• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1182-1190
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• 2014

$Cd_{1-x}Zn_xS$-sensitized $K_4Nb_6O_{17}$ composite photocatalysts (designated $Cd_{1-x}Zn_xS/K_4Nb_6O_{17}$) were prepared via a simple deposition-precipitation method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), $N_2$ sorption, ultraviolet-visible light diffuse reflectance spectroscopy (UV-Vis DRS), photoluminescence measurements (PL), and X-ray photoelectron spectroscopy (XPS). The $Cd_{0.8}Zn_{0.2}S$ particles were scattered on the surface of $K_4Nb_6O_{17}$, and had a relatively uniform size distribution around 50 nm. The absorption edge of $K_4Nb_6O_{17}$ was shifted to the visible light region and the recombination of photo-generated electrons and holes suppressed after $Cd_{0.8}Zn_{0.2}S$ loading. The $Cd_{0.8}Zn_{0.2}S$(25 wt %)/$K_4Nb_6O_{17}$ composite possessed the highest photocatalytic activity for hydrogen production under visible light irradiation, evolving 8.278 mmol/g in 3 h. Recyclability tests were performed, and the composite photocatalysts were found to be fairly stable. The mechanism of charge separation between the photogenerated electrons and holes at the $Cd_{0.8}Zn_{0.2}S/K_4Nb_6O_{17}$ composite was discussed.

• Restorative Dentistry and Endodontics
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• v.43 no.2
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• pp.26.1-26.12
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• 2018

Objective: The purpose of this study was to investigate the degree of conversion (DC) and mechanical properties of a microhybrid Filtek Z250 (3M ESPE) resin composite after aging. Method: The specimens were fabricated using circular molds to investigate Vickers microhardness (Vickers hardness number [VHN]) and DC, and were prepared according to ISO 4049 for flexural strength testing. The initial DC (%) of discs was recorded using attenuated total reflectance-Fourier transforming infrared spectroscopy. The initial VHN of the specimens was measured using a microhardness tester under a load of 300 g for 15 seconds and the flexural strength test was carried out with a universal testing machine (crosshead speed, 0.5 mm/min). The specimens were then subjected to thermocycling in $5^{\circ}C$ and $55^{\circ}C$ water baths. Properties were assessed after 1,000-10,000 cycles of thermocycling. The surfaces were evaluated using scanning electron microscopy (SEM). Data were analyzed using 1-way analysis of variance followed by the Tukey honest significant difference post hoc test. Results: Statistical analysis showed that DC tended to increase up to 4,000 cycles, with no significant changes. VHN and flexural strength values significantly decreased upon thermal cycling when compared to baseline (p < 0.05). However, there was no significant difference between initial and post-thermocycling VHN results at 1,000 cycles. SEM images after aging showed deteriorative changes in the resin composite surfaces. Conclusions: The Z250 microhybrid resin composite showed reduced surface microhardness and flexural strength and increased DC after thermocycling.

• Journal of Sensor Science and Technology
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• v.24 no.6
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• pp.385-391
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• 2015

In this paper, we propose a new method to infiltrate $Fe_3O_4$-nanoparticles into a porous silicon film and a monitoring technique to detect packing density of nanoparticles within the film. Recently, research to use porous silicon as a drug carrier or a new functional sensor material by infiltrating $Fe_3O_4$-nanoparticles has been extensively performed. However, it is still necessary to enhance the packing density and to develop a monitoring technique to detect the packing density in real time. In this light, we forcibly injected a nanoparticle solution into a rugate-structured free-standing porous silicon (FPS) film by applying a pressure difference between the two sides of the film. We found that the packing density by the pressure-infiltration method proposed in this paper is enhanced, relative to that by the previous diffusion method. Moreover, a continuous shift in wavelength of the rugate reflectance peak measured from the film surface was observed while the nanoparticle solution was being injected. By exploiting this phenomenon, we could qualitatively monitor the packing density of $Fe_3O_4$-nanoparticles within the FPS film with the injection volume of the nanoparticle solution.

