• 광물과 암석
• /
• 제34권3호
• /
• pp.169-176
• /
• 2021

본 연구는 압력을 이용한 제올라이트 내 중금속 양이온 또는 CO₂ 기체 포집 등의 응용연구를 하기 위한 기초 단계로 제올라이트의 압력 및 압력전달 매개체(Pressure-transmitting medium, PTM)에 따른 결정구조의 변화를 알아보기위한 목적으로 실험을 진행하였다. 천연 제올라이트 멜리노이트(Merlinoite, (K,Ca_0.5,Ba_0.5,Na)₁₀ Al₁₀Si₂₂O₆₄× 22H₂O)와 동일한 골격구조를 가지는 합성 물질인 제올라이트-W(K_6.4Al_6.5Si_25.8O₆₄× 15.3H₂O, K-MER)의 압력 하 압력전달 매개체에 따른 선형 압축률 및 체적 탄성률의 변화에 대한 X선 회절연구를 진행하였다. 합성된 시료는 정방정계에 속하는 I4/mmm 공간군으로 확인되었다. 압력전달 매개체 중 제올라이트의 동공 및 채널을 투과할 수 있는 투과 매개체(Penetrating medium)로 물, 이산화탄소를, 비투과 매개체로 실리콘 오일(Silicone-oil)을 각각 사용하였으며, 상압에서 최대 3 GPa까지 약 0.5 GPa 간격으로 가압하였다. 다이아몬드 고압유도장치 및 방사광 X-선원을 이용하여 압력 하 시료의 분말 회절을 측정하였고, 르바일(Le-Bail)법 및 버치-머내한 상태방정식을 이용하여 격자상수 및 체적탄성률의 변화를 관찰하였다. 모든 실험에서 c축의 선형압축률(𝛽^c)은 0.006(1) GPa^-1또는 0.007(1) GPa^-1의 값을 보여 압력 증가 대비 유사한 압축률을 보인 반면, a축의 압축률(𝛽^a)은 실리콘 오일 실험에서 0.013(1) GPa^-1을 보여 물과 이산화탄소 (𝛽^a=0.006(1) GPa^-1) 실험결과에 비해 압축률이 약 두 배정도 큰 것으로 확인할 수 있었다. 체적탄성률(K₀)은 물, 이산화탄소, 실리콘 오일의 실험에서 각각 50(3) GPa, 52(3) GPa, 29(2) GPa로 도출되었다. 압력 증가에 따른 ac면의 orthorhombicity를 측정한 결과 물과 이산화탄소 실험에서는 0.350~0.353의 비교적 일정한 값을 보였으나, 실리콘 오일의 실험에서는 y = -0.005(1)x + 0.351(1)의 함수를 만족시키며 압력이 증가할수록 값이 점차 작아졌다.

• 한국해안·해양공학회논문집
• /
• 제35권6호
• /
• pp.146-154
• /
• 2023

본 연구에서는 서해안 해상기상타워 2기에서 관측된 수면변동자료를 이용하여 해양특성을 구분하는 주요 인자인 첨두주기 T_p와 평균주기 T₀₂와 T_{m-1, 0}를 산정하고 이상자료의 비율, 상관관계 분석 및 최적 확률밀도함수를 추정하였다. 산정된 대표주기 중 첨두주기의 경우, 이상 자료의 비율은 각각의 지점에서 5.73 %, 0.67 %로 나타났으며, T₀₂는 4.35%, 0.01%, T_{m-1, 0}는 2.82%, 0.03%로 나타났다. 한편, T₀₂와 T_p 사이의 관계를 분석한 결과 각 지점별로 0.53, 0.63의 관계로 산정됐으며, T_{m-1, 0}와 T_p의 관계는 각각 1.15, 1.32로 나타났다. T₀₂와 T_{m-1, 0}는 서로 1.18, 1.22의 관계를 보이고 있었다. 산정된 대표주기의 최적 확률밀도함수를 추정한 결과, T_p는 각각의 지점에서 'Lognormal', 'Normal' 분포를 따르고 있었으며, T₀₂는 'Gamma', 'Normal' 분포, T_{m-1, 0}는 각각 'Log-normal', 'Normal' 분포가 우세한 것으로 나타났다. 이러한 결과는 서해안을 대상으로 수행되는 파랑 분석에 기초자료로 사용될 수 있을 것으로 판단된다.

