• 제목/요약/키워드: Sulfate environments

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해수-석탄회 상호작용에 의한 미량원소 용출특성:Batch 실험연구

  • 박성민;김강주;황갑수;김진삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.295-298
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    • 2004
  • It was revealed that leaching of elements were partly inhibited because seawater contains plenty of dissolved ions than fresh water. On the other hands, the low activity coefficient and the formation of complex with chloride and sulfate play roles in enhancing element leachability. However, the pH buffaring capacity of seawater is the most important factor that makes the leaching of elements and its chemical behavior in the seawater system different from those in the fresh water environments. In general, the leaching from the weathered ash was smaller than that from the fresh ash. However, it was revealed that the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of ash weathering. They were dependant only on the pH of the solutions.

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식물 바이러스병의 감염기구 및 증식억제에 관한 연구 1 (Studies on the Infection Mechanism and Inhibition of Multiplication in Plant Virus Diseases(I))

  • 이정호;오정행;박찬걸;권신한
    • 미생물학회지
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    • 제12권2호
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    • pp.53-58
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    • 1974
  • A number of antibiotics and organic compounds were tested for their effect on the multoplication of tobacco mosaic virus(TMV) in floating leaf discs. 1)Among six antibiotics tested, kanamycin sulfate showed 24% or more inhibition to TMV multiplication under these experimental conditions. Aureomycin hydrochloride and chloramphenicol showed 19% and 14% inhibition respectively. 2)For screening of organic compounds two environments were used, a diffuse day- light environment (25 foot-candles and laboratory temperature) and an artificial light environment for 12 hours per day(300 foot-candles at 4 to $5^{\circ}C above laboratory temperature). A wide range of organic compounds increased virus multoplication in the diffuse daylight environment but had less effect, or ingibited virus multiplication, in the artificial light environment. 3)The following compounds were among the most effective in increasing TMV multiplication: glucose-1-phosphate, L-aspartic acid, glucose, and 5-bromouracil. The following compoumds were most effective in inhibiting TMT multiplication: thiouracil, uracil, DL-isoleucine, L-leucine, and zinc chloride.

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A Review on the Radioisotopic Methods for Measuring Bacterial Production in Aquatic Environments

  • Hyun, Jung-Ho;Larock, Paul A.
    • Journal of the korean society of oceanography
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    • 제31권2호
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    • pp.97-106
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    • 1996
  • Advantages and disadvantages of four radioisotopic methods, $^{3}H$-thymidine, $^{3}H$-adenine, $^{3}H$-leucine, and $^{35}S$-sulfate, for measuring bacterial production were reviewed. The maior issues discussed in production methods were: (1) whether all the actively growing bacteria take up the radiolabeled (organic) tracers; (2) how each target molecule should be purified (nonspecific labeling); and (3) how important the determination of the precursor pool specific activity is (internal isotope dilution). Since all the radioisotoic methods have their own advantages and disadvantages, careful consideration must be paid in choosing the radioisotope according to the conditions of each environment investigated.

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철산화물의 합성 및 이를 이용한 비소의 흡착제거 (Synthesis of Iron Oxide and Adsorption of Arsenic on Iron Oxide)

  • 김연정;최식영;김영훈
    • 한국환경과학회지
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    • 제28권1호
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    • pp.99-106
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    • 2019
  • Arsenic is among the heavy metals commonly found in aqueous environments. Iron oxide is known as an efficient adsorbent for the arsenic. A new synthetic method was applied to provide iron oxide giving a large specific surface area. The mixing method affects the formation of iron oxide. Ultrasonic waves assisted the formation of very fine iron oxide in an organic phase. The synthesized iron oxide is amorphous type with a high surface area of more than $181.3m^2/g$. Sorption capacity of the synthesized adsorbent was relatively very high for arsenic and varied depending on the oxidation state of arsenic: a higher capacity was obtained with As(V). Lower solution pH provided a higher sorption capacity for As(V). The competitive effect of co-exist anions such as chloride, nitrate, and sulfate was minimal in sorption capacity of the iron oxide for arsenic.

Degradation mechanisms of concrete subjected to combined environmental and mechanical actions: a review and perspective

  • Ye, Hailong;Jin, Nanguo
    • Computers and Concrete
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    • 제23권2호
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    • pp.107-119
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    • 2019
  • In-service reinforced concrete structures are simultaneously subjected to a combination of multi-deterioration environmental actions and mechanical loads. The combination of two or more deteriorative actions in environments can potentially accelerate the degradation and aging of concrete materials and structures. This paper reviews the coupling and synergistic mechanisms among various deteriorative driving forces (e.g. chloride salts- and carbonation-induced reinforcement corrosion, cyclic freeze-thaw action, alkali-silica reaction, and sulfate attack). In addition, the effects of mechanical loads on detrimental environmental factors are discussed, focusing on the transport properties and damage evolution in concrete. Recommendations for advancing current testing methods and predictive modeling on assessing the long-term durability of concrete with consideration of the coupling effects are provided.