• Environmental Engineering Research
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• v.17 no.4
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• pp.179-184
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• 2012

The light absorbance of photocatalysts and reaction kinetics of environmental pollutants at the liquid-solid and gas-solid interfaces differ from each other. Nevertheless, many previous photocatalytic studies have applied the science to aqueopus applications without due consideration of the environment. As such, this work reports the surface and morphological characteristics and photocatalytic activities of carbon-embedded (C-$TiO_2$) photocatalysts for control of gas-phase methyl tertiary-butyl ether (MTBE) under a range of different operational conditions. The C-$TiO_2$ photocatalysts were prepared by oxidizing titanium carbide powders at $350^{\circ}C$. The characteristics of the C-$TiO_2$ photocatalysts, along with pure TiC and the reference pure $TiO_2$, were then determined by X-ray diffraction, scanning emission microscope, diffuse reflectance ultraviolet-visible-near infrared (UV-VIS-NIR), and Fourier transform infrared spectroscopy. The C-$TiO_2$ powders showed a clear shift in the absorbance spectrum towards the visible region, which indicated that the C-$TiO_2$ photocatalyst could be activated effectively by visible-light irradiation. The MTBE decomposition efficiency depended on operational parameters, including the air flow rate (AFR), input concentration (IC), and relative humidity (RH). As the AFRs decreased from 1.5 to 0.1 L/min, the average efficiencies for MTBE increased from 11% to 77%. The average decomposition efficiencies for the ICs of 0.1, 0.5, 1.0, and 2.0 ppm were 77%, 77%, 54%, and 38%, respectively. In addition, the decomposition efficiencies for RHs of 20%, 45%, 70%, and 95% were 92%, 76%, 50%, and 32%, respectively. These findings indicate that the prepared photocatalysts could be effectively applied to control airborne MTBE if their operational conditions were optimized.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.727-731
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• 2003

ASTER image has some advantages for classification such as 15 spectral bands and 15m ${\sim}$ 90m spatial resolution. However, in the classification using general remote sensing image, shadow areas are often classified into water area. It is very difficult to divide shadow and water. Because reflectance characteristics of water is similar to characteristics of shadow. Many land cover items are consisted in one pixel which is 15m spatial resolution. Nowadays, very high resolution satellite image (IKONOS, Quick Bird) and Digital Surface Model (DSM) by air borne laser scanner can also be used. In this study, mixed pixel analysis of ASTER image has carried out using IKONOS image and DSM. For mixed pixel analysis, high accurated geometric correction was required. Image matching method was applied for generating GCP datasets. IKONOS image was rectified by affine transform. After that, one pixel in ASTER image should be compared with corresponded 15×15 pixel in IKONOS image. Then, training dataset were generated for mixed pixel analysis using visual interpretation of IKONOS image. Finally, classification will be carried out based on Linear Mixture Model. Shadow extraction might be succeeded by the classification. The extracted shadow area was validated using shadow image which generated from 1m${\sim}$2m spatial resolution DSM. The result showed 17.2% error was occurred in mixed pixel. It might be limitation of ASTER image for shadow extraction because of 8bit quantization data.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.324-327
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• 2005

An electrophoretic display using $TiO_2$ particles is the most promising candidate because it offers various advantages such as ink-on-paper appearance, good contrast ratio, wide viewing angle, image stability in the off-state and extremely low power consumption. The core technology of electrophoretic display is the dispersion controlling of $TiO_2$ nano particles in nonaqueous solution. To prepare an ink for electronic paper using electrophoretic properties of $TiO_2$ nano particles, cyclohexane with low dielectric constant and transparency, polyethylene for producing polymer coating layer which reduces apparent gravity of $TiO_2$, and $TiO_2$ powders were mixed together by planetary-mill. The zeta-potential value of $TiO_2$ particles in cyclohexane was measured about -40mV, but was measured over -110mV by dispersant attached to polyethylene-coated $TiO_2$ surface. Prepared electronic ink was filled in cross patterned micro-wall with $200{\mu}m$ in width and $40{\mu}m$ in height on ITO glass designed by photolithography. The response time of electronic paper evaluated by mobility of $TiO_2$ particle between micro-walls was measured 0.067sec, but the drift velocity from reflectance wave form during reverse from of electronic ink was measured 0.07cm/sec.

