• Title/Summary/Keyword: Surface characteristic

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Microstructure Control of Porous Ceramics by Freeze-Drying of Aqueous Slurry (동결건조공정을 이용한 다공성 세라믹스의 미세구조 제어)

  • 황해진;문지웅
    • Journal of the Korean Ceramic Society
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    • v.41 no.3
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    • pp.229-234
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    • 2004
  • In this study, we proposed new forming process for a porous ceramic body with unique pore structure. h tubular-type porous NiO-YSZ body with radially aligned pore channels was prepared by freeze-drying of aqueous slurry. A NiO-YSZ slurry was poured into the mold, which was designed to control the crystallization direction of the ice, followed by freezing. Thereafter the ice was sublimated at a reduced pressure. SEM observations revealed that the NiO-YSZ porous body showed aligned large pore channels parallel to the ice growth direction, and fine pores are formed around the outer surface of the tube. It was considered that the difference in the ice growth rate during the freezing process resulted in such a characteristic microstructure. Bilayer consisting of dense thin electrolyte film of YSZ onto the tubular type porous body has been successfully fabricated using a slurry-coating process followed by co-firing. It was regarded that the obtained bilayer structure is suitable for constructing electrode-support type electrochemical devices such as solid oxide fuel cells.

Growth and Characteristics of YIG, Bi:YIG, TbBi:YIG Single Crystal Thick Films (YIG, Bi:YIG, TbBi:YIG 단결정 후막의 성장과 특성)

  • 윤석규;김근영;김명진;이형만;김회경;윤대호
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.672-676
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    • 2003
  • The single crystalline thick films of Y$_3$Fe$\sub$5/O$\sub$12/(YIG), Y$_3$Fe$\sub$5/O$\sub$12/(Bi:YIG), (TbBi)$_3$(FeAlGa)$\sub$5/O$\sub$12/ (TbBi:YIG) were grown on (GdCa)$_3$(GaMgZr)$\sub$5/O$\sub$12/ (SGGG) by Liquid Phase Epitaxy (LPE). The change of lattice mismatch, Bi concentration, characteristic of magnetic and surface morphology were investigated in the thick film growth as a function of species and amount of chemical element, while substrate rotation speed, supercooling and growth time were kept constant. It was observed that the lattice constant of garnet single crystalline thick films of TbBi:YIG (12.500 ${\AA}$) is closed to the one of the substrate (12.496 ${\AA}$). Besides magnetic field of saturation exhibits excellent results (150 Oe).

The Characteristic of Agglomerate and Sintering of Y-PSZ Powders Prepared by Different Processes (제조방법에 따른 Y-PSZ 분말의 응집 및 소결특성)

  • Lee, Jong-Kook;Kim, Hwan;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.9-16
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    • 1985
  • Agglomeration of Y-PSZ and its related properties were studied. The ultrafine $ZrO_2$ powder containg 3 mol% $Y_2O_3$ was prepared by 1) coprecipitation method b) hot petroleum drying method c) sol-gel method and the characteristics of calcined powders and the microstructures of sintered body were observed. Powder prepared by the coprecipitation method was about 125$\AA$ in crystallite size and 0.1~1.0${\mu}{\textrm}{m}$ of intra-agglomerate pore size when calcined at $600^{\circ}C$ for 1 hour. because of small crystallite size and weak agglo merate strength resultant densification of sintered body was high. But above the temperature of 130$0^{\circ}C$ efflorescent phenomena due to anions attached to powder surface was observed. Powder prepared by hot petroleum drying method was 65$\AA$ in crystallite size and 1~10${\mu}{\textrm}{m}$ of intraagglome-rate pore size and it was observed that the agglemerates were formed during the calcining process. In this case despite of small crystallite size the rate of sintering was slow and the existing lenticular interagglomerate pore was not eliminated to the final stage of sintering. Powder prepared by sol-gel method showed solid agglomertes due to rapi dhydrolysis reaction. In this powder which involves strong solid agglomerates overall sintering rate was determined by the sintering between the agglomerates and therefore sinterability of powders made by sol-gel method was very poor.

