• Title/Summary/Keyword: Surface characteristic

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Crystalline structure and electrical properties of PbSe thin films prepared using PLD method (PLD 법으로 제작한 PbSe 박막의 결정구조와 전기적 특성)

  • Park, Jong-Man;Lee, Hea-Yeon;Jeong, Jung-Hyun
    • Journal of Sensor Science and Technology
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    • v.8 no.6
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    • pp.476-480
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    • 1999
  • PbSe thin films were grown using PLD method on the p-Si(100) substrate. To determine what crystalline structure of PbSe thin films have according to the growth temperature, the films were prepared under a substrate temperature changing between a room temperature and $400^{\circ}C$. As a result of analyzing XRD patterns of PbSe thin films prepared at various substrate temperatures and FWHM of PbSe(200) rocking curve, it was found that PbSe thin film obtained at the growth temperature of $200^{\circ}C$ was best crystallized. In addition, the surface morphology of PbSe thin film observed using AFM found itself having the most regularly arranged particles in case of growing the film at $200^{\circ}C$. The measurement of Hall effect indicated that PbSe thin films were n-type semiconductors and that current-voltage characteristic curve exhibit the typical p-n junction phenomenon. In addition, electric conductivity of PbSe thin films was found somewhat higher than that of general semiconductors.

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Removal Characteristic of Acidic Ion in Aqueous Solution by Alumina (알루미나에 의한 수용액 중의 산성이온 제거 특성)

  • Hong, Young-Ho
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.454-458
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    • 2007
  • The removal characteristics of ionic species, such as $Ca^{2+}$, $Mg^{2+}$, $Sr^{2+}$, $SO{_4}^{2-}$, $NO{_3}^-$, and $Cl^-$ by adsorption on the alumina were investigated. Alumina precusor powders were prepared from $Al(NO_3)_3{\cdot}9H_2O$ and $NH_4OH$. Alumina materials prepared from the heat treatment in a furnace at $450{\sim}750^{\circ}C$ for 5 h were analysed using FT-IR and the Brunauer-Emmett-Teller (BET) method. The specific surface area of the product particles decreased significantly with treatment temperature. The adsorption capacities of $SO{_4}^{2-}$and $NO{_3}^-$ on alumina were 23 mg/g and 12.4 mg/g, respectively. But, removal efficiencies of $Cl^-$ were less than 4 mg/g. In general, the removal efficiencies of the anion species were decreased with increasing treatment temperature. The best anion removal efficiency was obtained when the alumina was treated under $450^{\circ}C$. Removal efficiencies of $Ca^{2+}$, $Mg^{2+}$, and $Sr^{2+}$ were increased with increasing treatment temperature.

Studies on the Synthesis and Characteristic of Silica-PMMA Nano Hybrid Material (실리카-PMMA 나노 하이브리드 코팅액 제조 및 특성에 관한 연구)

  • Son, Dae Hee;Kim, Dae-Sung;Lee, Seung-Ho;Kim, Song Hyuk;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.53-58
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    • 2012
  • In order to improve the surface hardness of transparent plastic films, an organic-inorganic hybrid coating solution was sunthesized by the sol-gel method. Coating solutions that were prepared colloidal silica (CS), poly methyl methacrylate (PMMA), vinyltrimethoxysilane (VTMS), and [3-(methacryloyloxy)]propyltrimethoxy silane (MAPTMS) was varied with synthesizing parameters such as kinds of organic silane and weight ratio of CS to PMMA. Such coating solution was bar coated on the PET film, cured, and investigated on the chemical and physical properties of coating film. The organic-inorganic hybrid coating solutions have better properties at the pencil hardness and adhesion of coating film than those of an organic material such as PMMA.

