• The Journal of Korean Academy of Prosthodontics
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• v.57 no.4
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• pp.335-341
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• 2019

Purpose: Chemically strong-acids (HF and $HCl/H_2SO_4$) dual etching implant surfaces have higher strengths of osseointegration than machined implant surfaces. However, the dual acid treatment deteriorates the physical properties of the titanium by weakening the fatigue resistance of the implant and causing microcracks. The removal torque comparison between the dual-acid etched (hydrochloric acid, sulfuric acid, HS) and single-acid etched implants (hydrochloric acid, H) could reveal the efficiency of implant surface acid treatment. Materials and methods: Nine $3.75{\times}4mm$ dual-acid etched SLA implants and nine single-acid etched SLA implants were inserted into New Zealand rabbit tibias. After 10 days, removal torque, roughness, and wetting angle were measured. Results: Mean removal torque values were as follows: Mean removal torque were 9.94 Ncm for HS group and 9.96 Ncm for H group (P=.995). Mean surface roughness value were $0.93{\mu}m$ for HS group and $0.84{\mu}m$ for H group (P=.170). Root mean square roughness (RSq) values were $1.21{\mu}m$ for HS group and $1.08{\mu}m$ for H group (P=.294), and mean wetting angle values were $99^{\circ}$ for HS group and $98^{\circ}$ for H group (P=.829). Statistical analysis showed no significant difference between the removal torques, roughness, or wetting angles of the two groups. Conclusion: In this experiment, we found no significant difference in removal torque, roughness, or wetting angle between dual-acid etched and single-acid etched implants.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.227-232
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• 2002

To evaluate the practical application of oyster shells as construction materials, an experimental study was performed. More specifically, the long-term mechanical properties and durability of concrete blended with oyster shells were investigated. Test results indicate that long-term strength of concrete blended with 10% oyster shells is almost identical to that of normal concrete. However, the long-term strength of concrete blended with 20% oyster shells Is appreciably lower than that of normal concrete. 1'hereby, concrete with higher oyster shell has the possibility giving a bad influence on the concrete long-term strength. Elastic modulus of concrete blended with crushed oyster shells decreases as the blending mixture ratio increases. Namely, the modulus is reduced by approximately 10∼15% when oyster shells are blended up to 20% replacing the fine aggregate. The drying shrinkage strain increases as the blending ratio increases. In addition, the existing model code of drying shrinkage does not coincide with the test results of this study. An adequate prediction equation needs to be developed. The utilization of oyster shells as the fine aggregate in concrete has an insignificant effect on freezing and thawing resistance, carbonation and sulfuric acid attack of concrete recycling. However, water permeability is considerably improved.

• International Journal of Concrete Structures and Materials
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• v.6 no.3
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• pp.145-153
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• 2012

The aim of this study is to explore the possibility of re-cycling a waste material that is now produced in large quantities, while achieving an improvement of the mechanical properties and durability of the mortar. This study examines the mechanical properties and the durability parameters of mortars incorporating plastics bag wastes (PBW) as fine aggregate by substitution of a variable percentage of sand (10, 20, 30 and 40 %). The influence of the PBW on the, compressive and flexural strength, drying shrinkage, fire resistance, sulfuric acid attack and chloride diffusion coefficient of the different mortars, has been investigated and analyzed in comparison to the control mortar. The results showed that the use of PBW enabled to reduce by 18-23 % the compressive strength of mortars containing 10 and 20 % of waste respectively, which remains always close to the reference mortar (made without waste). The replacement of sand by PBW in mortar slows down the penetration of chloride ions, improves the behavior of mortars in acidic medium and improves the sensitivity to cracking. The results of this investigation consolidate the idea of the use of PBW in the field of construction.

• Journal of the Korean Magnetics Society
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• v.3 no.3
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• pp.221-228
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• 1993

The general requirements of recording media include recording performance, environmental stability, runnability on the drive or deck, and manufacturability. CoCrMo thin films were prepared using RF sputtering system for a study on chemical stability. Surface degradation of the CoCrMo thin film was studied by SEM, XPS and AES. Surface degradation was found to be dependent of sputtering condition and Mo content. Addition of Mo to CoCr thin film improved dramatically its surface degradation resistance in dilute sulfuric acid, as indicated by active-passive transition appeared in electrochemical polarization curve. Futhermore, the passive current density was decreased with increasing Mo content. The reduction in a number density of corrosion sites by Mo addition vms observed, after accelerated corrosion test. AES survey indicated that corrosion occured on the site with Cr depletion and highly concentrated chloride ions.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.305-308
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• 2005

The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and disaggregation of concrete. The purpose of this study is to estimate the antibacterial performance of antibiotics and the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the fundamental properties of restorative mortar spead with antibiotics. Also, testing items such as bonding strength, abrasion contents, contents of water absorption, contents of air permeability was tested to estimate the fundamental properties in this study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And bonding strength of restorative mortar spread with antibiotics was similla to that of plain mortar. But, resistance to abrasion, water absorption and air permeability of restorative mortar spread with antibiotics was superior to that of plain mortar.

