• 한국전산구조공학회논문집
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• 제16권4호
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• pp.387-399
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• 2003

현재 국내에서는 벽과 바닥판으로만 이루어진 벽식구조형식이 아파트 건물에 많이 적용되고 있다. 이와 더불어 최근에는 건축 계획적인 필요에 따라서 필로티가 있는 건물이 급격히 늘어나고 있다 이런 건물은 전이보를 기준으로 상부층과 하부층의 구조적 특성의 급격한 변화가 발생하게 된다. 필로티가 있는 벽식건물을 정확하게 해석하기 위해서는 많은 수의 유한요소를 사용하여 구조물을 모형화하는 것이 필요하다. 그러나 구조물 전체를 수많은 요소로 세분하여 해석하는 것은 막대한 해석시간과 기억용량을 필요로 한다. 따라서 본 연구에서는 필로티가 있는 구조물에 효과적으로 적용할 수 있는 해석기법을 제시하고자 한다. 제안된 해석기법은 전이보를 슈퍼요소로 모형화하고, 각 부재 사이의 변형적합조건을 만족시키기 위하여 가상의 보를 사용하였다. 필로티가 있는 여러 가지 유형의 예제 모델을 사용하여 제안된 해석기법의 정확성을 검증하였다.

• 한국지진공학회논문집
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• 제2권2호
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• pp.23-34
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• 1998

본 논문은 바닥판을 고려한 3차원 골조 구조물의 효율적인 연직 진동 해석법을 제안한다. 바닥판의 영향을 고려하면 구조물의 진동해석을 좀더 정확히 수행할 수 있는 반면, 면요소의 사용에 따른 많은 자유도의 사용으로 많은 해석시간과 기억용량이 필요하게 된다. 따라서, 행렬응축기법을 사용하여 적절한 요소분할 및 주자유도 선택 기법을 제안하였으며, 대형요소를 사용하여 정확화된 일반적인 건물의 동적해석에 적용하여 입력 데이터의 작성을 간단히 하고 동적해석을 빠르고 신뢰할 만한 결과를 얻을 수 있는 기법에 대하여 연구하였다.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2001년도 가을 학술발표회 논문집
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• pp.3-10
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• 2001

The box system that is composed only of reinforced concrete walls and slabs are adopted on many high-rise apartment buildings recently constructed in Korea. And the framed structure with shear wall core that can effectively resist horizontal forces is frequently adopted for the structural system for high-rise building structures. In these structures, a shear wall may have one or more openings for functional reasons. It is necessary to use subdivided finite elements for accurate analysis of the shear wall with openings. But it would take tremendous amount of computational time and memory if the entire building structure is subdivided into a finer mesh . An efficient analysis method that can be used regardless of the number, size and location of openings is proposed in this study, The analysis method uses super element, substructure, matrix condensation technique and fictitious beam technique. Three-dimensional analyses of the box system and the framed structure with shear wall core having various types of openings were performed to verify the efficiency of the proposed method. It was confirmed that the proposed method have outstanding accuracy with drastically reduced time and computer memory from the analyses of example structures.

• 한국해양공학회지
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• 제27권2호
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• pp.75-79
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• 2013

This study was carried out to investigate the precipitation behavior of the ${\chi}$ phase and the impact toughness of 25%Cr-7%Ni-2%Mo-4%W super duplex stainless steel. The ${\chi}$ phase was precipitated in the early stage of aging, and with the increasing aging time. However, after reaching a maximum value, the number decreased as a result of the gradual transformation of the ${\chi}$ phase into the ${\sigma}$-phase. It was proved that the ${\chi}$ phase was an intermetallic compound, which represented a lower nickel concentration, higher chromium and molybdenum concentrations, and very higher tungsten concentration compared to the matrix phases. It also showed higher molybdenum and tungsten concentrations than the ${\sigma}$ phase. The decomposition of the ferrite phase into the ${\gamma}_2$ and ${\sigma}$ phases was retarded by W substitution for Mo. Thus, the number of ${\chi}$ phases increased. The impact value was decreased by the substitution of W for Mo. The impact toughness rapidly decreased with time when the ${\chi}$ phase began to precipitate in the initial stage of aging. The impact toughness was, therefore, greatly influenced for the precipitation of the ${\chi}$ phase.

• Corrosion Science and Technology
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• 제19권4호
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• pp.203-210
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• 2020

The corrosion behavior of super austenitic stainless steel was studied by examining the characteristics of the sigma phase formed in the steel. A range of experimental and analytical methods was employed, including potentiodynamic polarization tests, critical pitting temperature tests, transmission electron microscopy, and energy-dispersive spectroscopy. Three steel samples with different sigma phase levels were obtained by intentionally adjusting the manufacturing process. The results showed that the corrosion resistance of the samples was strongly dependent upon the size and distribution of the sigma phase precipitated in the samples. The larger the size of the sigma phase, the higher the Mo content in the sigma phase and the higher the depletion level of Mo at the interface between the matrix/sigma phase, the more samples with a coarse-sized sigma phase were susceptible to localized pitting corrosion at the interface. These results suggest that various manufacturing processes, such as welding and the post-heat treatment of the steel, should be optimized so that both the size and fraction of the sigma phase precipitated in the steel are small to improve the resistance to localized corrosion.