• 대한수학회보
• /
• 제58권3호
• /
• pp.659-668
• /
• 2021

Let R be a semiprime ring with maximal right ring of quotients Q_mr(R), and let n₁, n₂, …, n_k be k fixed positive integers. Suppose that R is (n₁+n₂+⋯+n_k)!-torsion free, and that f : 𝜌 → Q_mr(R) is an additive map, where 𝜌 is a nonzero right ideal of R. It is proved that if [[…[f(x), x^n₁], …], x^n_k] = 0 for all x ∈ 𝜌, then [f(x), x] = 0 for all x ∈ 𝜌. This gives the result of Beidar et al. [2] for semiprime rings. Moreover, it is also proved that if R is p-torsion, where p is a prime integer with p = Σ^k_i=1 n_i and if f : R → Q_mr(R) is an additive map satisfying [[…[f(x), x^n₁], …], x^n_k] = 0 for all x ∈ R, then [f(x), x] = 0 for all x ∈ R.

• Journal of Electrochemical Science and Technology
• /
• 제11권1호
• /
• pp.50-59
• /
• 2020

Birnessite-type manganese dioxide (δ-MnO₂) with hierarchical micro-/mesoporosity was synthesized via sacrificial graphene template approach under mild hydrothermal conditions for the first time. Graphene template was obtained by a surfactant (cetyltrimethylammonium bromide, CTAB) assisted liquid phase exfoliation (LPE) in water. A thin PEDOT:PSS (poly (3,4-ethylene dioxythiophene): poly (styrene sulfonate)) layer was applied to improve electrical conductivity and rate capability of MnO₂. The MnO₂ (535 F g^-1 at 1 A g^-1 and 45 F g^-1 at 10 A g^-1) and MnO₂/PEDOT:PSS nanocomposite (550 F g^-1 at 1 A g^-1 and 141 F g^-1 at 10 A g^-1) delivered electrochemical performances superior to their previously reported counterparts. An asymmetric supercapacitor, composed of MnO₂/PEDOT:PSS (positive) and Fe₃O₄/Carbon (negative) electrodes, provided a maximum specific energy of 18 Wh kg^-1 and a maximum specific power of 4.5 kW kg^-1 (ΔV= 2 V, 1M Na₂SO₄) with 85% capacitance retention after 1000 cycles. The graphene-templated MnO₂/PEDOT:PSS nanocomposite obtained by a simple and green approach promises for future energy storage applications with its remarkable capacitance, rate performance and cycling stability

• Journal of Preventive Medicine and Public Health
• /
• 제56권5호
• /
• pp.449-457
• /
• 2023

Objectives: This study investigated the association between baseline exposures to particulate matter with a diameter <2.5 microns (PM_2.5) and subsequent temporal changes in PM_2.5 exposure with the incidence of type 2 diabetes among Royal Thai Army personnel. Methods: A retrospective cohort study was conducted using nationwide health check-up data from 21 325 Thai Army personnel between 2018 and 2021. Multilevel mixed-effects parametric survival statistics were utilized to analyze the relationship between baseline (i.e., PM_2.5-baseline) and subsequent changes (i.e., PM_2.5-change) in PM_2.5 exposure and the occurrence of type 2 diabetes. Hazard ratios (HRs) and 95% confidence intervals (CIs) were employed to assess this association while considering covariates. Results: There was a significant association between both PM_2.5 baseline and PM_2.5-change and the incidence of type 2 diabetes in a dose-response manner. Compared to quartile 1, the HRs for quartiles 2 to 4 of PM_2.5-baseline were 1.11 (95% CI, 0.74 to 1.65), 1.51 (95% CI, 1.00 to 2.28), and 1.77 (95% CI, 1.07 to 2.93), respectively. Similarly, the HRs for quartiles 2 to 4 of PM_2.5-change were 1.41 (95% CI, 1.14 to 1.75), 1.43 (95% CI, 1.13 to 1.81) and 2.40 (95% CI, 1.84 to 3.14), respectively. Conclusions: Our findings contribute to existing evidence regarding the association between short-term and long-term exposure to PM_2.5 and the incidence of diabetes among personnel in the Royal Thai Army.