Study on the Accuracy Improvement for Survey of Estuary Riverbed (하구하상 측량 정밀도 향상에 관한 연구)

  • 박운용;김천영;김용보
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.21 no.2
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    • pp.137-145
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    • 2003
  • Currently, the availability of 3-D topographical survey by combination of GPS and Echo Sounder has been increased in the various field like as the construction of structure, the dredging and the reclamation in the ocean and river, and observation of topographic change in seabed or riverbed. In this case, the error of depth sounding can divide in form that is happened by combination of GPS and Echo Sounder, and form that is happened in Echo Sounder itself, In this study, in the case happen by Echo Sounder itself, analyzed error by specially about geological features of the seabed and riverbed that is specular surface of sound wave and wished to present solution way. The sounding error about the echo sounder and characteristic of estuary riverbed was found by understanding the relation of average diameter and residual error and we defined correction formula, Y=-0.00474$^{*}$In(X) -0.0045 by the regression analysis. and then we verified applicability of correction formula. As the result, if measure Preliminary investigation or pre-survey the geological features for the survey area at topographical survey of estuary riverbed, we presented the error correction formula that estimate and can correct of error by Echo Sounderer.

Study on the characteristics and biodegradable of synthetic PLGA membrane from lactic acid and glycolic acid (젖산 및 글리콜산에서 합성된 PLGA 멤브레인의 특성과 생분해성에 관한 연구)

  • Xie, Yuying;Park, Jong-Soon;Kang, Soon-Kook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2958-2965
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    • 2015
  • The PLGA(Poly lactide-co-glycolide) Copolymer have been actively applied to the medical implant material as biomaterials. PLGA membrane was able to alveoloplasty with osteotomy for favorable degradation characteristics and possibilities for sustained drug delivery. In this study, PLGA membrane was prepared using phase inversion method, and examined to optical method analysis(NMR, IR), mechanical property measurement (tearing strength) and thermal characteristic analysis(DSC). In addition, the biodegradation characteristics of the PLGA membrane filled with a PBS(Phosphate Buffered Solution) of the water bath ($60^{\circ}C$) according to the degree of surface degradation in the degradation time, the pH change of the solution and change of the mass of the membrane were measured.

The estimation of friction coefficient by using entropy theory in open channels (엔트로피 이론에 의한 개수로 마찰계수 산정)

  • Choo, Tai Ho;Kwak, Kil Sin;Yun, Gwan Seon;Yoon, Hyeon Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2868-2875
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    • 2015
  • Both the friction velocity and the friction coefficient have to be estimated to determine flow characteristic in an open channel. In spite of the importances in an open channel, the complete interpretation is highly difficult because of free water surface, the complex of cross section and the various hydraulic parameters. The researches related to the friction factor are based on empirical outcome. Therefore, the equations are difficult to be generally applied. For that reason, the new friction factor estimation equation using the entropy concept was proposed in the present study, and the data measured in rectangular and trapezoid cross sections was used to verify the accuracy of equation. The advantage of the proposed equation dose not use the energy slope term which is difficult to be measured and to be estimated in an open channel. In addition, the proposed method showed that the accurate friction factor f can be estimated on the Basis of theoretical background.

A Study on the Comfort, Physiological Responses and Microclimate in Beding Pad (온돌에서의 욕의 쾌적성에 관한 연구)

  • Lee Soon Won;Kweon Soo Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.1 s.33
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    • pp.44-54
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    • 1990
  • The purpose of this study was to investigate the effects of thickness of the sleeping pad on the physiological responses and the microclimate in the heating ondol room during sleeping time. The measuring points were skin temp., weight loss and body movement as physiological responses and the compression ratio, the temp. on/under the sleeping pad, the inside limp. of the sleeping quilts and subjective sence while 7 hours sleeping. Thickness of sleeping pads was 27.2 mm(A), 34.8 mm (B), 47.9 mm(C) used for 90 days and no used pad 60.7 mm(D). The floor surface temp. was keeping $29{\pm}1^{\circ}C$ while the environmental conditions was at $23{\pm}1^{\circ}C$ ($50{\pm}5\%$ R.H.) The results were as followings; 1) The mean compression ratio after using the sleeping pads for 45 days was about $70\%$ , and it wasn't increased any more thereafter 2) After 2 hours sleeping the temp. under the sleeping pads was shown that C and D were higher than A and B, and the temp. on the sleeping pads was shown that A and C pads were higher than B and D. But after 3-4 hours sleeping the skin temp. of legs was shown that B and D pads were higher than A and C. 3) Weight loss for C pad was significantly higher than others. Body movement and side position in tying was higher in A and C pads than B and D. 4) The inside temp. of quilt for A and C pads were higher in the early part of sleeping period than those of B and C pads and relative humidity was lower in C than others. 5) D pad was softer than others and fatigue degree was turned out to be lowest in D, the highest in A. From this point of view, we concluded that thickness of the sleeping Pad in the heating ondol room had different characteristic from that in no heating ondol room. And 35 mm used pad was turned out to be proper.

