• 대한기계학회논문집B
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• 제26권10호
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• pp.1370-1377
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• 2002

This study analyzed the design performance of the bottoming system of combined cycle power plants using a once-through heat recovery steam generator. For a parallel arrangement of the main heater and reheater, parametric analyses were carried out to present the criteria for determining the reheater pressure and the location of the starting point of the reheater in the HRSG. The performance of the bottoming system was presented fer a range from high subcritical to supercritical pressure. The steam turbine power is as high as that of conventional triple-pressure bottoming systems. The serial arrangement of heat exchangers with division of each heater into several segments can achieve similar power level.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2011년도 춘계학술논문집 1부
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• pp.489-492
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• 2011

Supercritical fluid technology has been an alternative for purification and separation of biological compounds in cosmetic, food, and pharmaceutical products. Solubility information of biological compounds in supercritical fluids is essential for choosing a supercritical fluid processes. The equilibrium solubility of hinokitiol was measured in supercritical carbon dioxide with a static method in the pressure range from 8 to 40 MPa and at temperatures equal to 313.2, 323.2 and 333.2 K. The experimental data were correlated well by Peng.Robinson equation of state and quasi-chemical nonrandom lattice fluid model.

• Journal of Microbiology and Biotechnology
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• 제19권12호
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• pp.1596-1602
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• 2009

A lipase-catalyzed esterification reaction of (S)-naproxen ethyl ester by CALB (Candida antarctica lipase B) enzyme was performed in supercritical carbon dioxide. Experiments were performed in a high-pressure cell for 10 h at a stirring rate of 150 rpm over a temperature range of 313.15 to 333.15 K and a pressure range of 50 to 175 bar. The productivity of (S)-naproxen ethyl ester was compared with the result in ambient condition. The total reaction time and conversion yields of the catalyzed reaction in supercritical carbon dioxide were compared with those at ambient temperature and pressure. The experimental results show that the conversion and reaction rate were significantly improved at critical condition. The maximum conversion yield was 9.9% (216 h) at ambient condition and 68.9% (3 h) in supercritical state. The effects of varying amounts of enzyme and water were also examined and the optimum condition was found (7 g of enzyme and 2% water content).

• 대한기계학회:학술대회논문집
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• 대한기계학회 2005년도 창립60주년 기념 추계 학술대회
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• pp.3.2-3.2
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• 2005

• Korean Chemical Engineering Research
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• 제47권3호
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• pp.281-286
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• 2009

아임계 및 초임계 조건의 물을 이용하여 캐나다산 Athabasca 오일샌드로부터 역청 추출 및 황 제거 실험을 수행하였다. 0~120 min의 반응시간, 360, $380^{\circ}C$의 온도, 15~30 MPa의 압력 및 $0.074{\sim}0.61g/cm^3$의 물 밀도를 변화시키면서 micro reactor에서 역청 수율을 조사하였다. 역청 수율은 온도에 상관없이 압력이 증가할수록 증가하였으며, 특히 초임계 영역에서 수증기 개질반응에 의해 생성된 수소에 의해 역청의 수율이 급격히 증가하였다. 전체 기상 생성량은 압력 증가에 따라 감소하였으나 $380^{\circ}C$에서 황과 수소의 생성분율은 25 및 30 MPa로 압력 증가에 따라 소량 증가하였다. 이상의 결과는 초임계 조건이 수소의 생성과 황의 제거에 유리하다는 것을 보여준다. 초임계 조건$380^{\circ}C$, 25와 30 MPa)에서 역청 수율은 최대 약 22%였으며, 오일샌드에 함유된 황 제거율도 최대값 40%에 도달하였다.

• 한국분무공학회지
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• 제1권1호
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• pp.35-43
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• 1996

A vaporization model for single component fuel droplet has been developed for applying to sub- and supercritical conditions. This model can account for transient liquid heat ins and circulation effect inside the droplet, forced and natural convection, Stefan flow effect, real gas effect and ambient gas solubility into the liquid droplet in high-pressure conditions. Thermodynamic and transport properties are calculated as functions of temperature and pressure in both phases. Numerical calculations are carried out for several validation cases with the detailed experimental data. Numerical results confirm that this supercritical vaporization model is applicable to the high-pressure conditions encountered in the combustion processes of diesel engine.

• 설비공학논문집
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• 제16권6호
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• pp.538-545
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• 2004

This paper presents the experimental data for the heat transfer and pressure drop characteristics obtained during the gas cooling process of carbon dioxide in a horizontal tube. The tube in which carbon dioxide flows is made of copper with an inner diameter of 7.73 mm. Experiments were conducted for various mass fluxes and inlet pressures of carbon dioxide. Mass fluxes are controlled at 225, 337 and 450 kg/$m^2$s and inlet pressures are adjust-ed from 7.5 to 8.8 ㎫. The experimental results in this study are compared with the existing correlations for the supercritical heat transfer coefficient, which generally under-predict the measured data. Pressure drop data agree very well with those calculated by the Blasius' equation. Based on the experimental data, a new empirical correlation to estimate the near-critical heat transfer coefficients has been developed.

• 한국추진공학회지
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• 제17권3호
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• pp.21-29
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• 2013

초임계조건의 기체수소/액체산소 화염의 난류유동 및 온도장에 대해 난류모델을 이용한 해석이 수행되었다. 실제유체의 연소유동을 해석하기 위하여 화염편모델에 SRK 상태방정식이 도입되었다. 수정된 압력-속도-밀도 연계알고리듬이 초임계유동에 적용되었다. 수정된 알고리듬을 토대로 6개의 대류항 차분법과 4개의 난류모델의 상대적인 성능비교가 이루어졌다. 선택된 난류모델들은 실제유체 연소유동의 다양한 특징을 고려하기 위해서 수정이 필요함을 나타내었다.

• Biotechnology and Bioprocess Engineering:BBE
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• 제7권2호
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• pp.85-88
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• 2002

A study was carried out on the application of supercritical fluid to the hydrolysis of boll fibers of cotton (cultivar Tashkent-6 of Gossypium hirsutum L.) by cellulase enzymes from Trichoderma viride, Trichoderma reesei and Aspergillus niger. Conditions of the enzymatic process were optimized. The stabilities of cellulase enzymes were sustained at the pressure of up to 160 attn for 48 hours at 5$0^{\circ}C$ in supercritical carbon dioxide.

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1429-1432
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• 2006

Polyaromatic hydrocarbons were separated by a capillary supercritical fluid chromatographic (SFC) column and detected by a UV detector at the wavelength of 280 $\mu$m. The temperature-controlled restrictor was designed for UV detection. The temperature-controlled restrictor is a 20 cm length of deactivated fused silica of 7 mm i.d. which is held right after UV detector of the capillary SFC. The temperature of the restrictor will control the flow rate of the supercritical carbon dioxide mobile phase through the capillary column in SFC. Thus as the pressure in the column is increased from 1500 psi to 4000 psi during a pressure program, the temperature of 7 $\mu$m fused-silica tube can be varied from 100 to 350 ${^{\circ}C}$ to maintain a constant flow rate.