• Korean Journal of Mathematics
• /
• 제28권2호
• /
• pp.379-389
• /
• 2020

An r-color Rado number N = R(𝓛, r) for a system 𝓛 of equations is the least integer, provided it exists, such that for every r-coloring of the set {1, 2, …, N}, there is a monochromatic solution to 𝓛. In this paper, we study the 2-color Rado number R(𝓔, 2) for 𝓔 : x₁ + x₂ + ⋯ + x_n = y₁ + y₂ = z when n ≥ 4.

• 대한수학회보
• /
• 제57권2호
• /
• pp.331-343
• /
• 2020

This paper is concerned with the global behavior of components of radial nodal solutions of semilinear elliptic problems -Δv = λh(x, v) in Ω, v = 0 on ∂Ω, where Ω = {x ∈ R^N : r₁ < |x| < r₂} with 0 < r₁ < r₂, N ≥ 2. The nonlinear term is continuous and satisfies h(x, 0) = h(x, s₁(x)) = h(x, s₂(x)) = 0 for suitable positive, concave function s₁ and negative, convex function s₂, as well as sh(x, s) > 0 for s ∈ ℝ \ {0, s₁(x), s₂(x)}. Moreover, we give the intervals for the parameter λ which ensure the existence and multiplicity of radial nodal solutions for the above problem. For this, we use global bifurcation techniques to prove our main results.

• Bulletin of the Korean Chemical Society
• /
• 제24권1호
• /
• pp.60-64
• /
• 2003

The reactions of $[Pt(dppf)Cl_2]$ with thiophenol (PhSH), 1-propanethiol (n-PrSH), and 1,3-propanedithiol $(HSCH_2CH_2CH_2SH)$ gave the corresponding Pt-dppf-di(thiolato) compounds, $[Pt(dppf)(SPh)_2]\;(1),\;[Pt(dppf)(S-n-Pr)_2]\;(2),\;and [Pt(dppf)(SCH_2CH_2CH_2S)]\;(3)$, respectively. All products are monomeric and 4-coordinate square-planar compounds and were structurally characterized by X-ray diffraction. Electrochemical measurements (cyclovoltammograms) revealed that the oxidation potential of the dppf ligand appears to depend on the type of the group on the thiolato ligand.

• Journal of applied mathematics & informatics
• /
• 제40권3_4호
• /
• pp.409-431
• /
• 2022

In this paper, we deal with the existence of solutions of the following system of nonlinear rational difference equations with order five $x_{n+1}=\frac{y_{n-3}x_{n-4}}{y_n(a+by_{n-3}x_{n-4})}$, $y_{n+1}=\frac{x_{n-3}y_{n-4}}{x_n(c+dx_{n-3}y_{n-4})}$, n = 0, 1, ⋯, where parameters a, b, c and d are not executed at the same time and initial conditions x_-4, x_-3, x_-2, x_-1, x₀, y_-4, y_-3, y_-2, y_-1 and y₀ are non zero real numbers.

• 한국세라믹학회지
• /
• 제43권1호
• /
• pp.55-61
• /
• 2006

The microwave dielectric properties and low temperature sintering of $Ca[Ti_{1-x}(Ni_{1/3}Nb_{2/3})_x]O_3$ system were investigated at the sintering temperature $1,200\~1,350^{\circ}C$. The density and quality factors $(Q{\times}f)$ increased while dielectric constants slightly decreased with the decrease of Ti. The dielectric constant, quality factor, and temperature coefficient of resonance frequency $(\tau_f)$ were 64, 17,000 GHz, and $-9.1\;ppm/^{\circ}C$ respectively, when $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ ceramics were sintered at $1,300^{\circ}C$ for 4 h. $2Li_2O-B_2O_3$ was added to $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ to decrease the sintering temperature for LTCC application. The microwave dielectric properties of the samples sintered at $925^{\circ}C$ for 2 h with the addition of $6\;wt\%\;2Li_2O-B_2O_3$ were $\varepsilon_r=48.7,\;Q{\times}f=8,460\;GHz$, and $\tau_f=+5.6ppm/^{\circ}C$. Compatibility test of the composition with silver electrode shows no reaction with silver electrode, implying the feasibility as a high-K LTCC material.