high temperature helium in a very high temperature reactor is caused by interaction with the impurities in the helium. This interaction then induces high temperature mechanical deterioration. By considering the effect of the impurity concentration on material corrosion, a long-term coolant chemistry guideline can be determined for the range of impurity concentration at which the material is stable for a long time. In this work, surface reactions were investigated by analyzing the thermodynamics and the experimental results for Alloy 617 exposed to controlled impure helium at $950^{\circ}C$. Moreover, the surfaces were examined for the Alloy 617 crept in air and in uncontrolled helium, which was explained by possible surface reactions.

Composite coating of Suspended Inert Particles in the Rotating Disk Electrode (회전원판 전극에서 비활성 현탁분체의 복합도금)

  • 박세용;김래현;김진성;최창균
    • Journal of the Korean institute of surface engineering
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    • v.25 no.2
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    • pp.73-81
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    • 1992
  • The composite coating of suspended inert particles $\alpha$-Al2O3 and copper from acid sulphate bath was investigated at the Rotating Disk Electrode. Effects of rotation speeds of electrode, physical properties of electrolyte, the size and concentration of suspended particles on the codeposition ratio of Al2O3 and the enhancement of mass transfer of copper ions were examined. Particularly, new experimental method for the measurement of the codeposition ratio was suggested and also the characteristics of the composite coating layer were measured by Rutherford Backscattering Spectrometry. Mass transfer of suspended particles system were increased up to 40% more than those of without suspended particles system. Optimum conditions of current density, hydrodynamics of RDE, and particles concentration showing maximum codeposition ratio were appeared in our experimental ranges. It was shown that the suspended inert particles were codeposited mainly near the surface of the composite coating layer.

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Molybdate Chemical Conversion Coating of Electro-Galvanized Steel (전기아연도금 강판의 몰리브데이트 화성처리)

  • 김헌태;김인수
    • Journal of the Korean institute of surface engineering
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    • v.37 no.4
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    • pp.200-207
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    • 2004
  • Molybdate chemical conversion coating layer formed on EGI has been studied in view of corrosion resistance, surface morphologies, and phases formed. It was found that coating layer consists of$ MoO_3$, $MoO_2$, Mo oxides having lower valences than 4 and ZnO. It is interesting to note that the coating layer formed at high Mo concentration (30 g/l) in the temperature range of $40-60^{\circ}C$ exhibited relatively high corrosion resistance, although thickness of coating layer is nearly identical with those formed under the other conditions. It was believed that an increase of driving force due to high Mo concentration plays an important role in the formation of corrosion-resistant coating layer, probably due to tile formation of dense coating layer.

Effect of 11-Mercaptoundecylphosphoric-acid Layer Formation on Gold Surfaces Interacting with Titanium Dioxide Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2861-2866
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    • 2010
  • We studied effects of the 11-Mercaptoundecylphosphoric-acid layer formation on gold surfaces that have the interactions with the titanium dioxide surface for design of gold- titanium dioxide distribution. The atomic force microscope (AFM) was used to measure forces between the surfaces as a function of the salt concentration and pH value. The forces were analyzed with the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory, to evaluate the potential and charge density of the surfaces quantitatively for each salt concentration and each pH value. The interpretation for the evaluation was performed with the law of mass action and the ionizable groups on the surface.

Monitoring for the Fermentation Conditions of Sweet Persimmon Vinegar using Response Surface Methodology (반응표면분석에 의한 단감식초 제조조건의 모니터링)

  • 정용진;서권일;이기동;윤광섭;강미정;김광수
    • Journal of the East Asian Society of Dietary Life
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    • v.8 no.1
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    • pp.57-65
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    • 1998
  • To utilize deteriorated sweet persimmon effectively, response surface methodology(RSM) was used to determine the optimal vinegar fermentation conditions and monitored by a divided two stage fermentation. The optimum conditions for maximum alcohol content were obtained when the first stage (alcohol fermentation) was carried out with an initial sugar concentration of 18.5$^{\circ}$Brix, agitation rate of 140.8 rpm, fermentation time of 127.6 hr. When sugar concentration was 14$^{\circ}$Brix maximum alcohol content(7.1%) was predicted at fermentation conditions of 160 rpm in agitation rate, 140hr in fermentation time. The optimum conditions for maximum acidity were obtaiend when second stage(vinegar fermentation)was carried out 249.5 rpm in agitation rate, 148.8 hr in fermentation time. Predicted values at the optimum conditions were similar to experimental values.

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Production of Tetrodotoxin Using Novel Marine Microorganism Isolated from Intestine of Pufferfish (복어 장내에서 분리한 신규 해양 미생물을 이용한 Tetrodotoxin 생산)

  • 윤성준;송성광;이명자;정동윤;김희숙;김동수;이은열
    • Journal of Life Science
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    • v.10 no.2
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    • pp.196-201
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    • 2000
  • The production of tetrodotoxin (TTX) using Vibrio sp. YE-101, a novel marine microorganism isolated from the intestine of pufferfish, was investigated. Culture condition was optimized for the enhanced production of TTX using response surface methodology. The experimental sets of environmental conditions including pH, temperature and NaCl concentration were designed using central composite experimental design. The optimal conditions of pH, temperature and NaCl concentration were determined to be 8.1, 29.2℃, and 2.6% (w/v) respectively. The relative growth extent could be enhanced up to 80%, and final mouse unit (MU) value of TTX was also enhanced up to 87% by response surface optimization.

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The Effects of Polyphosphate Corrosion Inhibitor and Lime Water to Reduce Red Water for Carbon Steel (탄소강의 녹물저감에 대한 인산염부식억제제와 석회수 효과 연구)

  • Park, Young-Bog;Kong, Sung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.228-237
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    • 2005
  • The main purpose of this study was to investigate the red water reducing effects of phosphate based inhibitor when it was applied to water distribution system. The effects of pH, alkalinity, calcium concentration in the reduction of the red water also studied. The most finished water in Korea showed relatively high corrosiveness and was required to introduce some types of corrosion reducing methods such as addition of alkalinity. The precipitation of $CaCO_3$ by addition of $Ca(OH)_2$ formed porous film on the surface of the carbon steel pipes and was displaced easily from the surface of the pipes; on the other hand, addition of zinc phosphate (ZOP) formed reliable film on the surface and reduced iron release and color. Although the main function of ZOP was to suppress the release of Pb and Cu, it also reduced iron concentration released from water distribution pipes.