Mechanical and durability properties of fly ash and slag based geopolymer concrete

  • Kurtoglu, Ahmet Emin;Alzeebaree, Radhwan;Aljumaili, Omar;Nis, Anil;Gulsan, Mehmet Eren;Humur, Ghassan;Cevik, Abdulkadir
    • Advances in concrete construction
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    • 제6권4호
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    • pp.345-362
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    • 2018
  • In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

흑백 사진의 재질 분석 - 보로부두르 사진을 중심으로 - (Material Analysis of Black and White Photograph - Photograph from Borobudur -)

  • 윤은영;;진홍주
    • 보존과학회지
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    • 제35권5호
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    • pp.385-391
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    • 2019
  • 인도네시아 보로부두르 보존처리소에서 촬영한 보로부두르 사원 흑백 사진의 재질 특성을 조사하기 위해 과학적 분석을 수행하였다. 흑백 사진에서 시료를 채취하여 현미경 조사, 성분 및 재질 분석을 진행한 결과 흑백 사진은 지지체, 바리타층, 바인더층, 표면층 등 4개의 층으로 구성되어 있는 것을 확인하였다. 지지체는 마섬유로 구성된 종이, 바리타층은 분말상태의 황산바륨(BaSO4), 바인더층은 할로겐화은이 함유된 유제, 표면보호층은 젤라틴을 사용하여 제작된 것으로 판단하였다. 사진은 구성 재질에 따라 특성 및 보존 환경이 다르므로 시대에 따른 다양한 흑백 사진 재질 특성에 대한 연구가 필요하다.

콘크리트의 강도 및 내구성에 대한 고로슬래그미분말 분말도의 영향 (Effect of Fineness Levels of GGBFS on the Strength and Durability of Concrete)

  • 이승태
    • 대한토목학회논문집
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    • 제34권4호
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    • pp.1095-1104
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    • 2014
  • 본 연구는 콘크리트의 강도특성 및 내구성에 대한 고로슬래그미분말 분말도의 영향을 평가하기 위하여 수행되었다. 본 실험에 사용된 고로슬래그미분말의 분말도는 3종류(4,450, 6,000 및 $8,000cm^2/g$)를 선정하였으며, 보통포틀랜드시멘트에 대하여 50%를 대체하여 공시체를 제조하였다. 강도실험 결과에 따르면, 분말도가 $8,000cm^2/g$인 고로슬래그미분말을 사용한 콘크리트의 압축 및 쪼갬인장강도는 초기재령에서는 보통 포틀랜드시멘트 콘크리트에 비하여 다소 작았으나, 장기재령에서는 잠재수경성의 촉진으로 인하여 강도가 우수하게 나타났다. 내구성 분석결과에 의하면, 고분말도(6,000 및 $8,000cm^2/g$) 고로슬래그미분말 사용 콘크리트의 동결융해 저항성이 다소 작게 나타난 반면, 염소이온 침투저항성은 분말도 크기에 관계없이 고로슬래그미분말 적용 콘크리트가 우수하게 관찰되었다. 한편, 고로슬래그미분말을 사용한 모르타르의 황산염침식 저항성은 침식환경에 지배적인 영향을 받는 것으로 조사되었다.

메타카올린을 이용한 시멘트 모르타르의 기초물성에 관한 실험적 연구 (A Study on the Experimental of Basic Property of Cement Mortars using the Metakaolin)

  • 최강석;손홍우;김명식;백동일;장희석;김충호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.893-896
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    • 2008
  • 본 연구는 황산염 환경하에서 메타카올린을 사용하여 제작된 시멘트 모르타르의 기초물성을 평가하기 위한 연구이다. 최근 열악한 환경에 노출되는 콘크리트 구조물이 증가함에 따라 콘크리트의 내구성에 대한 관심이 늘어나고 있다. 광물성 혼화재료를 첨가할 경우 콘크리트 내부의 조직을 치밀하게 하여 내구성을 좋게하는 방안이 있으며 현재에도 실리카흄, 플라이애쉬, 슬래그와 같은 기존의 광물질 혼화재료 이외에 새로운 혼화재료에 대한 연구가 활발히 진행되고 있는 실정이다. 따라서 본 연구에서는 열악한 환경에 노출된 콘크리트 열화에 대하여 아직 그 연구가 미비한 광물질 혼화재료인 메타카올린을 5%, 10%, 15%로 치환하여 시멘트 모르타르로 시편을 제작하였고, 이를 28일 표준양생을 시켜 담수, 해수, 10% 황산나트륨용액, 10% 황산마그네슘 용액에서 28일, 60일, 90일, 180일, 270일, 365일 동안 촉진양생 시켜 다양한 시편의 기초물성에 대한 실험을 수행하였다. 또한 현재 널리 쓰이고 있는 광물질 혼화재료인 실리카흄과 플라이애쉬를 가지고 같은 방법으로 실험을 한 후 메타카올린을 치환한 시편과의 비교 분석을 통하여 메타카올린의 내구적 성능을 평가하고자 한다.

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감마선 조사에 의한 Acetylsalicylic Acid의 분해 (Decomposition of Acetylsalicylic Acid by Gamma Ray)

  • 안영덕;이경훤;이오미;김태훈;정인하;유승호;이면주
    • 방사선산업학회지
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    • 제5권3호
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    • pp.253-258
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    • 2011
  • Acetylsalicylic acid (ASA) has been issued recently in contaminated water environments because of potential impacts on ecosystem and public health. This study was aimed at investigating the possibility of ASA degradation using gamma ray irradiation. In addition, the use of sodium persulfate, hydrogen peroxide, ferrous sulfate were tested in order to examine a synergistic effect with gamma ray. The absorbed dose was ranged from 0.2 to 10 kGy and the concentration of oxidants were from 0.1 to 10 mM in this study. The concentration of ASA was gradually decreased corresponding to the increase of the absorbed dose. When soudium persulfate was simultaneously applied, most of the parent compound was completely degraded even at a low dose of 0.8 kGy. The removal efficiency of total organic carbon was 90% even at the highest dose of 10 kGy without sodium persulfate. However, the efficiency was dramatically enhanced up to 98% at the same dose by adding 10 mM of oxidants. It was suggested that hydroxyl radical ($OH{\cdot}$) and sulfate radical ($SO{_4}^-{\cdot}$) were formed in the system and made roles in degrading ASA at the same time.