• Title/Summary/Keyword: Surface Energy

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Surface Modification of F-MgO by High Energy Electron-beam (높은 에너지의 전자빔을 이용한 F-MgO의 표면 개질)

  • Kim, Kwang-Dae;Tai, Wei Sheng;Luo, Yuan;Seo, Hyun Ook;Lee, Byung Cheol;Yang, Ki Ho;Park, Ok Kyung;Kim, Young Dok
    • Journal of Radiation Industry
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    • v.3 no.1
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    • pp.1-5
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    • 2009
  • The variation of MgO surfaces, in which fluorine was contained (F-MgO), by high energy electron-beam (EB) was studied using X-ray photoelectron spectroscopy (XPS). Fluorine on the MgO surface was eliminated by EB treatment with the consequence that the electronic structures of Mg, O and C were varied. Moreover, as a result of oxidation of carbon species on the surface by high dose EB treatment (90 kGy), the concentration of carbonate and carboxyl species on the surface was increased. In this experiment, it was confirmed that the structure of oxidized metal surface can be adjusted by varying conditions of EB treatment (energy and dose). This result implies that EB can be applied for developing new catalysts.

A Study on the Relationship between Surface Condition and Critical Heat Flux in Heat Exchanger (열교환기 표면상태와 CHF의 상관관계에 대한 연구)

  • Kim, Woo-Joong;Kim, Nam-Jin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.16 no.2
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    • pp.1-6
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    • 2020
  • This work experimentally explored the influence of nano-fouling on CHF, flow boiling heat transfer coefficient, contact angle, and surface roughness. In this study, the flow velocity conditions are established at 0.5, 1.0, and 1.5 m/s. Also, the nanoparticles of oxidized MWCNT were deposited on a heat transfer surface for 0, 120, 180, and 240 sec. As the results, it was found that CHF and superheated temperature were increased in case of nano fouling on the heat transfer surface in oxidized MWCNT fluid. Also, the contact angle and surface roughness decreased when flow velocity and nano coating increased.

Effects of Hydrophilic Surface Treatment on SUS Substrates by Using Dielectric Barrier Discharge

  • Joa, Sang-Beom;Kang, In-Je;Yang, Jong-Keun;Lee, Heon-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.458-458
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    • 2012
  • Fuel Cell is used stacking metal or polymer substrate. This hydro property of substrate surface is very important. Usually, surface property is hydrophilic. The surface oxidation of SUS is investigated through plasma treatments with an atmospheric-pressure dielectric barrier discharge (DBD) for increasing hydrophilic property. The plasma process makes an experiment under various operating conditions of the DBD, which operating conditions are treatment time, plasma gas mixture ratio, the plasma source supply frequency. Two kinds of SUS substrate, SUS-304 and SUS 316L, were used. Discharge frequency has a crucial impact on equipment performance and gas treatment. After the plasma treatment of a SUS plate, highly improved wettability was noted. But, when high oxygen supply, the substrate damaged seriously.

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Surface Analysis Techniques for Studying Optical Degradation of Solar Coatings (태양에너지 박막의 광퇴화 연구를 위한 표면분석)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.29 no.2
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    • pp.55-61
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    • 2009
  • This paper reviews the state-of-the art in surface analysis techniques for solar coatings. For analyzing solar coatings and interfaces, surface properties were very important factor for obtaining the information related to the optical degradation processes and microstructure. Various types of analytical techniques for chemical composition, microstructure and surface topography analysis of solar coatings were discussed. In addition, the examples of solar selective coating analysis results for applications were demonstrated. Development and analysis technique of solar coating for energy conservation was felt to be necessary at this time.

Low Energy Ion-Surface Reactor

  • Choi, Won-Yong;Kang, Tae-Hee;Kang, Heon
    • Bulletin of the Korean Chemical Society
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    • v.11 no.4
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    • pp.290-296
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    • 1990
  • Ion-surface collision studies at low kinetic energies (1-100 eV) provide a unique opportunity for investigating reactions and collision dynamics at surfaces. A special ion optics system for generating an energy- and mass-selected ion beam of this energy is designed and constructed. An ultrahigh vacuum (UHV) reaction chamber, in which the ions generated from the beamline collide with a solid surface, is equipped with Auger electron spectroscopy (AES) and thermal desorption spectrometry (TDS) as in-situ surface analytical tools. The resulting beam from the system has the following characteristics : ion current of 5-50 nA, energy spread < 2eV, current stability within ${\pm}5%,$ and unit mass resolution below 20 amu. The performance of the instrument is illustrated with data representing the implantation behavior of $Ar^+$ into a graphite (0001) surface.

Mechanical analysis of cutout piezoelectric nonlocal nanobeam including surface energy effects

  • Eltaher, Mohamed A.;Omar, Fatema-Alzahraa;Abdalla, Waleed S.;Kabeel, Abdallah M.;Alshorbagy, Amal E.
    • Structural Engineering and Mechanics
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    • v.76 no.1
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    • pp.141-151
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    • 2020
  • This manuscript tends to investigate influences of nanoscale and surface energy on a static bending and free vibration of piezoelectric perforated nanobeam structural element, for the first time. Nonlocal differential elasticity theory of Eringen is manipulated to depict the long-range atoms interactions, by imposing length scale parameter. Surface energy dominated in nanoscale structure, is included in the proposed model by using Gurtin-Murdoch model. The coupling effect between nonlocal elasticity and surface energy is included in the proposed model. Constitutive and governing equations of nonlocal-surface perforated Euler-Bernoulli nanobeam are derived by Hamilton's principle. The distribution of electric potential for the piezoelectric nanobeam model is assumed to vary as a combination of a cosine and linear variation, which satisfies the Maxwell's equation. The proposed model is solved numerically by using the finite-element method (FEM). The present model is validated by comparing the obtained results with previously published works. The detailed parametric study is presented to examine effects of the number of holes, perforation size, nonlocal parameter, surface energy, boundary conditions, and external electric voltage on the electro-mechanical behaviors of piezoelectric perforated nanobeams. It is found that the effect of surface stresses becomes more significant as the thickness decreases in the range of nanometers. The effect of number of holes becomes significant in the region 0.2 ≤ α ≤ 0.8. The current model can be used in design of perforated nano-electro-mechanical systems (PNEMS).

