• Journal of Advanced Marine Engineering and Technology
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• 제19권3호
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• pp.42-49
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• 1995

In this study, the optimum structural modification of the L-type structure by shape changes is suggested. The vibration characteristics of L-type structure are analyzed by the sub-structure synthesis method, and the coordinte sensitivities of each sub-structure are calculated and the change quantities of the positions to be modified are suggested by using the coordinate sensitivities. The results obtained are as follows : 1. The sensitivities of the natural frequency could be calculated by the sensitivity analysis. 2. The change quantities of the position to be modified could be suggested by the optimum structural modification method. 3. The developed program could reduce the process and time of computation, since the sensitivity was directly calculated by differential method, not finite difference method.

• Advances in nano research
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• 제13권5호
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• pp.437-451
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• 2022

Synthesis approaches usually affect the physical and chemical properties of ferrites. This helps ferrite materials to design them for desired applications. Some of these methods are mechanical milling, ultrasonic method, micro-emulsion, co-precipitation, thermal decomposition, hydrothermal, microwave-assisted, sol-gel, etc. These methods are extensively reviewed by taking example of ZnFe₂O₄. These methods also affect the microstructure and local structure of ferrite which ultimately affect the physical and chemical properties of ferrites. Various spectroscopic techniques such as Raman spectroscopy, Fourier Transform Infrared spectroscopy, Ultra Violet-Visible spectroscopy, Mossbauer spectroscopy, extended x-ray absorption fine structure, and electron paramagnetic resonance are found helpful to reveal this information. Hence, the basic principle and the usefulness of these techniques to find out appropriate information in ZnFe₂O₄ nanoparticles is elaborated in this review.

• Nuclear Engineering and Technology
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• 제53권5호
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• pp.1593-1601
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• 2021

Oxide dispersion strengthening (ODS) tungsten alloys are highly desirable in irradiation applications. However, how to improve the properties of ODS-tungsten alloys efficiently has been worth studying for a long time. Here we report a nanostructuring approach that achieves W-La₂O₃ alloy with a high level of flexural strength and Vickers hardness at room temperature, which have the maximum value of 581 MPa and 703 Hv, respectively. This method named solution combustion synthesis (SCS) can generate 30 nm coating structures W-La₂O₃ composite powders by using Keggin-type structural polyoxometalates as raw materials in a fast and low-cost process. The composite powder can be fabricated to W-La₂O₃ alloy with an optimal microstructure of submicrometric W grains coexisting with nanometric oxide particles in the grain interior, and a stability interface structure of grain boundaries (GBs) by forming transition zones. The method can be used to prepare new ODS alloys with excellent properties in the future.

• Structural Engineering and Mechanics
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• 제45권4호
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• pp.423-437
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• 2013

Complex structures are usually assembled from several substructures with joints connecting them together. These joints have significant effects on the dynamic behavior of the assembled structure and must be accurately modeled. In structural analysis, these joints are often simplified by assuming ideal boundary conditions. However, the dynamic behavior predicted on the basis of the simplified model may have significant errors. This has prompted the researchers to include the effect of joint stiffness in the structural model and to estimate the stiffness parameters using inverse dynamics. In the present work, structural joints have been modeled as a pair of translational and rotational springs and frequency equation of the overall system has been developed using sub-structure synthesis. It is shown that using first few natural frequencies of the system, one can obtain a set of over-determined system of equations involving the unknown stiffness parameters. Method of multi-linear regression is then applied to obtain the best estimate of the unknown stiffness parameters. The estimation procedure has been developed for a two parameter joint stiffness matrix.

• 한국지구과학회지
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• 제23권1호
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• pp.52-58
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• 2002

A colorless and transparent zirconium oxide ($Zr_{0.73}Y_{0.27}O_{1.87}$) crystal has been synthesized by the Bridgman-Stockbager method. The gem-quality material is produced by adding 20${\sim}$25 wt.% $Y_2O_3$ (stabilizer) and 0.04 wt.% $Nd_2O_3$ (decolorising agent) to the $ZrO_2$ powder. It shows a vitreous luster with a slight oily appearance. Under a polarizing microscope, it shows isotropic nature with no appreciable anisotropism. Mohs hardness value and specific gravity is measured to be 8${\sim}$$8{\frac{1}{2}}$ and 5.85, respectively. Under ultraviolet light it shows a faint white glow. The crystal structure of yttria-stabilized zirconia with 0.27 at.% Y has been re-investigated, using single crystal X-ray diffraction, and confirmed to be a cubic symmetry, space group $Fm{\overline{3}}m$ ($O^5_h$) with a=5.1552(5) ${{\AA}}$, V=136.99(5) ${{\AA}}^3$, Z=4. The stabilizer atoms randomly occupy the zirconium sites and there are displacements of oxygen atoms with amplitudes of ${\Delta}/a{\sim}$0.033 and 0.11 along <110> and <111> from the ideal positions of the fluorite structure, respectively.