• 한국재료학회지
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• 제20권11호
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• pp.606-610
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• 2010

Films consisting of a silicon quantum dot superlattice were fabricated by alternating deposition of silicon rich silicon nitride and $Si_3N_4$ layers using an rf magnetron co-sputtering system. In order to use the silicon quantum dot super lattice structure for third generation multi junction solar cell applications, it is important to control the dot size. Moreover, silicon quantum dots have to be in a regularly spaced array in the dielectric matrix material for in order to allow for effective carrier transport. In this study, therefore, we fabricated silicon quantum dot superlattice films under various conditions and investigated crystallization behavior of the silicon quantum dot super lattice structure. Fourier transform infrared spectroscopy (FTIR) spectra showed an increased intensity of the $840\;cm^{-1}$ peak with increasing annealing temperature due to the increase in the number of Si-N bonds. A more conspicuous characteristic of this process is the increased intensity of the $1100\;cm^{-1}$ peak. This peak was attributed to annealing induced reordering in the films that led to increased Si-$N_4$ bonding. X-ray photoelectron spectroscopy (XPS) analysis showed that peak position was shifted to higher bonding energy as silicon 2p bonding energy changed. This transition is related to the formation of silicon quantum dots. Transmission electron microscopy (TEM) and electron spin resonance (ESR) analysis also confirmed the formation of silicon quantum dots. This study revealed that post annealing at $1100^{\circ}C$ for at least one hour is necessary to precipitate the silicon quantum dots in the $SiN_x$ matrix.

• 멤브레인
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• 제34권2호
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• pp.154-162
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• 2024

음이온 교환막은 수전해 시스템에서 매우 중요한 역할을 하며, 생성된 수소와 산소 기체를 물리적으로 분리할 뿐만 아니라 전극 사이에서 수산화 이온의 선택적인 전달을 용이하게 한다. 음이온 교환막에 요구되는 특성은 수산화 이온에 대한 높은 전도도와 알칼리 환경에서의 화학적/기계적 안정성 등이 있다. 본 연구에서는 셀룰로오스 나노 크리스탈이 포함된 poly(terphenyl piperidinium) (qPTP/CNC) 복합매질분리막을 제조하였다. 고분자 매질로 사용된 poly(terphenyl piperidinium)은 super-acid 중합법을 통해 제조되었으며 이온전도성과 알칼라인 내구성이 뛰어난 소재로 알려져 있다. qPTP/CNC 분리막의 구조는 고분자와 나노 입자 계면의 공극이나 큰 응집체가 없는 조밀하고 균일한 형태를 나타냈다. CNC 나노 입자가 2wt% 첨가된 qPTP/CNC 분리막은 높은 이온교환용량(1.90 mmol/g)과 낮은 함수율(9.09%) 및 팽윤도(5.56%)를 보였다. 또한, 복합막은 수전해 작동 환경인 50℃ 1 M KOH에서 상용 FAA-3-50 분리막에 비해 월등히 낮은 저항과 우수한 알칼라인 내구성(384시간)을 달성했다. 이러한 결과는 친수성 첨가제인 CNC가 음이온 교환막의 이온 전도 특성과 알칼라인 내구성 향상에 기여할 수 있음을 보고하였다.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1708-1714
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• 2013

Polyhexamethylene guanidine (PHMG) polymers used as an active ingredient in an antibacterial humidifier disinfectant were reported to cause harm to the human health when inhaled, although physical contact with this material was known to present low toxicity to humans. It is therefore necessary to develop an optimal analysis method which enables detection and analysis of PHMG polymers. MALDI-TOF investigations of PHMG are performed with a variety of matrices, and it is found that CHCA and 2,5-DHB are excellent matrices which well reflects the polymer population even at high mass. For the provided PHMG sample, the number-average ($M_n$) and weight-average ($M_w$) molecular masses were determined to be 744.8 and 810.7, respectively, when the CHCA was used as a matrix. The rank of the matrices in terms of averaged molecular weight was CHCA ~2,5-DHB > 5-NSA > DHAP, THAP > ATT > IAA ~ super-DHB ~ HABA. In addition, PSD of the PHMG oligomer ions exhibited a few unique fragmenation characteristics. The formation of a- and c-type fragments was the major fragmentation pathway, and the 25-Da loss peaks generally accompanied a- and c-type fragments.

• 대한기계학회논문집A
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• 제24권5호
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• pp.1254-1260
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• 2000

There have been many developments in super precision working technique and working method up to, now. But, it is very difficult to evaluate working surface accurately without the technicians experience and judgment. Surface roughness tester using stylus was used to measure surface condition generally But this method is not so desirable because of damage on test piece caused by contact between the workpiece and the stylus sensor. As a result, non-contact method was known as a good way to carry, out this process without damage. However, this is a difficult one among the various measuring methods. So we are tying to suggest a new method using texture analysis through image processing to get a surface information in worked test piece. Co-occurrence matrix using difference of gray levels between a pixel and its neighboring one was used to study behavior of surface roughness and to J acquire data for analysis. Standard specimen was adapted to verify this research. We suggest texture information method in order to evaluate surface state for the best measurement system.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.201-204
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• 2004

Immobilization is seen as a promising technology for lead remediation. In a laboratory experiment, immobilization of lead with soluble P was tested as a function of reaction time and P concentration. The P treated with an acidic solution to enhance heavy metal immobilization was worked into the soil, and within 7 days, lead was stabilized. Different molar ratios of soluble phosphates (super-phosphate and KH$_2$PO$_4$) would be considerably effective to accelerate the formation of highly insoluble minerals due to the lack of leachable Pb in the contaminated soil. Although it was demonstrated that the addition of soluble phosphates with an acidic solution significantly reduced available lead in soil up to over 95%, remaining phosphorus in soil matrix might cause a possible groundwater eutrophication in the near future.