On response of Surface Equilibrium Temperature for Change of Surface Characteristics : An EBM Study (지표 특성 변화에 대한 평형온도의 반응 연구 : EBM 연구)

  • Seo, Ye-Won;Chu, Jung-Eun;Ha, Kyung-Ja
    • The Korean Journal of Quaternary Research
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    • v.24 no.2
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    • pp.1-11
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    • 2010
  • Energy Balance Model (EBM) was used to experiment the distribution of surface equilibrium temperature which responds to external forcing associated with the surface characteristics. Surface equilibrium temperature is calculated as sum of incoming solar radiation and latitudinal transport is balanced with outgoing infrared radiation. To treat incoming solar radiation, the source of the earth energy, significantly for energy balance, the experiment for surface equilibrium temperature distribution was performed considering the energy balance with the latitudinal albedo change as well as land and sea distribution. In addition, linear albedo change experiment, arctic albedo 5%, 10%, 15% change experiments and the opposite albedo change experiments between arctic and mid-latitudes were performed using incoming solar radiation as an external forcing. Moreover, with and without ice-albedo feedback experiments were performed. Increasing of arctic albedo is blocked out the incoming solar radiation so that it induces decreasing of latitudinal heat transport. It is strengthened energy transport from low latitudes by keeping arctic low energy states. Therefore the temperature change in the mid-latitudes exhibits larger response than that of arctic due to the difference of transport. The land which has lower heat capacity than sea can be reach to equilibrium temperature shortly. Also land is more sensitive to temperature change with respects to albedo. Thus it induces the thermal difference between land and sea. As a result, the equilibrium temperature exhibits differently as the difference of albedo and heat capacity which are the one of surface characteristics. Surface equilibrium temperature decreases as albedo increase and the ratio of temperature change is large as heat capacity is small. The decreasing of surface equilibrium temperature with respects to increasing of linear albedo is accelerated by ice-albedo feedback. However local change of surface equilibrium temperature decreases non-linearly.

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Performance characterization of liquid desiccant system with extended surface (확장표면을 적용한 액체식 제습시스템의 성능특성에 관한 연구)

  • Jang, Young-Soo;Song, Gwi-Eun;Lee, Dae-Young
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.639-644
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    • 2009
  • This study presents the new idea of liquid desiccant system with extended surface to reduce the system size. The extended surface is inserted between vertical cooling/heating tubes to increase the mass transfer area, and the liquid desiccant flows through the tube wall and the extended surface. Mathematical models for heat and mass transfer between liquid desiccant and air stream at tube wall and extended surface are provided. Dimensionless design parameters governing heat and mass transfer phenomena around the tube and the extended surface are identifier, and dimensionless operating parameters depicting system operating condition including flow rate ratio between dehumidification/regeneration processes, and mass flow rate ratio between air stream and liquid desiccant are explained. The effects of the parameters on system performance are summarized.

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Adhesion and Electrical Performance by Plasma Treatment of Semiconductive Silicone Rubber (반도전성 실리콘 고무의 플라즈마 표면처리에 따른 접착특성과 절연성능)

  • Hwang, Sun-Mook;Lee, Ki-Taek;Hong, Joo-Il;Huh, Chang-Su
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.450-456
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    • 2005
  • In this paper, the effect of adhesion properties of semiconductive-insulating interface layer of silicone rubber on electrical properties was investigated. The modifications produced on the silicone surface by oxygen plasma were accessed using ATR-FTIR, contact angle and Surface Roughness Tester. Adhesion was obtained from T-peel tests of semiconductive layer haying different treatment durations. In addition, ac breakdown test was carried out for elucidating the change of electrical property with duration of plasma treatment. From the results, the treatment in the oxygen plasma produced a noticeable increase in surface energy, which can be mainly ascribed to the creation of O-H and C=O. It is observed that adhesion performance was determined by surface energy and roughness level of silicone surface. It is found that at dielectric strength was increased with improving the adhesion between the semiconductive and insulating interface.

Sur face Modification of Ultra High Molecular Weight Polyethylene Films by UV/ozone Ir radiation

  • Yun, Deuk-Won;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.76-82
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    • 2011
  • Ultra High molecular weight polyethylene(UHMWPE) films were photooxidized by UV/ozone irradiation. Reflectance of the irradiated films decreased in the low wavelength regions of visible light, indicating destructive interference of visible light due to roughened surface. The UV treatment developed the nano-scale roughness on the UHMWPE films surface, which increased by two-fold from 82.6 to 156.6nm in terms of peak-valley roughness. The UV irradiation caused the oxygen content of the UHMWPE film surface to increase. Water contact angle decreased from $83.2^{\circ}$ to $72.9^{\circ}$ and surface energy increased from 37.8 to 42.6mJ/$m^2$ with increasing UV energy. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of UHMWPE films. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the film surfaces.