• Korean Journal of Remote Sensing
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• v.19 no.6
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• pp.411-419
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• 2003

An area corresponding to the spatial resolution of optical remote sensor imagery often includes more than one pure surface material. In such case, a pixel value represents a mixture of spectral reflectance of several materials within it. This study attempts to apply the spectral mixture analysis on forest and to evaluate the information content of endmember fractions resulted from the spectral unmixing. Landsat-7 ETM+ image obtained over the study area in the Kwangneung Experimental Forest was initially geo-referenced and radiometrically corrected to reduce the atmospheric and topographic attenuations. Linear mixture model was applied to separate each pixel by the fraction of six endmember: deciduous, coniferous, soil, built-up, shadow, and rice/grass. The fractional values of six endmember could be used to separate forest cover in more detailed spatial scale. In addition, the soil fraction can be further used to extract the information related to the canopy closure. We also found that the shadow effect is more distinctive at coniferous stands.

• Journal of Korea Water Resources Association
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• v.52 no.11
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• pp.941-946
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• 2019

A wildfire could significantly alter the local hydrological regime, depending on the area and severity, and thus it is critical to understand its effect and feedback using data and simulation. For the wildfire in Gangwon-do on April 4-5, 2019, South Korea, we retrieved the Normalized-Burned Ratio (NBR) index using remote-sensing data (500-m 8-day MODIS surface reflectance data), and detect the damaged-area based on the difference in the NBR (dNBR) before and after the fire. The damaged area was $29.50km^2$ in total, taking up 1.00-6.19% of five catchments. We then used remote-sensing data (500-m 8-day MODIS evapotranspiration data) and estimated that annual evapotranspiration (AET) would decrease as 0.05-1.56% over the five catchments, as compared to the pre-fire AET (2004-2018). This study highlights the importance of improving our understanding about the impact of wildfire on the local hydrological cycle.

• The Korean Journal of Malacology
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• v.25 no.3
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• pp.203-210
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• 2009

Optical properties and color analysis of nacreous layers were performed using various pearl shells. The cross section and microstructure of the surface in each nacreous layers were observed through a SEM (Scanning Electron Microscope), and the diffraction pattern on SEM images was analyzed using FFT (Fast Fourier Transform). Through these analysises, it was verified that the color and optical characteristics are closely related to the structure of nacreous layers. Incident angle-dependent reflection spectrum was used to examine the phenomena of color differenceas the direction of observation. Quantified values on the color change were obtained by CIE $L^*a^*b^*$ color scale. Using this research, database for the characteristics of natural pearl shells can be established, and the precise analytic method for observation of pearl shells was suggested.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.593-601
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• 2015

The NDVI (Normalized difference vegetation index) is used as indicators of crop growth situation in remote sensing. To measure or validate the NDVI, reliable NDVI sensors have been needed. We tested new fixed-field NDVI sensor, "SRS (Spectral Reflectance Sensor)" developed by Decagon Devices, during Kimchi cabbage growing season at the cultivation area located in Gochang, Gangneung and Taebaek in Korea from 2014 to 2015. The diurnal variation of NDVI measured by SRS (SRS NDVI) showed a slight ${\cap}$-profile shape and was affected by water on the sensor surface. This means that SRS NDVI around noontime is resonable, except rainy day. Comparisons were made between the SRS NDVI and NDVI of used widely mobile sensor (Cropcircle NDVI). The comparisons indicate that SRS NDVI are close to Cropcircle NDVI (R=0.99). SRS NDVI time series displayed change of the plant height and leaf width of Kimchi cabbage. An obvious exponential relationship is found between SRS NDVI and the plant height ($R^2{\geq}0.92$) and leaf width ($R^2{\geq}0.92$) of Kimchi cabbage. Thus, SRS NDVI will be used as indicator of crop growth situation and a very powerful tool for evaluation of remote sensing NDVI estimates and associated corrections.