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A Study on the Genesis of Eonyang Amethyst Deposits (언양(彦陽) 자수정 광상(鑛床)의 성인(成因)에 관한 연구(硏究))

  • Youn, Seok-Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.335-343
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    • 1994
  • The Eonyang amethyst deposits are composed of vug quartz emplaced in the Eonyang granites of Mesozoic Cretaceous age. The Eonyang granites are composed of biotite granite, porphyritic biotite granite, aplite and miarolitic granite. The petrochemical data of the Eonyang granites show the trend of subalkaline magma, calc-alkaline magma, I-type granitoid and magnetite series. The vug quartz show the characteristic growth zoning (white quartz-smoky quartz-amethyst) from wall side. Generally fluid inclusions in the vug quartz can be divided into four main types based on compositions (I-type: gas inclusion, II-type: liquid inclusion, III-type: polyphase inclusion, IV-type: liquid $CO_2$-bearing inclusion). Solid phase of polyphase inclusions are halite(NaCl), sylvite(KCl), hematite ($Fe_2O_3$) and unknown anisotropic solid. Homogenization temperatures inferred from the fluid inclusion study ranges from $440^{\circ}C$ to $485^{\circ}C$ in white quartz, from $227^{\circ}C$ to $384^{\circ}C$ in smoky quartz, from $133^{\circ}C$ to $186^{\circ}C$ in amethyst, respectively. Salinities of fluid inclusions in each mineralization stages ranges from 40 wt.% to 58 wt.% in white and smoky quartz, from 1.0 wt.% to 8.7 wt.% in amethyst respectively. A consideration of the pressure regime during vug quartz deposition based on the boiling evidence suggests lithostatic pressure of less than 72 bars. This range of pressure indicate that vug quartz lay at depth of 750 m below the surface at the during mineralization.

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Contribution of Geophysics to the Study of Barite Mineralization in the Paleozoic Formations of Asdaf Tinejdad (Eastern Anti Atlas Morocco)

  • Ibrahim, Dakir;Ahmed, Benamara;Habiba, Aassoumi;Abdessalam, Ouallali;Youssef, Ait Bahammou
    • Economic and Environmental Geology
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    • v.53 no.3
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    • pp.259-269
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    • 2020
  • The use of the geophysical method in mining prospecting has been studied in the Asdaf region (South-East of Morocco). The objective of the study is to examine the aptitude of the electrical technique, in this case induced polarization (IP) and electric tomography, combined with the electromagnetic method (VLF), in the exploration of barite . The result obtained by the pseudo-sections of electrical tomography and that of KH filtration highlighted anomalies of resistant contact (greater than 400Ω.m) and of high charge chargeability (5mV / V). These contacts are hosted in less resistant Devonian age shale and sandstone. The resistivity response obtained at their level is characteristic of the venous structures associated with barite mineralization. The direction of the mineralized veins is parallel to the direction of the fractured zones (NE-SW), which indicates that the mineralization in place is due to the tectonic movements of the Hercynian orogeny (from Devonian to Permian). These veins are aligned with the locations of abandoned mine shafts and with surface mining areas. Geophysical technique therefore seems to play a key role in barite mining exploration.

A Study on the Reaction Characteristics of the NH3 Oxidation over W/TiO2 (W/TiO2 촉매의 NH3 단독 산화 반응 특성 연구)

  • Kim, Geo Jong;Lee, Sang Moon;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.645-649
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    • 2013
  • In this study, we investigated the $NH_3$ oxidation reaction characteristic over $W/TiO_2$ catalyst in order to control $NH_3$ generated from a thermoelectric power plant or incinerator. As a result, it was found that the optimal content of tungsten in $W/TiO_2$ catalyst is 10 wt% and $NH_3$ removal efficiency decreased due to decreasing specific surface areas of catalyst with increasing tungsten contents. When $NH_3$ was injected more than 420 ppm, $NH_3$ conversion decreased at the middle temperature range. In addition, $NH_3$ conversion decreased due to the competitive adsorption of moisture and with increasing oxygen concentration, the $NH_3$ conversion increased while the $N_2$ selectivity decreased.