• 한국분말재료학회지
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• 제25권5호
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• pp.420-425
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• 2018

Core-shell structured nanoparticles are garnering attention because these nanoparticles are expected to have a wide range of applications. The objective of the present study is to improve the coating efficiency of gold shell formed on the surface of silica nanoparticles for $SiO_2@Au$ core-shell structure. For the efficient coating of gold shell, we attempt an in-situ synthesis method such that the nuclei of the gold nanoparticles are generated and grown on the surface of silica nanoparticles. This method can effectively form a gold shell as compared to the conventional method of attaching gold nanoparticles to silica particles. It is considered possible to form a dense gold shell because the problems caused by electrostatic repulsion between the gold nanoparticles in the conventional method are eliminated.

• 대한기계학회논문집A
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• 제24권6호
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• pp.1427-1437
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• 2000

In the authors＇ preceeding paper, an improved component mode synthesis (CMS) technique in which experimental data as well as finite-element data are available in sub-systems has been proposed. Thi s technique, called an improved experimental free-interface method (IEFIM), has been proved to be more accurate and more efficient than the conventional experimental CMS method based on McNeal's formulation. It is due to the facts that dynamic residual terms as well as static ones are compensated from experimentally obtained FRFs and that FRFs measured on any frequencies can be used for the compensation. In this paper, the technique is applied to the component mode synthesis of a car body structure. As a result, the applicability of the technique to a large structure is demonstrated.

• Journal of Advanced Marine Engineering and Technology
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• 제39권4호
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• pp.393-398
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• 2015

진동해석에 있어서 매우 중요한 부분 중의 하나가 주파수응답함수를 구하는 것이다. 크거나 복잡한 구조물은 일반적으로 아주 큰 자유도-예를 들면 수 백 만 자유도-를 가지기 때문에 역행렬에 의한 전통적인 방법으로는 주파수응답함수를 구할 수 없을지도 모른다. 그래서 전체 구조물을 몇 개의 부분구조로 나누어서 해석하는 부분구조 해석법을 이용한다. 여기에서는 부분구조별로 나누어 계산한 부분구조 진동모드를 이용하여 자유도를 현격하게 낮춘 등가의 저 자유도 모델에서 주파수응답함수를 구하는 방법을 제시한다. 개발한 프로그램의 신뢰도를 확인하기 위하여 평판 구조물에 적용하여서 실험과 축소하지 않는 영역에서의 해석 결과와 본 해석 결과를 비교하였고, 매우 좋은 결과를 얻었다.

• Advances in nano research
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• 제1권4호
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• pp.211-218
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• 2013

A low-cost, green and reproducible citric acid assisted synthesis of nanocrystalline $Al_{0.5}Ag_{0.5}TiO_3$ (n-AAT) powder is reported. X-ray, FTIR, energy dispersive X-ray, transmission electron microscopy and scanning electron microscopy analyses are performed to ascertain the formation of n-AAT. X-ray diffraction data analysis indicated the formation of monoclinic structure. Spherical shaped particles having the sizes of 3-15 nm are found. The mechanism of nano-transformation for the soft-chemical synthesis of n-AAT has been explained using simple organic chemistry rules and nucleation and growth theory. Dielectric study revealed that AAT ceramic might be a suitable candidate for capacitor applications.

• 한국세라믹학회지
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• 제56권2호
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• pp.111-129
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• 2019

Recently, all-solid-state batteries (ASSBs) have attracted increasing interest owing to their higher energy density and safety. As the core material of ASSBs, the characteristics of the solid electrolyte largely determine the performance of the battery. Thus far, a variety of inorganic solid electrolytes have been studied, including the NASICON-type, LISICON-type, perovskite-type, garnet-type, glassy solid electrolyte, and so on. The garnet Li₇La₃Zr₂O₁₂ (LLZO) solid electrolyte is one of the most promising candidates because of its excellent comprehensively electrochemical performance. Both, experiments and theoretical calculations, show that cubic LLZO has high room-temperature ionic conductivity and good chemical stability while contacting with the lithium anode and most of the cathode materials. In this paper, the crystal structure, Li-ion transport mechanism, preparation method, and element doping of LLZO are introduced in detail based on the research progress in recent years. Then, the development prospects and challenges of LLZO as applied to ASSBs are discussed.