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Influence of Rainfall-induced Wetting on Unsaturated Weathered Slopes (강우시 국내 불포화 풍화토 사면에서의 습윤영향 분석)

  • Jeong Sang-Seom;Kim Jae-Hong;Park Seong-Wan
    • Journal of the Korean Geotechnical Society
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    • v.20 no.7
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    • pp.159-169
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    • 2004
  • Surface failures of slopes in weathered soil are caused by infiltration due to prolonged rainfall. These failures are mainly triggered by the deepening of the wetting band accompanied by a decrease in suction induced by the infiltrating water. This paper reports trends of rainfall-induced wetting band depth in two types of weathered soils that are commonly found in Korea. Both theoretical and numerical analyses are presented based on the soil-water characteristic curve (SWCC) obtained using filter paper as well as tensiometer tests. It is found that the magnitude of wetting front suction plays a key role in the stability of slopes in weathered soils. Theoretical analysis based on modified Green and Ampt model tends to underestimate the wetting band depth for typical Korean weathered soils. It was also deduced that for Korean weathered soils, the factor of safety drops rapidly once the wetting band depth of 1.2 m is reached.

The Investigation on Thermal Aging Characteristics of Oil-Paper Insulation in Bushing

  • Liao, Rui-jin;Hu, En-de;Yang, Li-jun;Xu, Zuo-ming
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1114-1123
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    • 2015
  • Bushing is the key link to connect outer and inner insulating systems and also the essential electric accessory in electric power system, especially in the high voltage engineering (AC 1000kV, DC 800kV). This paper presented the experimental research of thermal aging characteristic of oil-paper insulation used in bushing. A thermally accelerated aging experiment at 90℃ was performed. The bushing models containing five layers of paper were sealed into the aging vessels and further aged for 250 days. Then several important parameters associated with the aging were observed and evaluated. The results showed that the degree of polymerization (DP) of papers gradually decreased. The DP values of outermost layer and middle layer fit well into the second-order kinematic model and first-order kinematic model, respectively. Less deterioration speed of the inter-layer paper than outer layer was confirmed by the variation of DP. Hydrolysis was considered as the main cause to this phenomenon. In addition, the logarithm of the furfural concentrations in insulation oil was found to have good linear relationship with DP of papers. Interestingly, when the aging time is about 250 days and DP is 419, the aging process reaches an inflection point at which the DP approaches the leveling off degree of polymerization (LODP) value. Both tanδ and acid number of oils increased, while surface and volume resistivity of papers decreased. The obtained results demonstrated that thermal aging and moisture absorbed in papers brought great influence to the degradation of insulating paper, leading to rapid decrease of DP and increase of the tanδ. Thus, the bushing should be avoided from damp and real-time monitoring to the variation of tanδ and DP values of paper is an effective way to evaluate the insulation status of bushing.

Development of Speed Control System for SPMSM with Direct Torque Control (직접토크 제어에 의한 SPMSM 속도제어시스템 개발)

  • Kim, Dong-Hee;Lim, Tae-Hoon;Baik, Won-Sik;Kim, Min-Huei
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.3
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    • pp.66-74
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    • 2005
  • This paper presents an implementation of digital servo speed control system of SPMSM(Surface-mounted Permanent Magnet Synchronous Motor) for industrial application with Direct Torque Control(DTC) using TMS320F2812 DSP. Although, the vector control scheme is adapted in many industrial servo system, but the DSP calculation ratio is increased by reference frame transformation and SVPWM of vector control. Therefore, this paper investigate the possibility of DTC scheme for industrial servo drive system instead of vector control scheme. DSP calculation ratio is compared between vector control and DTC algorithm in addition to the characteristic of speed control response. The suggested SPMSM control system shows the possibility of DTC scheme for industrial servo motor drive system instead of a vector control algorithm.

Characteristics of Structure Settlement due to Urban Railway Construction on Reclaimed Land (해안매립지반의 도시철도 시공에 따른 구조물 침하 특성 분석)

  • Shin, Eun-Chul;Rim, Yong-Kwan;Park, Jeong-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.1
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    • pp.23-33
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    • 2012
  • The stability of urban railway foundation can be a problem due to the excessive settlement. The settlement at the base of railway is monitored by the installed settlement gauges. The piezometer and pore water pressure measurement device are installed to measure the variation of pore water pressure and ground water table during the continuous pullout of sheet piles which were used for the braced cut. The settlement of railway is predicted with using the computer program CAIN RDA. The input data for the numerical analysis are obtained from the field soil exploration data and soil properties. The surcharged load from landscaping over the ground surface and the weight of train are taken into account for the estimation of settlement. As a result of numerical analysis, the range of settlement for six different Sites is from 5.94 cm to 12.77 cm. Thus, the settlement level at Site 2 is occurred 12.77 cm which is higher than the allowable settlement of 10 cm.