• Corrosion Science and Technology
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• v.6 no.2
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• pp.62-67
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• 2007

Several heavy duty coatings at an every kind industry facilities to various systems currently have been applied review to the many industry fields. Corrosion-protective characteristics in the case of novolac epoxy among them and unsaturated polyester have been applied most widely. epoxy and flake heavy duty coatings are applied for such reason in an every kind facilities(stack, FGD, cooler, chemical tank etc) of a fossil-fuel power plants Cases of the fossil-fuel power plants are exposed to more severe corrosion environment compared with other facilities and It is difficult to display the performance of long-term method at apply to be the partial. Our study shows fluoro-polymer composite coating method to overcome of the limit. The comparison did previous method and heavy duty coating about FGD plants most at a corrosion environment among fossil-fuel power plants. Additionally, other facilities examined different heavy duty method. The design mode of fluoro-polymer composite coating according to an every kind facilities show extensive methods that are characteristic revelation of film(top, middle and primer layer) composition of the paint, film thickness in accordance with a facilities corrosion and the corrosion protective effectiveness to come into being use fluoro-polymer composite with heavy duty paint(epoxy).

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3697-3702
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• 2010

We demonstrate that vertically aligned carbon nanotubes can be synthesized directly on tantalum substrate via water-assisted chemical vapor deposition and evaluate their properties as electrochemical capacitors. The mean diameter of the carbon nanotubes was $7.1{\pm}1.5\;nm$, and 70% of them had double walls. The intensity ratio of G-band to D-band in Raman spectra was as high as 5, indicating good quality of the carbon nanotubes. Owing to the alignment and low equivalent series resistance, the carbon nanotube based supercapacitors showed good rate performance. Rectangular shape of cyclic voltammogram was maintained even at the scan rate of > 1 V/s in 1 M sulfuric acid aqueous solution. Specific capacitance was well-retained (~94%) even when the discharging current density dramatically increased up to 145 A/g. Consequently, specific power as high as 60 kW/kg was obtained from as-grown carbon nanotubes in aqueous solution. Maximum specific energy of ~20 Wh/kg was obtained when carbon nanotubes were electrochemically oxidized and operated in organic solution. Demonstration of direct synthesis of carbon nanotubes on tantalum current collectors and their applications as supercapacitors could be an invaluable basis for fabrication of high performance carbon nanotube supercapacitors.

• Journal of the Korean institute of surface engineering
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• v.49 no.2
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• pp.125-129
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• 2016

Anodizing is a technology to generate thicker and high-quality films than natural oxide films by treating metals via electrochemical methods. Electrochemical manufacturing method of nano structure is an efficient technology in terms of cost reduction, high productivity and complicated shapes, which receives the spotlight in diverse areas. Especially, artificial films generated by anodizing technology possess excellent mechanical characteristics including hardness and wear resistance. It is also easy to modify thickness and adjust shape of those artificial films so that they are mainly used in sensors, filters, optical films and electrolytic condensers. In this study, experiment was performed to observe the effect of current density on porous film formation in two-step anodizing for Al alloy. Anodizing process was performed with 10 vol.% sulfuric acid electrolyte while the temperature was maintained at $10^{\circ}C$ using a double beaker. and $10{\sim}30mA/cm^2$ was applied for 40 minutes using a galvanostatic method. As a result, both pore diameters and distances between pores tended to increase as the local temperature and electrolysis activity increased due to the increase in applied current density.

• Korean Journal of Metals and Materials
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• v.47 no.11
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• pp.740-747
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• 2009

The purpose of this study is to identify the effect of electrolyte compositions on electrodeposited copper foil. First of all, the polyimide substrate was pretreated with plasma. Finally, copper foil was deposited on a Cu/Ni/Polyimide substrate using the electroplating technique. As the quantity of Cu increased, preferred orientations changed into (111). Increasing sulfuric acid, on the other hand, brought down the preferred orientation of (111). The lowest sheet resistance, surface roughness, and fine adhesion were detected when the ratio of $Cu^{2+}$ and $H_2SO_4$ is 50:50(g/l).

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.195-196
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• 2021

The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.