Mycological Findings of Trichophyton tonsurans Isolated in New Orleans Area (Trichophyton tonsurans의 진균학적 소견)

  • Kim, Ki-Hong
    • Journal of Yeungnam Medical Science
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    • v.8 no.2
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    • pp.45-51
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    • 1991
  • There had been no reports of Trichophyton tonsurans infection in Korea yet. We have much chances to import the organism through international travels and exchanges. But we, Korean, have no experiences to observe T. tonsurans. Author tried mycological studies with T. tonsurans isolated in New Orleans, USA. The results are as follows : Gross findings of T. tonsurans showed that fine granular surface with light yellow hue or white color and groving in the central area on the front side and mahogany brown color on the reverse side. On the urease test, various reddish discoloration was noted. Microscopic findings showed that septated hyphae, macroconidia, chlamydoconidia and microcondia. Macroconidia were 3-5 septated, smooth-surfaced, and were found more frequently in the whitish colony. Microconidia were characteristic in their arrangement and shape ; round or oval shaped microconidia laterally to hyphae, some were match-head like terminal swelling. Hair perforation test showed positive results in 16 strains among 19 tested strains. All these findings are similar to T. rubrum and T. menatgrophytes, the most frequent isolates of dermatophytes in Korea. And we have to pay an attention to diffentiate carefully.

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Development of Observational Environment Evaluation Model for Sunshine Duration at ASOSs Located in Urban Areas (도시지역 유인관측소 일조 관측환경 평가 모델 개발)

  • Kim, Do-Yong;Kim, Do-Hyoung;Kim, Jae-Jin
    • Atmosphere
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    • v.23 no.3
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    • pp.275-282
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    • 2013
  • In this study, the numerical model was developed to evaluate the observational environment of sunshine duration and, for evaluating the accuracy and utility of the model, it was verified against the observational data measured at Dae-gu Automated Synoptic Observing System (ASOS) located in an urban area. Three-dimensional topography and building configuration as the surface input data of the model were constructed using a Geographic Information System (GIS) data. First, the accuracy of the computing planetary positions suggested by Paul Schlyter was verified against the data provided by Korea Astronomy and Space Science Institute (KASI) and the results showed that the numerical model predicted the Sun's position (the solar azimuth and altitude angles) quite precisely. Then, this model was applied to reproduce the sunshine duration at the Dae-gu ASOS. The observed and calculated sunshine durations were similar to each other. However, the observed and calculated sunrise (sunset) times were delayed (curtailed), compared to those provided by KASI that considered just the ASOS's position information such as latitude, longitude, and elevation height but did not consider the building and topography information. Further investigation showed that this was caused by not only the topographic characteristic (higher in the east and lower in the west) but also the buildings located in the southeast near the sunrise and the southwest near the sunset. It was found that higher building resolution increased the accuracy of the model. It was concluded that, for the accurate evaluation of the sunshine duration, detailed building and topography information around the observing sites was required and the numerical model developed in this study was successful to predict and/or the sunshine duration of the ASOS located in an urban area.

Variations of Trace Gases Concentrations and Their Relationship with the Air Mass Characteristic at Gosan, Korea (제주도 고산에서의 미량기체 농도변화와 공기괴 특성과의 관계)

  • Kim, In-Ae;Li, Shan-Lan;Kim, Kyung-Ryul
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.584-593
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    • 2008
  • The surface $O_3,\;CO,\;NO_x,\;and\;SO_2$ were measured at Gosan in Jeju Island from May 2004 to April 2005. Over this period, the mean concentrations $({\pm}s.d.)$ of each gas was 40.06 $({\pm}16.01)$ ppbv for $O_3,\;264.92({\pm}115.73)ppbv\;for\;CO,\;1.98({\pm}2.73)ppbv\;for\;SO)_2,\;and\;4.64 ({\pm}3.24) ppbv\;for\;NO_x$. The monthly variations and the diurnal variations of these gases show that the Gosan site is situated in a relatively clean region. However, there were episodic simultaneous peaks in CO and $SO_2$, especially in winter and early spring. Using cluster analysis with air mass back- ward trajectory analysis, we suggest that these episodes are due to the influence of transportation of polluted air mass from polluted regions. In the cluster, which was under the dominant influence of clean maritime air mass, low levels of $O_3,\;CO,\;and\;SO_2$ were observed. The levels of these species were elevated in the other two clusters which had the air mass influenced by polluted continental regions. In addition, ratios of the chemical species such as $CO/NO_x,\;SO_2/NO_x,\;and\;CO/SO_2$ revealed the somewhat different characteristics of emission sources influencing each cluster. The differences in concentration of trace gases among clusters with different origin and transport pathways imply that Gosan is under the effect of pollution transported from other regions.